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(2-AMINO-6-CHLORO-PHENYL)-METHANOL

Product Name
(2-AMINO-6-CHLORO-PHENYL)-METHANOL
CAS No.
39885-08-0
Chemical Name
(2-AMINO-6-CHLORO-PHENYL)-METHANOL
Synonyms
2-Chloro-6-aminobenzyl alcohol;2-Amino-6-chlorobenzyl alcohol;2-Amino-6-chlorobenzenemethanol;Benzenemethanol,2-amino-6-chloro-;(2-AMINO-6-CHLORO-PHENYL)-METHANOL
CBNumber
CB7843473
Molecular Formula
C7H8ClNO
Formula Weight
157.6
MOL File
39885-08-0.mol
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(2-AMINO-6-CHLORO-PHENYL)-METHANOL Property

Melting point:
76-78℃
Boiling point:
324.2±27.0 °C(Predicted)
Density 
1.341±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
solid
pka
13.84±0.10(Predicted)
color 
White to off-white
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Safety

HS Code 
2922190090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Apolloscientific
Product number
OR931392
Product name
(2-Amino-6-chlorophenyl)methanol
Purity
97%
Packaging
5g
Price
$73
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0068986
Product name
(2-AMINO-6-CHLORO-PHENYL)-METHANOL
Purity
95.00%
Packaging
5MG
Price
$502.81
Updated
2021/12/16
AK Scientific
Product number
5253AB
Product name
(2-Amino-6-chlorophenyl)methanol
Packaging
1g
Price
$127
Updated
2021/12/16
AK Scientific
Product number
5253AB
Product name
(2-Amino-6-chlorophenyl)methanol
Packaging
5g
Price
$282
Updated
2021/12/16
Chemenu
Product number
CM101484
Product name
Benzenemethanol,2-amino-6-chloro-
Purity
95+%
Packaging
5g
Price
$316
Updated
2021/12/16
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(2-AMINO-6-CHLORO-PHENYL)-METHANOL Chemical Properties,Usage,Production

Synthesis

2148-56-3

39885-08-0

General procedure for the synthesis of (2-amino-6-chlorophenyl)-methanol from 2-amino-6-chlorobenzoic acid: 50.0 g (286 mmol) of 2-amino-6-chlorobenzoic acid was dissolved in 300 mL of anhydrous tetrahydrofuran (THF). The resulting solution was cooled to 0-10°C, followed by the slow addition of 450 mL of 1.0 M lithium aluminum hydride in THF solution. The reaction mixture was gradually warmed to room temperature and stirred continuously at room temperature overnight. Upon completion of the reaction, 300 mL of 10% aqueous sodium hydroxide solution was carefully added to the mixture to quench the reaction. The organic phase was separated and washed sequentially with ethyl acetate and water. The organic phase was dried over anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent, yielding 42 g (270 mmol, 95% yield) of a yellow solid product, which could be used without further purification.

References

[1] Patent: CN107722059, 2018, A. Location in patent: Paragraph 0094; 0097; 0098; 0099
[2] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 19, p. 5810 - 5831
[3] Journal of Medicinal Chemistry, 2005, vol. 48, # 6, p. 2080 - 2092
[4] Patent: US2018/105527, 2018, A1. Location in patent: Paragraph 0783-0785
[5] Patent: WO2006/10142, 2006, A2. Location in patent: Page/Page column 70

(2-AMINO-6-CHLORO-PHENYL)-METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-AMINO-6-CHLORO-PHENYL)-METHANOL Suppliers

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China
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View Lastest Price from (2-AMINO-6-CHLORO-PHENYL)-METHANOL manufacturers

Career Henan Chemical Co
Product
(2-AMINO-6-CHLORO-PHENYL)-METHANOL 39885-08-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-03