methyl 4-bromo-3,5-dimethoxybenzoate

Product Name: methyl 4-bromo-3,5-dimethoxybenzoate
CAS No.: 26050-64-6
Chemical Name: methyl 4-bromo-3,5-dimethoxybenzoate
Synonyms: Methyl 3,5-dimethoxy-4-bromobenzoate;Methyl 4-bromo-3,5-dimethoxybenzoate 95+%;4-BROMO-3,5-DIMETHOXYBENZOIC ACID METHY ESTER;3,5-Dimethoxy-4-bromobenzoic acid methyl ester;Benzoic acid, 4-bromo-3,5-dimethoxy-, methyl ester
CBNumber: CB7896080
Molecular Formula: C10H11BrO4
Formula Weight: 275.1
MOL File: 26050-64-6.mol

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methyl 4-bromo-3,5-dimethoxybenzoate Property

Melting point:: 119-120 °C
Boiling point:: 351.0±37.0 °C(Predicted)
Density: 1.436±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: soluble in Ether
form: White Crystals
Appearance: White to off-white Solid

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M296558
Product name: Methyl4-Bromo-3,5-dimethoxybenzoate
Packaging: 500mg
Price: $110
Updated: 2021/12/16

TRC

Product number: M296558
Product name: Methyl4-Bromo-3,5-dimethoxybenzoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: 8317CA
Product name: Methyl4-bromo-3,5-dimethoxybenzoate
Packaging: 10g
Price: $252
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0044139
Product name: 4-BROMO-3,5-DIMETHOXYBENZOIC ACID METHYL ESTER
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

Apolloscientific

Product number: OR5931
Product name: Methyl4-bromo-3,5-dimethoxybenzoate
Purity: 95+%
Packaging: 5g
Price: $118
Updated: 2021/12/16

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methyl 4-bromo-3,5-dimethoxybenzoate Chemical Properties,Usage,Production

Uses

Chemical building block used in the synthesis of more complex structures.

Synthesis

67-56-1

56518-42-4

26050-64-6

To a round bottom flask was added 4-bromo-3,5-dimethoxybenzoic acid (Compound 8, 4 g, 15.3 mmol) and anhydrous methanol (100 mL). The reaction mixture was cooled to 0 °C and thionyl chloride (11.1 mL, 153 mmol) was added slowly and dropwise with stirring. After the dropwise addition was completed, the reaction system was heated to 80 °C and the reaction was stirred at this temperature for 2 hours. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure to remove the solvent. The residue was dissolved in ethyl acetate (100 mL) and the organic layer was washed sequentially with water (50 mL x 2) and saturated saline (50 mL). The organic layer was dried over anhydrous sodium sulfate, filtered, and the filtrate was concentrated under reduced pressure to afford methyl 4-bromo-3,5-dimethoxybenzoate as a white crystalline solid (Compound 12, 4.24 g, quantitative yield).Results of LC-MS analysis: retention time (TR) = 2.3 min; [M+H]+ = 274.9, 277.0 (bromine isotope peak).

References

[1] Chemistry - A European Journal, 2013, vol. 19, # 15, p. 4786 - 4797
[2] Patent: WO2018/85552, 2018, A1. Location in patent: Page/Page column 59
[3] European Journal of Medicinal Chemistry, 2016, vol. 107, p. 255 - 274
[4] RSC Advances, 2016, vol. 6, # 2, p. 947 - 952

methyl 4-bromo-3,5-dimethoxybenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl 4-bromo-3,5-dimethoxybenzoate Suppliers

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26050-64-6, methyl 4-bromo-3,5-dimethoxybenzoate Related Search:

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26050-64-6