ChemicalBook > CAS DataBase List > 6-Methoxy-2-methylpyridin-3-amine

6-Methoxy-2-methylpyridin-3-amine

Product Name
6-Methoxy-2-methylpyridin-3-amine
CAS No.
52090-56-9
Chemical Name
6-Methoxy-2-methylpyridin-3-amine
Synonyms
5-AMINO-2-METHOXY-6-PICOLINE;3-AMINO-6-METHOXY-2-PICOLINE;6-Methoxy-2-methyl-3-pyridinamine;3-Pyridinamine,6-methoxy-2-methyl;2-Methyl-6-methoxypyridin-3-amine;6-Methoxy-2-methyl-3-pyridylamine;6-methoxy-2-methylpyridin-3-amine;2-Methyl-3-amine-6-methoxypyridine;2-Methoxy-5-amino-6-methylpyridine;6-Methoxy-2-methyl-pyridin-3-ylamine
CBNumber
CB7740231
Molecular Formula
C7H10N2O
Formula Weight
138.17
MOL File
52090-56-9.mol
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6-Methoxy-2-methylpyridin-3-amine Property

Boiling point:
260.0±35.0 °C(Predicted)
Density 
1.103±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
5.05±0.10(Predicted)
Appearance
Light yellow to brown Solid-Liquid Mixture
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M218888
Product name
6-Methoxy-2-methylpyridin-3-amine
Packaging
100mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
X3021
Product name
3-Amino-6-methoxy-2-methylpyridine
Packaging
1g
Price
$63
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA55483
Product name
3-Amino-6-methoxy-2-methylpyridine
Packaging
1g
Price
$180
Updated
2021/12/16
Apolloscientific
Product number
OR345360
Product name
3-Amino-6-methoxy-2-methylpyridine
Purity
98%
Packaging
5g
Price
$192
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-613
Product name
3-Amino-6-methoxy-2-methylpyridine
Purity
98%
Packaging
5G
Price
$212
Updated
2021/12/16
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6-Methoxy-2-methylpyridin-3-amine Chemical Properties,Usage,Production

Synthesis

5467-69-6

52090-56-9

6-Methoxy-2-methyl-3-nitropyridine (2 g, 0.012 mol) was used as starting material, which was dissolved in H2O/MeOH (1:1, 40 mL) mixed solvent. Subsequently, NH4Cl (2.2 g, 3.5 eq.) and iron powder (2.3 g, 3.5 eq.) were added to the solution. The reaction mixture was stirred at 80 °C for 16 hours. After completion of the reaction, the iron powder was removed by filtration and the filtrate was washed with MeOH. The MeOH was removed from the filtrate by evaporation, diluted with H2O, and then the aqueous phase was extracted with EtOAc (3 x 50 mL). The organic phases were combined and dried with anhydrous Na2SO4. The desiccant was removed by filtration and the solvent was evaporated to dryness to give 2-methoxy-5-amino-6-methylpyridine (1.35 g, 81% yield) as a brown oil. Its nuclear magnetic resonance hydrogen spectrum (1H NMR, CDCl3) data were as follows: δ 6.9 (d, 1H), 6.4 (d, 1H), 3.8 (s, 3H), 2.33 (s, 3H).

References

[1] Patent: WO2004/62665, 2004, A1. Location in patent: Page/Page column 45
[2] Journal of the Chemical Society, <1954> 2448, 2452,

6-Methoxy-2-methylpyridin-3-amine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 6-Methoxy-2-methylpyridin-3-amine manufacturers

Dideu Industries Group Limited
Product
3-AMINO-6-METHOXY-2-PICOLINE 52090-56-9
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-12-06
Career Henan Chemical Co
Product
3-AMINO-6-METHOXY-2-PICOLINE 52090-56-9
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2019-12-26

52090-56-9, 6-Methoxy-2-methylpyridin-3-amineRelated Search:


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