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VANADIUM(IV) OXIDE

Description References
Product Name
VANADIUM(IV) OXIDE
CAS No.
12036-21-4
Chemical Name
VANADIUM(IV) OXIDE
Synonyms
VO2;dioxovanadium;VANADIUM OXIDE;Vanadium(Ⅳ)oxide;VANADIUM DIOXIDE;VANADIUM(IV) OXIDE;vanadiumoxide(vo2);Vanadium tetroxide;VANADIUM TETRAOXIDE;Vanadium(IV)dioxide
CBNumber
CB7715136
Molecular Formula
O2V
Formula Weight
82.94
MOL File
12036-21-4.mol
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VANADIUM(IV) OXIDE Property

Melting point:
1967°C
Density 
4.339 g/mL at 25 °C(lit.)
solubility 
insoluble in H2O; soluble in acid solutions, alkaline solutions
form 
Powder
Specific Gravity
4.339
color 
black
Water Solubility 
Insoluble in water.
Crystal Structure
MoO2 type
crystal system
Monoclinic
Space group
P21/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.535280.453780.5382590115.208900.1183
Exposure limits
NIOSH: Ceiling 0.05 mg/m3
CAS DataBase Reference
12036-21-4(CAS DataBase Reference)
EPA Substance Registry System
Vanadium oxide (VO2) (12036-21-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-37/39
RIDADR 
UN3285
WGK Germany 
3
10-23
HazardClass 
6.1
PackingGroup 
II
HS Code 
28253090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
215821
Product name
Vanadium(IV) oxide
Purity
≥99% trace metals basis
Packaging
5g
Price
$141
Updated
2024/03/01
Sigma-Aldrich
Product number
215821
Product name
Vanadium(IV) oxide
Purity
≥99% trace metals basis
Packaging
20g
Price
$408
Updated
2024/03/01
Alfa Aesar
Product number
022957
Product name
Vanadium(IV) oxide
Purity
99% (metals basis)
Packaging
10g
Price
$89.9
Updated
2024/03/01
Alfa Aesar
Product number
022957
Product name
Vanadium(IV) oxide
Purity
99% (metals basis)
Packaging
50g
Price
$360
Updated
2024/03/01
Strem Chemicals
Product number
93-2309
Product name
Vanadium(IV) oxide, 99+%
Packaging
2g
Price
$39
Updated
2024/03/01
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VANADIUM(IV) OXIDE Chemical Properties,Usage,Production

Description

Vanadium (IV) dioxide is a kind of inorganic compound with its chemical formula being VO2. It can undergo a phase transition at a normal temperature (~66 °C). Its electrical resistivity and opacity can also change several fold. These special properties make it have many applications. For example, it can be used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It can also be used as a stationary optical shutter, optical modulators, cameras and data storage. Moreover, it can be applied to the missile guidance system due to its infrared modulation capability. It can also be used to make thin films which have been used in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft. It can also be used in phase change computing and memory.

References

https://en.wikipedia.org/wiki/Vanadium(IV)_oxide
https://www.alfa.com/en/catalog/022957/

Chemical Properties

Blue-black powder. Insoluble in water; soluble in alkalies and acids.

Chemical Properties

Vanadium(IV) Oxide (vanadium dioxide, VO2) is a blue-black solid, having a distorted rutile (TiO2) structure. It can be prepared from the reaction of V2O5 at the melting point with sulfur or carbonaceous reductants such as sugar or oxalic acid. The dioxide slowly oxidizes in air. Vanadium dioxide dissolves in acids to give the stable (VO)2+ ions and in hot alkalies to yield vanadate(IV) species, eg, (HV2O5)?.

Uses

Vanadium(IV) oxide is used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It acts as a stationary optical shutter, optical modulators, cameras and data storage. As infrared modulators, it is used for the missile guidance systems. Thin films made up of vanadium dioxide find applications in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft.

Definition

ChEBI: Vanadium dioxide is a vanadium oxide.

Hazard

Toxic and irritating.

Flammability and Explosibility

Non flammable

VANADIUM(IV) OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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VANADIUM(IV) OXIDE Suppliers

Shanghai Yunfu Nano Technology Co., LTD
Tel
15796584478; 15796584478
Email
3246531796@qq.com
Country
China
ProdList
500
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
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View Lastest Price from VANADIUM(IV) OXIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
VANADIUM(IV) OXIDE 12036-21-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Mojin Biotechnology Co., Ltd
Product
VANADIUM(IV) OXIDE 12036-21-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16

12036-21-4, VANADIUM(IV) OXIDERelated Search:


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