ChemicalBook > CAS DataBase List > 2-Butyne

2-Butyne

Product Name
2-Butyne
CAS No.
503-17-3
Chemical Name
2-Butyne
Synonyms
Butyne;2-BUTYNE;But-2-yne;CROTONYLENE;2-Butyne>2-BUTYNE 98%;2-Butyne,98%;CH3CequivCCH3;2-Butyne(delete);CROTONYLENE(DOT)
CBNumber
CB7853683
Molecular Formula
C4H6
Formula Weight
54.09
MOL File
503-17-3.mol
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2-Butyne Property

Melting point:
-32 °C
Boiling point:
27 °C(lit.)
Density 
0.691 g/mL at 25 °C(lit.)
vapor pressure 
11.47 psi ( 20 °C)
refractive index 
n20/D 1.393(lit.)
Flash point:
-25 °C
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
0.691
color 
Clear colorless to light yellow
Water Solubility 
Not miscible in water.
BRN 
1361340
InChI
InChI=1S/C4H6/c1-3-4-2/h1-2H3
InChIKey
XNMQEEKYCVKGBD-UHFFFAOYSA-N
SMILES
CC#CC
CAS DataBase Reference
503-17-3(CAS DataBase Reference)
EPA Substance Registry System
2-Butyne (503-17-3)
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Safety

Hazard Codes 
F+,Xi
Risk Statements 
12-36/37/38
Safety Statements 
16-26-36
RIDADR 
UN 1144 3/PG 1
WGK Germany 
3
RTECS 
GQ7210000
TSCA 
Yes
HazardClass 
3
PackingGroup 
I
HS Code 
29012990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
254339
Product name
2-Butyne
Purity
99%
Packaging
5g
Price
$62.51
Updated
2025/07/31
Sigma-Aldrich
Product number
254339
Product name
2-Butyne
Purity
99%
Packaging
25g
Price
$223
Updated
2025/07/31
TCI Chemical
Product number
B0951
Product name
2-Butyne
Purity
>97.0%(GC)
Packaging
5mL
Price
$61
Updated
2025/07/31
GFS CHEMICALS
Product number
80281
Product name
2-Butyne, 98%
Packaging
25g
Price
$187.81
Updated
2021/12/16
Oakwood
Product number
117205
Product name
2-Butyne
Purity
97%
Packaging
5g
Price
$35
Updated
2021/12/16
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2-Butyne Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

2-Butyne is used to synthesize alkylated hydroquinones in the total synthesis of Vitamin E. It is also used as pharmaceutical intermediates.

General Description

A clear colorless liquid with a petroleum-like odor. Flash point below -4°F. Boiling point 81°F. Less dense than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

2-Butyne may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

Hazard

Flammable, dangerous fire risk. Moderate explosion hazard.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Safety Profile

A simple asphyxiant. Very dangerous fire hazard when exposed to heat or flame; can react with oxidzing materials. Moderately explosive in the form of vapor when exposed to heat or flame. To fight fire, use foam, CO2, dry chemicals. See also ACETYLENE COMPOUNDS and ARGON (for a description of simple asphyxiants).

Purification Methods

Stand it over sodium for 24hours, then fractionally distil it under reduced pressure into a cooled receiver. [Beilstein 1 IV 971.]

2-Butyne Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Butyne Suppliers

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