Ethyltriphenylphosphonium bromide

Product Name: Ethyltriphenylphosphonium bromide
CAS No.: 1530-32-1
Chemical Name: Ethyltriphenylphosphonium bromide
Synonyms: TEP;Ethyl triphenyl phosphine bromide;ethyltriphenylphosphanium bromide;AD182;ETPPB;ETPPBR;Ethyl triphenyl pho;TEP (oniuM coMpound);Antioxidants Impurity 15;Ethyltriphenylbromophosphine
CBNumber: CB7752854
Molecular Formula: C20H20BrP
Formula Weight: 371.25
MOL File: 1530-32-1.mol

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Ethyltriphenylphosphonium bromide Property

Melting point:: 203-205 °C(lit.)
Boiling point:: 240℃[at 101 325 Pa]
Density: 1.38[at 20℃]
vapor pressure: 0-0.1Pa at 20-25℃
Flash point:: 200 °C
storage temp.: Inert atmosphere,Room Temperature
solubility: 174g/l soluble
form: Crystalline Powder
color: White to off-white
Water Solubility: 120 g/L (23 ºC)
Sensitive: Hygroscopic
BRN: 3599630
InChIKey: JHYNXXDQQHTCHJ-UHFFFAOYSA-M
LogP: -0.69--0.446 at 35℃
CAS DataBase Reference: 1530-32-1(CAS DataBase Reference)
EPA Substance Registry System: Phosphonium, ethyltriphenyl-, bromide (1530-32-1)

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Safety

Hazard Codes: Xn,N,Xi
Risk Statements: 22-51/53-36/37/38-21/22
Safety Statements: 61-36/37/39-26-36
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29310095

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: E50604
Product name: Ethyltriphenylphosphonium bromide
Purity: 99%
Packaging: 25g
Price: $44.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: E50604
Product name: Ethyltriphenylphosphonium bromide
Purity: 99%
Packaging: 100g
Price: $133
Updated: 2024/03/01

TCI Chemical

Product number: E0382
Product name: Ethyltriphenylphosphonium Bromide
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $29
Updated: 2024/03/01

TCI Chemical

Product number: E0382
Product name: Ethyltriphenylphosphonium Bromide
Purity: >98.0%(HPLC)(T)
Packaging: 100g
Price: $74
Updated: 2024/03/01

Alfa Aesar

Product number: B23096
Product name: Ethyltriphenylphosphonium bromide, 98+%
Packaging: 25g
Price: $31.65
Updated: 2024/03/01

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Ethyltriphenylphosphonium bromide Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystalline powder

Uses

suzuki reaction

Uses

Ethyltriphenylphosphonium Bromide is used as a wittig reagent. Ethyltriphenylphosphonium Bromide and other phosphonium salts show antiviral activity.

Uses

Ethyltriphenylphosphonium Bromide (ETPB) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.

Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination.
It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions.
it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers.
Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

Uses

PTC catalyst

Flammability and Explosibility

Not classified

Purification Methods

Recrystallise it from H2O and dry it in high vacuum at 100o. IR has bands at 1449, 1431 and 997cm-1 . [Wittig & Wittenberg Justus Liebigs Ann Chem 606 1 1957, Bergmann & Dusza J Org Chem 23 1245 1958, Beilstein 16 IV 982.]

Ethyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyltriphenylphosphonium bromide Suppliers

Americas 1 Belgium 2 Canada 4 China 496 Cyprus 1 Czech Republic 1 Europe 4 Germany 9 India 83 Italy 1 Japan 8 New Zealand 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 Turkey 1 United Kingdom 17 United States 51 Global 685

Anhui Jinshan Chemical Technology Co., Ltd.

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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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View Lastest Price from Ethyltriphenylphosphonium bromide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Ethyltriphenylphosphonium bromide 1530-32-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-23

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Ethyltriphenylphosphonium Bromid 1530-32-1
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000kg/Month
Release date: 2024-04-29

Hebei Weibang Biotechnology Co., Ltd

Product: Ethyltriphenylphosphonium bromide 1530-32-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-24

1530-32-1, Ethyltriphenylphosphonium bromideRelated Search:

DICHLOROTRIPHENYLPHOSPHORANE Triphenylphosphine hydrobromide Methyltriphenylphosphonium bromide Ethylmagnesium bromide PHENYLMAGNESIUM BROMIDE Tris(triphenylphosphine)rhodiu Vecuronium bromide Tetraphenylphosphonium bromide Dimidium bromide Tetraethylammonium bromide Ethyltriphenylphosphonium iodide Triphenylphosphine Allyl bromide Rocuronium bromide Triphenylphosphine oxide Sodium bromate Ethidium bromide Ethyltriphenylphosphonium acetate

Ethyltriphenylbromophosphine

ethyltriphenyl-phosphoniubromide

Ethyl(trisphenyl)phosphonium bromide

Ethyl triphenyl phosphoniuM broMide (ETPB)

TEP (oniuM coMpound)

ETHYLTRIPHENYLPHOSPHONIUM BRIMIDE

ethyl triphenylphosphoiuum bromide

ETHYLTRIPHENYLPHOSPHONIUM BROMIDE 99+%

Phosphonium, ethyltriphenyl-, bromide

ETPPBr: Ethyltriphenylphosphonium Bromide

Ethyltriphenylphosphonium bromide, 98+%

ETHYLTRIPHENYLPHOSPHONIUM BROMIDE pure

ETHYL TRIPHENYL PHOSPHENIUM BROMID

Ethyl triphenylphosphonium Bromide(ETPPBr)

Ethyl triphenylphosphonium bromidedisc 6/01

EthyltriphenylphosphoniuM broMide(T

Ethyl triphenyl pho

Ethyl(trisphenyl)phosphonium bromide 98%

AD182

EthyltriphenylphosphoniuM broMide(TPEPB)

EthyltriphenylphosphoniuM broM

EthyltriphenylphosphoniuM broMid

Ethyl threephosphoniuM broMide

PhosphoniuM,ethyltriphenyl-, broMide (1:1)

EthyltriphenylphosphoniuM BroMide, 97+%

ETHYLTRIPHENYLPHOSPHONIUM BROMIDE FOR SY

Three phenyl ethyl broMide phosphorus

ETPPBR

ETHYLTRIPHENYLPHOSPHONIUM BROMIDE

TEP

TRIPHENYLETHYLPHOSPHONIUM BROMIDE

ETPPB

Antioxidants Impurity 15

EthyltriphenylphosphoniumBromide&gt

Ethyl triphenyl phosphine bromide

Ethyl(triphenyl)phosphonium bromideCAS 1530-32-1

Ethyl triphenyl phosphonium Bromide Solid

Ethyl Triphenyl Phosphonium Bromide (ETPBB)

ethyltriphenylphosphanium bromide

thyltriphenylphosphonium bromide

Ethyltriphenylphosphonium bromide (6CI, 7CI)

Ethyl triphenyl phosphorus bromide

Ethyltriphenylphosphonium Bromide (ETPBr)

Visomitin Impurity 3 Bromide

1530-32-1

986-33-3

530-32-1

CH3CH2PC6H53Br

C6H53PC2H5Br

C2H5C6H53PBr

C20H20PBr

C20H20BrP

Synthetic Reagents

Olefination

Wittig Reaction

Phosphonium Compounds

Wittig & Horner-Emmons Reaction

C-C Bond Formation