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DIETHYL (CHLOROMETHYL)PHOSPHONATE

Product Name
DIETHYL (CHLOROMETHYL)PHOSPHONATE
CAS No.
3167-63-3
Chemical Name
DIETHYL (CHLOROMETHYL)PHOSPHONATE
Synonyms
NSC 67753;Diethyl (chloromethyl);DIETHYL (CHLOROMETHYL)PHOSPHONATE;[DIETHYL-(CHLORMETHYL)]-PHOSPHONAT;Diethyl chloromethylphosphonate 97%;Diethyl P-(chloromethyl)phosphonate;Diethyl (chloromethyl)phosphonate,98%;Diethyl (Chloromethyl)phosphonate >Diethyl(chloromethyl)phosphonate, 97 %;(chloromethyl)-phosphonicacidiethylester
CBNumber
CB7297881
Molecular Formula
C5H12ClO3P
Formula Weight
186.57
MOL File
3167-63-3.mol
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DIETHYL (CHLOROMETHYL)PHOSPHONATE Property

Boiling point:
109-110 °C10 mm Hg(lit.)
Density 
1.2 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.437(lit.)
Flash point:
188 °F
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
1.2
color 
Clear colorless to light yellow
BRN 
1363361
EPA Substance Registry System
Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
263613
Product name
Diethyl chloromethylphosphonate
Purity
97%
Packaging
1ml
Price
$124
Updated
2023/06/20
TCI Chemical
Product number
D4588
Product name
Diethyl (Chloromethyl)phosphonate
Purity
>98.0%(GC)
Packaging
1g
Price
$120
Updated
2024/03/01
TCI Chemical
Product number
D4588
Product name
Diethyl (Chloromethyl)phosphonate
Purity
>98.0%(GC)
Packaging
5g
Price
$400
Updated
2024/03/01
TRC
Product number
D444128
Product name
Diethyl (Chloromethyl)phosphonate
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
D444128
Product name
Diethyl (Chloromethyl)phosphonate
Packaging
500mg
Price
$90
Updated
2021/12/16
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DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to light yellow liquid

Uses

Reactant involved in:

  • Subsequent alkylation after nucleophilic substitution
  • One-pot alkylation-boration of α-haloalkylphosphonates
  • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
  • Phosphorylation leading to P-containing cyclopropanes
  • Wadsworth-Emmons reactions
  • Ring expansion of zircnacycles via carbenoid insertion

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1

DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL (CHLOROMETHYL)PHOSPHONATE Suppliers

JiNan NBT Fine Chemicals Co., Ltd
Tel
13075309700
Email
mtzhangwenjian@163.com
Country
China
ProdList
362
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Nanjing Habo Medical Technology Co., Ltd.
Tel
025-85760892 13376090521
Fax
025-85766769
Email
sales@habotech.com
Country
China
ProdList
979
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Hangzhou Disynthesis Chemical Technology Co., Ltd.
Tel
0571-88194596 15558156576
Fax
0571-88199298
Email
sales@disynchem.com
Country
China
ProdList
93
Advantage
55
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
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View Lastest Price from DIETHYL (CHLOROMETHYL)PHOSPHONATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
DIETHYL (CHLOROMETHYL)PHOSPHONATE 3167-63-3
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-08
Career Henan Chemical Co
Product
DIETHYL (CHLOROMETHYL)PHOSPHONATE 3167-63-3
Price
US $1.00/g
Min. Order
1g
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-10

3167-63-3, DIETHYL (CHLOROMETHYL)PHOSPHONATERelated Search:


  • (chloromethyl)-phosphonicacidiethylester
  • DIETHYL (CHLOROMETHYL)PHOSPHONATE
  • [DIETHYL-(CHLORMETHYL)]-PHOSPHONAT
  • Diethyl(chloromethyl)phosphonate, 97 %
  • (Chloromethyl)phosphonic acid diethyl ester
  • Diethyl (chloromethyl)phosphonate,98%
  • NSC 67753
  • Diethyl chloromethylphosphonate 97%
  • Diethyl (chloromethyl)
  • 1-[chloromethyl(ethoxy)phosphoryl]oxyethane
  • Phosphonic acid P -(chloromethyl)-diethyl ester
  • Diethyl (Chloromethyl)phosphonate &gt
  • Diethyl P-(chloromethyl)phosphonate
  • 3167-63-3
  • C5H12ClO3P
  • ClCH2POOC2H52
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Horner-Wadsworth-Emmons Reagents
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination