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3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER

Product Name
3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER
CAS No.
21911-84-2
Chemical Name
3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER
Synonyms
Methyl 3-(phenylamino);methyl 3-anilinopropanoate;methyl N-phenyl-beta-alaninate;N-Phenyl-β-alanine methyl ester;ethyl 3-(phenylamino)propanoate;N-phenyl-b-Alanine, methyl ester;METHYL 3-(PHENYLAMINO)PROPANOATE;N-Phenyl-beta-alanine Methyl Ester;β-Alanine, N-phenyl-, methyl ester;3-Anilinopropionic acid methyl ester
CBNumber
CB7763607
Molecular Formula
C10H13NO2
Formula Weight
179.22
MOL File
21911-84-2.mol
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3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER Property

Melting point:
37.6-38.3 °C
Boiling point:
125-126 °C(Press: 3 Torr)
Density 
1.107±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
4.32±0.50(Predicted)
Appearance
White to light yellow Solid
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Safety

HazardClass 
IRRITANT
HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M339258
Product name
Methyl3-(Phenylamino)propanoate
Packaging
50mg
Price
$60
Updated
2021/12/16
TRC
Product number
M339258
Product name
Methyl3-(Phenylamino)propanoate
Packaging
10mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
038621
Product name
Methyl 3-anilinopropanoate
Packaging
500mg
Price
$48
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0010833
Product name
METHYL-3-(PHENYLAMINO)PROPANOATE
Purity
95.00%
Packaging
1G
Price
$720
Updated
2021/12/16
Matrix Scientific
Product number
038621
Product name
Methyl 3-anilinopropanoate
Packaging
1g
Price
$74
Updated
2021/12/16
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3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

292638-85-8

62-53-3

21911-84-2

The reaction of 1 mmol of aniline with 1 mmol of activated α,β-unsaturated compound (Michael receptor, cas:292638-85-8) in appropriate solvent was catalyzed by 5 mol% (0.1 mmol) stabilized cobalt nanoparticles with stirring. The reaction progress was monitored by thin layer chromatography (TLC, unfolding agent: hexane/ethyl acetate). Upon completion of the reaction, dichloromethane was added to the reaction mixture, the cobalt catalyst was separated and recovered using an applied magnetic field, and the remaining reaction mixture was decanted into another flask. Subsequently, the solvent was removed by rotary evaporation to give the crude product. The crude product was further purified by silica gel column chromatography with the eluent being a mixed ethyl acetate/petroleum ether solvent. The structure of the final product was confirmed by 1H NMR, 13C NMR and mass spectrometry.

References

[1] Synthetic Communications, 2009, vol. 39, # 6, p. 1109 - 1119
[2] RSC Advances, 2016, vol. 6, # 98, p. 95951 - 95956
[3] Monatshefte fur Chemie, 2008, vol. 139, # 9, p. 1041 - 1047
[4] Inorganic Chemistry Communications, 2015, vol. 53, p. 92 - 96
[5] Tetrahedron, 2013, vol. 69, # 6, p. 1712 - 1716

3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER Suppliers

J & K SCIENTIFIC LTD.
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China
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Shanghai Topbiochem Technology Co., Ltd
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View Lastest Price from 3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co
Product
3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER 21911-84-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-23

21911-84-2, 3-PHENYLAMINO-PROPIONIC ACID METHYL ESTERRelated Search:


  • METHYL 3-(PHENYLAMINO)PROPANOATE
  • 3-PHENYLAMINO-PROPIONIC ACID METHYL ESTER
  • methyl N-phenyl-beta-alaninate
  • methyl 3-anilinopropanoate
  • 3-Anilinopropanoic acid methyl ester
  • 3-Anilinopropionic acid methyl ester
  • N-Phenyl-β-alanine methyl ester
  • 3-(phenylamino)propanoic acid methyl ester
  • ethyl 3-(phenylamino)propanoate
  • Methyl 3-(phenylamino)
  • N-phenyl-b-Alanine, methyl ester
  • N-Phenyl-beta-alanine Methyl Ester
  • beta-Alanine, N-phenyl-, methyl ester
  • β-Alanine, N-phenyl-, methyl ester
  • 21911-84-2