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Ethyltriphenylphosphonium bromide

Product Name
Ethyltriphenylphosphonium bromide
CAS No.
1530-32-1
Chemical Name
Ethyltriphenylphosphonium bromide
Synonyms
TEP;Ethyl triphenyl phosphine bromide;ethyltriphenylphosphanium bromide;AD182;ETPPB;ETPPBR;Ethyl triphenyl pho;TEP (oniuM coMpound);Antioxidants Impurity 15;Ethyltriphenylbromophosphine
CBNumber
CB7752854
Molecular Formula
C20H20BrP
Formula Weight
371.25
MOL File
1530-32-1.mol
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Ethyltriphenylphosphonium bromide Property

Melting point:
203-205 °C(lit.)
Boiling point:
240℃[at 101 325 Pa]
Density 
1.38[at 20℃]
vapor pressure 
0-0.1Pa at 20-25℃
Flash point:
200 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
174g/l soluble
form 
Crystalline Powder
color 
White to off-white
Water Solubility 
120 g/L (23 ºC)
Sensitive 
Hygroscopic
BRN 
3599630
InChIKey
JHYNXXDQQHTCHJ-UHFFFAOYSA-M
LogP
-0.69--0.446 at 35℃
CAS DataBase Reference
1530-32-1(CAS DataBase Reference)
EPA Substance Registry System
Phosphonium, ethyltriphenyl-, bromide (1530-32-1)
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Safety

Hazard Codes 
Xn,N,Xi
Risk Statements 
22-51/53-36/37/38-21/22
Safety Statements 
61-36/37/39-26-36
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
E50604
Product name
Ethyltriphenylphosphonium bromide
Purity
99%
Packaging
25g
Price
$44.7
Updated
2024/03/01
Sigma-Aldrich
Product number
E50604
Product name
Ethyltriphenylphosphonium bromide
Purity
99%
Packaging
100g
Price
$133
Updated
2024/03/01
TCI Chemical
Product number
E0382
Product name
Ethyltriphenylphosphonium Bromide
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
E0382
Product name
Ethyltriphenylphosphonium Bromide
Purity
>98.0%(HPLC)(T)
Packaging
100g
Price
$74
Updated
2024/03/01
Alfa Aesar
Product number
B23096
Product name
Ethyltriphenylphosphonium bromide, 98+%
Packaging
25g
Price
$31.65
Updated
2024/03/01
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Ethyltriphenylphosphonium bromide Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystalline powder

Uses

suzuki reaction

Uses

Ethyltriphenylphosphonium Bromide is used as a wittig reagent. Ethyltriphenylphosphonium Bromide and other phosphonium salts show antiviral activity.

Uses

Ethyltriphenylphosphonium Bromide (ETPB) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.

  1. Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination.
  2. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions.
  3. it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers.
  4. Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

Uses

PTC catalyst

Flammability and Explosibility

Not classified

Purification Methods

Recrystallise it from H2O and dry it in high vacuum at 100o. IR has bands at 1449, 1431 and 997cm-1 . [Wittig & Wittenberg Justus Liebigs Ann Chem 606 1 1957, Bergmann & Dusza J Org Chem 23 1245 1958, Beilstein 16 IV 982.]

Ethyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyltriphenylphosphonium bromide Suppliers

Anhui Jinshan Chemical Technology Co., Ltd.
Tel
16782111888
Fax
0556-5202073
Email
1151625602@qq.com
Country
China
ProdList
7
Advantage
58
Unichem Company Ltd.(China)
Tel
0510-0510-82328705 13771137389
Fax
86-510-82328706
Email
webmaster@unionchems.com
Country
China
ProdList
28
Advantage
58
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.
Tel
133-96369453 18678026865
Fax
0536-2101172
Email
sdfantai@163.com
Country
China
ProdList
854
Advantage
58
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
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58
Shanghai Chang-Gen Chemical Technology Co., Ltd.
Tel
021-69106814 13917161715
Email
3007500651@qq.com
Country
China
ProdList
80
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60
Weifang Runzhong Fine Chemical Co., LTD
Tel
18653686003
Email
sq@runzhongchem.com
Country
China
ProdList
71
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58
BeiJing Greenchem Technology Co.,Ltd.
Tel
131-21959385 15640741633
Fax
010-62925455
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
269
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Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-83946278 13820503911
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
969
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
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View Lastest Price from Ethyltriphenylphosphonium bromide manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ethyltriphenylphosphonium Bromid 1530-32-1
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/Month
Release date
2024-04-29
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Ethyltriphenylphosphonium bromide 1530-32-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Weibang Biotechnology Co., Ltd
Product
Ethyltriphenylphosphonium bromide 1530-32-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-24

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