Diethyl (trichloromethyl)phosphonate

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Diethyl (trichloromethyl)phosphonate

Product Name: Diethyl (trichloromethyl)phosphonate
CAS No.: 866-23-9
Chemical Name: Diethyl (trichloromethyl)phosphonate
Synonyms: Ro-30658;TIMTEC-BB SBB008195;DIETHYL TRICHLOROMETHYLPHOSPHONATE;diethyl trichloromethanephosphonate;Trichloromethylphosphonic acid diethyl;Diethyl (trichloromethyl)phosphonate 97%;(Trichloromethyl)phosphonic acid diethyl;Diethyl (Trichloromethyl)phosphonate >trichloromethyl-phosphonicacidiethylester;DIETHYL (TRICHLOROMETHYL)PHOSPHONATE, 97 %
CBNumber: CB7725977
Molecular Formula: C5H10Cl3O3P
Formula Weight: 255.46
MOL File: 866-23-9.mol

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Diethyl (trichloromethyl)phosphonate Property

Boiling point:: 130-131 °C/14 mmHg (lit.)
Density: 1.362 g/mL at 25 °C (lit.)
refractive index: n20/D 1.463(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: Liquid
color: Colorless to Almost colorless
Water Solubility: 4.5g/L(25 ºC)
BRN: 1210640

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-22
Safety Statements: 26-36-60-36/37
RIDADR: UN3278
WGK Germany: 3
RTECS: TA0988000
F: 9-21
HazardClass: 6.1
PackingGroup: III
HS Code: 29319000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D4607
Product name: Diethyl (Trichloromethyl)phosphonate
Purity: >96.0%(GC)
Packaging: 5g
Price: $102
Updated: 2024/03/01

TCI Chemical

Product number: D4607
Product name: Diethyl (Trichloromethyl)phosphonate
Purity: >96.0%(GC)
Packaging: 25g
Price: $406
Updated: 2024/03/01

Alfa Aesar

Product number: 010306
Product name: Diethyl trichloromethylphosphonate, 98%
Packaging: 2g
Price: $41.65
Updated: 2024/03/01

Alfa Aesar

Product number: 010306
Product name: Diethyl trichloromethylphosphonate, 98%
Packaging: 10g
Price: $153
Updated: 2023/06/20

TRC

Product number: D444815
Product name: Diethyl (Trichloromethyl)phosphonate
Packaging: 500mg
Price: $50
Updated: 2021/12/16

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Diethyl (trichloromethyl)phosphonate Chemical Properties,Usage,Production

Chemical Properties

Colorless to Almost colorless clear liquid.

Uses

Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.

Preparation

Diethyl trichloromethylphosphonate was also obtained from diethyltrimethylsilyl phosphite in 60 % yield, and from benzyldiethyl phosphite in the presence of dibenzoyl peroxide and an ultraviolet source in a radical induced reaction in 87 % yield (compared to 26 % without the dibenzoyl peroxide).

Application

Diethyl trichloromethylphosphonate has been used as a carbenoid precursor in the reaction with Bu3B.
Diethyl trichloromethylphosphonate is used mainly in the synthesis of 1,1-dichloro-1-alkenes from carbonyl compounds via Horner–Wadsworth–Emmons (HWE)-type reactions.
Diethyl trichloromethylphosphonate reacts with olefins under Cu(I) or Fe(III) catalysis to give insertion of the olefinic substrate into one of the C–Cl bonds.

General Description

Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported. Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.

Diethyl (trichloromethyl)phosphonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diethyl (trichloromethyl)phosphonate manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Diethyl (Trichloromethyl)phosphonate 866-23-9
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Career Henan Chemical Co

Product: DIETHYL TRICHLOROMETHYLPHOSPHONATE 866-23-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-07

866-23-9, Diethyl (trichloromethyl)phosphonateRelated Search:

Aprepitant Tenofovir disoproxil fumarate Diethyl methylphosphonate CHLOROMETHYLPHOSPHONIC ACID METHYLPHOSPHONIC ACID (dichloromethyl)phosphonic acid DIETHYL (CHLOROMETHYL)PHOSPHONATE Diethyl (trichloromethyl)phosphonate

trichloro-methanephosphonicacidiethylester

trichloromethyl-phosphonicacidiethylester

TIMTEC-BB SBB008195

DIETHYL TRICHLOROMETHYLPHOSPHONATE

DIETHYL (TRICHLOROMETHYL)PHOSPHONATE, 97 %

diethyl trichloromethanephosphonate

Diethyl (trichloromethyl)phosphonate 97%

1-[ethoxy(trichloromethyl)phosphoryl]oxyethane

(Trichloromethyl)phosphonic acid diethyl

Ro-30658

Trichloromethylphosphonic acid diethyl

Trichloromethylphosphonic acid diethyl ester

Diethyl (Trichloromethyl)phosphonate &gt

Phosphonic acid, P-(trichloromethyl)-, diethyl ester

866-23-9

C2H5O2POCCl3

CH3CH2O2POCCl3

C5H10Cl3O3P

Organic Building Blocks

Phosphonates/Phosphinates

Phosphorus Compounds

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Chemical Synthesis

Organic Building Blocks

Phosphorus Compounds

Phosphonates/Phosphinates

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