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CARBETAMIDE

Product Name
CARBETAMIDE
CAS No.
16118-49-3
Chemical Name
CARBETAMIDE
Synonyms
561 RP;Liquide;11,561rp;LEGURAME;RP 11561;Arbetamex;carbetamid;carbetamex;leguramepm;Legurame[R]
CBNumber
CB7717695
Molecular Formula
C12H16N2O3
Formula Weight
236.27
MOL File
16118-49-3.mol
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CARBETAMIDE Property

Melting point:
>110°C
Boiling point:
378.73°C (rough estimate)
Density 
1.174
refractive index 
1.5460 (estimate)
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
13.22±0.70(Predicted)
Water Solubility 
3.5g/L(20 ºC)
BRN 
8318291
LogP
1.520 (est)
EPA Substance Registry System
Carbetamide (16118-49-3)
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Safety

Hazard Codes 
Xi
WGK Germany 
2
RTECS 
FD8900000
HS Code 
29242990
Toxicity
dog,LD50,oral,900mg/kg (900mg/kg),Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 80, 1973.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45369
Product name
Carbetamide
Purity
PESTANAL
Packaging
250mg
Price
$94.4
Updated
2024/03/01
TRC
Product number
C178028
Product name
Carbetamide
Packaging
250mg
Price
$120
Updated
2021/12/16
AHH
Product number
MT-04527
Product name
Carbetamide
Purity
98%
Packaging
5g
Price
$412
Updated
2021/12/16
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CARBETAMIDE Chemical Properties,Usage,Production

Chemical Properties

Carbetamide is a colorless, crystalline powder, or solid.

Uses

Carbetamide is used in the determination of pesticides.

Definition

ChEBI: A carbamate ester obtained by the formal condensation of phenylcarbamic acid with the hydroxy group of N-ethyl-2-hydroxypropanamide.

Potential Exposure

Carbamate herbicide used to kill unwanted plants

Metabolic pathway

Photodegradation of carbetamide in solution with UV irradiation in the presence of UV ? H2O2 and ? TiO2 primarily occurs at the o- and p-positions, but not at the m-position of the phenyl ring, and the preferential photoproduct isolated is ortho-hydroxylated carbetamide. 5-Methyl-3-phenyl-oxazolidine dione is isolated only in the presence of TiO2. The cyclization may result from radical coupling with the dissolved oxygen. N-De-ethylation of the ethylcarbamoyl group and hydroxylation on the carbamoyloxy linkage occur to yield free amine of carbetamide and lactamide analogs. It is interesting to note that formulated carbetamide is phototransformed to N-ethyllactamide- 4-aminobenzoate as a major product via the rearrangement reaction similar to the Photo-Fries reaction. The degradation kinetics of carbetamide and its potential metabolites are measured at different temperatures in both unsterilized and sterilized alkaline soil.
The chemical degradation of carbetamide importantly gives N-phenyl-3-methyloxazolidine-2,5- dione which results in 2-(phenylcarbamoyloxy)- propionic acid and N-phenyl-2-hydroxypropionamide and the aniline in the soil. The purely biological degradation of this compound cannot clearly yield degradation products that are different from those by chemical degradation in non-sterilized soils.

Shipping

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN 2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Incompatibilities

Slowly hydrolyzes in water, releasing ammonia and forming acetate salts. Carbamates are incompatible with reducing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. Amides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides with strong reducing agents such as hydrideds and active metals. Amides are very weak bases (weaker than water). Mixing amides with dehydrating agents such as phosphorus pentoxide or thionyl chloride generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). This compound is decomposed by strong base or acid.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved land fill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

CARBETAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CARBETAMIDE Suppliers

J & K SCIENTIFIC LTD.
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16118-49-3, CARBETAMIDERelated Search:


  • (1-ethylcarbamoyl)ethylester,d-(-)-carbanilicaci
  • (phenylcarbamoyloxy)-2-n-ethylpropionamide
  • (r)-n-ethyl-2-(((phenylamino)carbonyl)oxy)propanamide
  • 11,561rp
  • (R)-1-(ethylaMino)-1-oxopropan-2-yl phenylcarbaMate
  • CarbetaMide 0
  • Carbetamide Standard
  • Carbetamide Solution, 1000ppm
  • 2-phenyl-carbamoyloxy-n-aethyl-propionamid
  • carbetamex
  • carbetamid
  • carbethamide
  • d-(-)-1-(ethylcarbamoyl)ethylphenylcarbamate
  • d-n-ethylacetamidecarbanilate
  • d-n-ethyllactamidecarbanilate(ester)
  • (2R)-N-Ethyl-2-[[(phenylamino)carbonyl]oxy]propanamide
  • Carbetamide Solution, 100ppm
  • LEGURAME
  • leguramepm
  • n-ethyl-,carbanilate(ester),d-lactamid
  • Carbetamex[R]
  • D-N-Ethylactamide carbanilate ester
  • Legurame[R]
  • (r)-(-)-1-(ethylcarbamoyl)ethyl n-phenylcarbamate
  • carbetamide (bsi,iso,ansi,wssa)
  • CARBETAMID STANDARD
  • (R)-(-)-1-(Ethylcarbamoyl)ethyl phenylcarbamate
  • Carbetamide, (2R)-1-(Ethylamino)-1-oxopropan-2-yl phenylcarbamate
  • Legruame P. M.
  • Liquide
  • RP 11561
  • D-N-ETHYL-2-(PHENYLCARBAMOYLOXY) PROPIONAMIDE
  • CARBETAMIDE
  • N-Ethyl-2-((phenylaminocarbonyl)oxy)propanamide
  • Arbetamex
  • (2R)-(-)-1-(Ethylcarbamoyl)ethyl phenylcarbamate
  • Carbetamide, (2R)-(-)-1-(Ethylamino)-1-oxoprop-2-yl phenylcarbamate
  • CARBETAMIDE PESTANAL, 250 MG ((R)-(-)-1-
  • Carbetamide@1000 μg/mL in Methanol
  • Carbetamide @100 μg/mL in MeOH
  • Propanamide, N-ethyl-2-[[(phenylamino)carbonyl]oxy]-, (2R)-
  • Carbetamide Solution in Methanol, 100μg/mL
  • Carbetamide 13C6
  • CarbetamideQ: What is Carbetamide Q: What is the CAS Number of Carbetamide
  • 561 RP
  • Caswell No. 159B
  • EPA Pesticide Chemical Code 259200
  • Refametinib Impurity 9
  • Carbetamide-d5 (phenyl-d5) in acetone
  • Carbetamide 100 μg/ml Acetonitrile
  • C11000000 Carbetamide
  • L11000000ALCarbetamidE10μg/mLin Acetonitril
  • Carbetamide in Acetonitrile
  • 16118-49-3