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ChemicalBook > CAS DataBase List > (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&

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Product Name
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
CAS No.
307926-51-8
Chemical Name
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
Synonyms
(S,S)Salen AI;(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-;(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%;Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)
CBNumber
CB7504613
Molecular Formula
C36H52AlClN2O2
Formula Weight
607.254
MOL File
307926-51-8.mol
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Property

Melting point:
>350 °C(lit.)
form 
Powder
color 
yellow
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531979
Product name
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Packaging
1g
Price
$82.4
Updated
2024/03/01
Strem Chemicals
Product number
13-5801
Product name
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging
1g
Price
$186
Updated
2024/03/01
Strem Chemicals
Product number
13-5801
Product name
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging
5g
Price
$741
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0000048
Product name
(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Purity
95.00%
Packaging
1G
Price
$671.25
Updated
2021/12/16
Ambeed
Product number
A913279
Product name
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Purity
98%
Packaging
25g
Price
$1365
Updated
2021/12/16
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Chemical Properties,Usage,Production

Reaction

Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes.

Uses

(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:

  • In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
  • In the cyanation of α,β-unsaturated imides to yield saturated imides.

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Preparation Products And Raw materials

Raw materials

Preparation Products

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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
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307926-51-8, (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&Related Search:


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  • (S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
  • (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
  • (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride
  • (S,S)Salen AI
  • Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)
  • (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%
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  • Jacobsen Metal