ChemicalBook > CAS DataBase List > DIETHYL (CHLOROMETHYL)PHOSPHONATE

DIETHYL (CHLOROMETHYL)PHOSPHONATE

Product Name
DIETHYL (CHLOROMETHYL)PHOSPHONATE
CAS No.
3167-63-3
Chemical Name
DIETHYL (CHLOROMETHYL)PHOSPHONATE
Synonyms
NSC 67753;Diethyl (chloromethyl);DIETHYL (CHLOROMETHYL)PHOSPHONATE;[DIETHYL-(CHLORMETHYL)]-PHOSPHONAT;Diethyl chloromethylphosphonate 97%;Diethyl P-(chloromethyl)phosphonate;Diethyl (chloromethyl)phosphonate,98%;Diethyl (Chloromethyl)phosphonate >Diethyl(chloromethyl)phosphonate, 97 %;(chloromethyl)-phosphonicacidiethylester
CBNumber
CB7297881
Molecular Formula
C5H12ClO3P
Formula Weight
186.57
MOL File
3167-63-3.mol
More
Less

DIETHYL (CHLOROMETHYL)PHOSPHONATE Property

Boiling point:
109-110 °C10 mm Hg(lit.)
Density 
1.2 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.437(lit.)
Flash point:
188 °F
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
1.2
color 
Clear colorless to light yellow
BRN 
1363361
EPA Substance Registry System
Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
263613
Product name
Diethyl chloromethylphosphonate
Purity
97%
Packaging
1ml
Price
$124
Updated
2023/06/20
TCI Chemical
Product number
D4588
Product name
Diethyl (Chloromethyl)phosphonate
Purity
>98.0%(GC)
Packaging
1g
Price
$120
Updated
2024/03/01
TCI Chemical
Product number
D4588
Product name
Diethyl (Chloromethyl)phosphonate
Purity
>98.0%(GC)
Packaging
5g
Price
$400
Updated
2024/03/01
TRC
Product number
D444128
Product name
Diethyl (Chloromethyl)phosphonate
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
D444128
Product name
Diethyl (Chloromethyl)phosphonate
Packaging
500mg
Price
$90
Updated
2021/12/16
More
Less

DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to light yellow liquid

Uses

Reactant involved in:

  • Subsequent alkylation after nucleophilic substitution
  • One-pot alkylation-boration of α-haloalkylphosphonates
  • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
  • Phosphorylation leading to P-containing cyclopropanes
  • Wadsworth-Emmons reactions
  • Ring expansion of zircnacycles via carbenoid insertion

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1

DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

DIETHYL (CHLOROMETHYL)PHOSPHONATE Suppliers

TCI EUROPE N.V.
Tel
--
Fax
--
Email
sales@tcieurope.be
Country
Belgium
ProdList
2200
Advantage
66
Acros Organics (Part of Thermo Fisher Scientific )
Tel
--
Fax
--
Email
fo@acros.com
Country
Belgium
ProdList
3824
Advantage
58
Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
More
Less

View Lastest Price from DIETHYL (CHLOROMETHYL)PHOSPHONATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
DIETHYL (CHLOROMETHYL)PHOSPHONATE 3167-63-3
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-08
Career Henan Chemical Co
Product
DIETHYL (CHLOROMETHYL)PHOSPHONATE 3167-63-3
Price
US $1.00/g
Min. Order
1g
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-10

3167-63-3, DIETHYL (CHLOROMETHYL)PHOSPHONATERelated Search:


  • (chloromethyl)-phosphonicacidiethylester
  • DIETHYL (CHLOROMETHYL)PHOSPHONATE
  • [DIETHYL-(CHLORMETHYL)]-PHOSPHONAT
  • Diethyl(chloromethyl)phosphonate, 97 %
  • (Chloromethyl)phosphonic acid diethyl ester
  • Diethyl (chloromethyl)phosphonate,98%
  • NSC 67753
  • Diethyl chloromethylphosphonate 97%
  • Diethyl (chloromethyl)
  • 1-[chloromethyl(ethoxy)phosphoryl]oxyethane
  • Phosphonic acid P -(chloromethyl)-diethyl ester
  • Diethyl (Chloromethyl)phosphonate &gt
  • Diethyl P-(chloromethyl)phosphonate
  • 3167-63-3
  • C5H12ClO3P
  • ClCH2POOC2H52
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Horner-Wadsworth-Emmons Reagents
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination