3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

ChemicalBook > CAS DataBase List > 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

Product Name: 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
CAS No.: 4568-71-2
Chemical Name: 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
Synonyms: 3-Benzyl-5-(hydroxyethyl)-4-methylthiazolium chloride;3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazol-3-ium chloride;3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazole-3-ium·chloride;Nsc172802;-3-ium chL;-5-(2-hydroxyethyL;LABOTEST-BB LT00452912;3-Benzyl-5(2-OHEt)-4-mEtthiazolium Cl;3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIA;2-(3-benzyl-4-methyl-thiazol-3-ium-5-yl)ethanol
CBNumber: CB7689262
Molecular Formula: C13H16ClNOS
Formula Weight: 269.79
MOL File: 4568-71-2.mol

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3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Property

Melting point:: 142-144 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: sol H2O, MeOH, EtOH; slightly sol cold MeCN; insol ether, pentane
form: Crystalline Powder
color: White
Water Solubility: Soluble in water.
Sensitive: Hygroscopic
BRN: 3788921
InChI: InChI=1S/C13H16NOS.ClH/c1-11-13(7-8-15)16-10-14(11)9-12-5-3-2-4-6-12;/h2-6,10,15H,7-9H2,1H3;1H/q+1;/p-1
InChIKey: IWSVLBKHBJGMAA-UHFFFAOYSA-M
SMILES: [N+]1(=CSC(CCO)=C1C)CC1=CC=CC=C1.[Cl-]
CAS DataBase Reference: 4568-71-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29341000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 256234
Product name: 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride
Purity: 98%
Packaging: 25g
Price: $67.2
Updated: 2024/03/01

TCI Chemical

Product number: B1224
Product name: 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium Chloride
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $95
Updated: 2024/03/01

Alfa Aesar

Product number: L08750
Product name: 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%
Packaging: 25g
Price: $50.65
Updated: 2024/03/01

Alfa Aesar

Product number: L08750
Product name: 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%
Packaging: 100g
Price: $150.65
Updated: 2024/03/01

AK Scientific

Product number: J56321
Product name: 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride
Packaging: 100g
Price: $173
Updated: 2021/12/16

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3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Chemical Properties,Usage,Production

Uses

3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, aliphatic aldehydes undergo the acyloin condensation in the presence of this catalyst and mild base. It acts as a catalyst for the addition of aliphatic and heterocyclic aldehydes to α,β-unsaturated ketones, nitriles and esters.

Purification Methods

Purify the chloride by recrystallisation from EtOH or H2O. If placed in a bath at 125o and heated at 2o/minute, the melting point is 140.5-141.4o. [Livermore & Sealock J Biol Chem 167 699 1947, Maier & Metzler J Am Chem Soc 79 4386 1957, Beilstein 27 III/IV 1758.]

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE manufacturers

Career Henan Chemical Co

Product: 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE 4568-71-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2018-08-13

4568-71-2, 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDERelated Search:

2,2'-Dithiobis(benzothiazole) Lithium chloride Lithium 4,5-Dimethylthiazole 3-BENZYL-4-METHYLTHIAZOLIUM CHLORIDE 5-Methylthiazole 5-(2-Hydroxyethyl)-4-methylthiazole 5-ethyl-4-methylthiazole 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazole-3-ium·chloride

3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazolium·chloride

5-(2-Hydroxyethyl)-3-benzyl-4-methylthiazole-3-ium·chloride

Nsc172802

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIA

3-Benzyl-5-(2-hydroxyethyl)-4-MethylthiazoliuM chloride 98%

3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazol-3-ium chloride

3-Benzyl-5(2-OHEt)-4-mEtthiazolium Cl

3-BENZYL-5-(-2-HYDROXYETHYL)-4-METHYL 1,3-THIAZOLIUM CHLORIDE

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

LABOTEST-BB LT00452912

3-Benzyl-5-(hydroxyethyl)-4-methylthiazolium chloride

3-Benzyl-5(2-hydroxyethyl)-4-methylthiazolium chloride, GC 98%

5-(2-Hydroxyethyl)-4-methyl-3-benzylthiazolium chloride

3-Benzyl-4-methyl-3-azoniathiazole-5-ethanol·chloride

3-Benzyl-4-methyl-5-(2-hydroxyethyl)-3-azoniathiazole·chloride

Thiazolium, 5-(2-hydroxyethyl)-4-methyl-3-(phenylmethyl)-, chloride

3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium Chloride &gt

3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%, for synthesis

-3-ium chL

-5-(2-hydroxyethyL

2-(3-benzyl-4-methyl-thiazol-3-ium-5-yl)ethanol

2-(3-benzyl-4-methyl-1,3-thiazol-3-ium-5-yl)ethanol

3-Benzyl-5-(2-via ethyl)-4-methylThiazole chloride

3-Blin-5-(2-hydroxyethyl)-4-AChlorinated prazole

4568-71-2

4658-71-2

C13H16NOSCl

Phase Transfer Catalysts

Synthetic Reagents

Heterocyclic Ammonium Salts

Greener Alternatives: Catalysis

Phase Transfer Catalysts