Uses
ChemicalBook > CAS DataBase List > 2,2'-(BENZYLIMINO)DIETHANOL

2,2'-(BENZYLIMINO)DIETHANOL

Uses
Product Name
2,2'-(BENZYLIMINO)DIETHANOL
CAS No.
101-32-6
Chemical Name
2,2'-(BENZYLIMINO)DIETHANOL
Synonyms
BUTTPARK 145\50-27;benzyldiethanolamine;N-BENZYLDIETHANOLAMINE;2,2’-(benzylimino)di-ethano;N-Benzyldiethanolamine 95+%;2,2'-(Benzylimino)diethanol;2,2'-(Benzylimino)diethanol;N-Benzyldiethanolamine;benzylbis(2-hydroxyethyl)amine;2,2'-(Benzylimino)bis(ethanol)
CBNumber
CB7745559
Molecular Formula
C11H17NO2
Formula Weight
195.26
MOL File
101-32-6.mol
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2,2'-(BENZYLIMINO)DIETHANOL Property

Melting point:
196.5 °C(Solv: benzene (71-43-2))
Boiling point:
226°C(lit.)
Density 
1.09
refractive index 
1.5370 to 1.5410
storage temp. 
Inert atmosphere,Room Temperature
form 
clear liquid
pka
14.39±0.10(Predicted)
color 
Colorless to Yellow to Orange
InChI
InChI=1S/C11H17NO2/c13-8-6-12(7-9-14)10-11-4-2-1-3-5-11/h1-5,13-14H,6-10H2
InChIKey
MIZIOHLLYXVEHJ-UHFFFAOYSA-N
SMILES
N(CCO)(CCO)CC1=CC=CC=C1
CAS DataBase Reference
101-32-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
RTECS 
KJ7538000
HazardClass 
IRRITANT
HS Code 
2922190090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5081
Product name
N-Benzyldiethanolamine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$121
Updated
2025/07/31
TRC
Product number
B230773
Product name
2,2''-(Benzylazanediyl)diethanol
Packaging
50mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
4756-1-V7
Product name
N,N-Bis(2-hydroxyethyl)benzylamine
Purity
95.0%
Packaging
1g
Price
$48
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB36398
Product name
N-Benzyldiethanolamine
Packaging
1g
Price
$80
Updated
2021/12/16
AK Scientific
Product number
0368AA
Product name
2-[2-Hydroxyethyl(phenylmethyl)amino]ethanol
Packaging
1g
Price
$91
Updated
2021/12/16
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2,2'-(BENZYLIMINO)DIETHANOL Chemical Properties,Usage,Production

Uses

2,2'-(Benzylazanediyl)diethanol is a useful research chemical.

Synthesis

100-39-0

111-42-2

101-32-6

General procedure for the synthesis of 2,2-(benzylimino)diethanol from benzyl bromide and diethanolamine: K2CO3 (8.65 g, 62.58 mmol) and benzyl bromide (2.96 g, 25 mmol) were added to anhydrous acetone (65 mL) followed by diethanolamine (2.63 g, 53.08 mmol). The reaction mixture was heated to reflux and the reaction was continued overnight. After completion of the reaction, the white suspension obtained was filtered and the solvent was removed by evaporation to obtain 5.6 g of yellow liquid. The liquid was dissolved in dichloromethane (DCM) and washed with deionized water. The organic layer was dried over anhydrous sodium sulfate and concentrated in vacuum to give the final 2,2-(benzylimino)diethanol (4.88 g, 100% yield). The product was analyzed by HPLC-MS (Method A): retention time 1.14 min; ESI-MS m/z 196 ([M+H]+).

References

[1] Inorganic Chemistry, 2012, vol. 51, # 19, p. 10384 - 10393,10
[2] Patent: WO2017/16669, 2017, A1. Location in patent: Page/Page column 201
[3] Journal of Medicinal Chemistry, 2003, vol. 46, # 12, p. 2376 - 2396
[4] Patent: EP970046, 2003, B1. Location in patent: Page 45-46
[5] Patent: US6342508, 2002, B1. Location in patent: Page column 58-59

2,2'-(BENZYLIMINO)DIETHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,2'-(BENZYLIMINO)DIETHANOL manufacturers

Career Henan Chemical Co
Product
2,2'-(BENZYLIMINO)DIETHANOL 101-32-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-08

101-32-6, 2,2'-(BENZYLIMINO)DIETHANOLRelated Search:


  • BUTTPARK 145\50-27
  • 2-[BENZYL(2-HYDROXYETHYL)AMINO]-1-ETHANOL
  • N-BENZYLDIETHANOLAMINE
  • N,N-BIS(HYDROXYETHYL)-BENZYLAMINE
  • 2,2’-((phenylmethyl)imino)bis-ethano
  • 2,2’-(benzylimino)di-ethano
  • benzylbis(2-hydroxyethyl)amine
  • benzyldiethanolamine
  • 2-[benzyl(2-hydroxyethyl)amino]ethan-1-ol
  • 2,2'-[(phenylmethyl)imino]bisethanol
  • N,N-Bis(2-hydroxyethyl)benzylamine
  • N-Benzyldiethanolamine 95+%
  • N,N-Bis(β-chloroethyl)benzylamine hydrochloride
  • 2-[benzyl(2-hydroxyethyl)amino]ethanol
  • 2,2'-(Benzylimino)bis(ethanol)
  • 2-[2-hydroxyethyl(phenylmethyl)amino]ethanol
  • N,N-Bis(2-hydroxyethyl)benzylamine 95+%
  • 2-[Benzyl(2-hydroxyethyl)amino]ethan-1-ol, 2,2'-(Benzylimino)diethanol, N-Benzyldiethanolamine
  • 2,2'-(benzylazanediyl)diethanol
  • Ethanol, 2,2'-[(phenylMethyl)iMino]bis-
  • 2,2'-(Benzylimino)diethanol 95+%
  • 2-[Benzyl(2-hydroxyethyl)amino]ethan-1-ol, N,N-Bis(2-hydroxyethyl)benzylamine, N-Benzyldiethanolamine
  • <i>N</i>-Benzyldiethanolamine
  • 2,2'-(Benzylimino)diethanol
  • 2,2’-(Benzylazanediyl)diethanol
  • 2-(2-hydroxyethyl (phenylmethyl) amino] eth
  • 2,2'-(Benzylimino)diethanol
  • 101-32-6
  • C11H156Cl3N