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3-PHENYLAMINO-PROPIONIC ACID

Product Name
3-PHENYLAMINO-PROPIONIC ACID
CAS No.
5652-38-0
Chemical Name
3-PHENYLAMINO-PROPIONIC ACID
Synonyms
NSC 54626;3-(Phenylamino);N-Phenyl-b-alanine;RARECHEM AL BO 0162;β-Alanine, N-phenyl-;N-PHENYL-BETA-ALANINE;3-Anilinopropionic acid;3-Anilinopropanoic acid;3-Phenylammoniopropanoate;N-(2-Carboxyethyl)aniline
CBNumber
CB6740092
Molecular Formula
C9H11NO2
Formula Weight
165.19
MOL File
5652-38-0.mol
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3-PHENYLAMINO-PROPIONIC ACID Property

Melting point:
218-221℃
Boiling point:
364.6±25.0 °C(Predicted)
Density 
1.209±0.06 g/cm3 (20 ºC 760 Torr)
storage temp. 
2-8°C(protect from light)
pka
3.58±0.12(Predicted)
Appearance
Light yellow to yellow Solid
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Safety

HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
P319638
Product name
3-(Phenylamino)propanoicAcid
Packaging
100mg
Price
$40
Updated
2021/12/16
TRC
Product number
P319638
Product name
3-(Phenylamino)propanoicAcid
Packaging
1g
Price
$140
Updated
2021/12/16
ChemScene
Product number
CS-W021779
Product name
3-(Phenylamino)propanoicacid
Purity
97.16%
Packaging
1g
Price
$22
Updated
2021/12/16
Matrix Scientific
Product number
126965
Product name
3-(Phenylamino)propanoicacid
Purity
>95%
Packaging
1g
Price
$108
Updated
2021/12/16
ChemScene
Product number
CS-W021779
Product name
3-(Phenylamino)propanoicacid
Purity
97.16%
Packaging
5g
Price
$109
Updated
2021/12/16
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3-PHENYLAMINO-PROPIONIC ACID Chemical Properties,Usage,Production

Uses

3-(Phenylamino)propanoic Acid is used in the preparation of spiroheterocycles as filamin A (FLNA) binding antiinflammatory analgesics.

Synthesis

57-57-8

62-53-3

5652-38-0

The general procedure for the synthesis of 3-anilinopropionic acid from β-propiolactone and aniline was as follows: aniline (5.00 g) was dissolved in acetonitrile (30 ml) and heated to reflux. Subsequently, β-propiolactone (3.36 ml) was added slowly and dropwise. The reflux condition was maintained and the reaction was continued for 3 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was dissolved in aqueous sodium hydroxide solution and the aqueous phase was washed with ether. The pH of the aqueous phase was adjusted to 4-5 with hydrochloric acid and subsequently extracted with ether. The organic layers were combined, washed sequentially with water and saturated saline, and dried over anhydrous sodium sulfate. After filtration, the organic phase was concentrated under reduced pressure. Finally, the residue was purified by silica gel column chromatography (eluent ratio of chloroform:methanol=9:1) to afford the target product 3-anilinopropionic acid (2.08 g, 23% yield).

References

[1] Patent: EP1452526, 2004, A1. Location in patent: Page 105
[2] Journal of the American Chemical Society, 1951, vol. 73, p. 3168,3171
[3] Patent: US2008/153871, 2008, A1. Location in patent: Page/Page column 24

3-PHENYLAMINO-PROPIONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-PHENYLAMINO-PROPIONIC ACID Suppliers

Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
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info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shanghai Sunway Pharmaceutical Technology Co., Ltd
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18270980682
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021 51613951
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mlcheng@sunwaypharm.cn
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China
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8669
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57
Taizhou Tongxin Bio-Tech Co., Ltd
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Cool Pharm, Ltd
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50966098
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China
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12346
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Shanghai GaoDao Pharmaceutical Co., Ltd.
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021-15001867143 15001867143
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909
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JW & Y Pharmlab Co., Ltd.
Tel
021-64340559 13651849907;
Fax
021- 64345308
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China
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12000
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Amadis Chemical Company Limited
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China
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131957
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Amatek Scientific Co. Ltd.
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China
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28785
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Aikon International Limited
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025-58859352 18068836627
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02557626880
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sales01@aikonchem.com
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China
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Shanghai Yinlin Pharmaceutical Co., Ltd.
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021-33690831
Fax
021-33690831
Email
813300142@qq.com
Country
China
ProdList
305
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58
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View Lastest Price from 3-PHENYLAMINO-PROPIONIC ACID manufacturers

Career Henan Chemical Co
Product
3-PHENYLAMINO-PROPIONIC ACID 5652-38-0
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08