4-amino-5-hydroxynaphthalene-1,3-disulphonic acid
- Product Name
- 4-amino-5-hydroxynaphthalene-1,3-disulphonic acid
- CAS No.
- 82-47-3
- Chemical Name
- 4-amino-5-hydroxynaphthalene-1,3-disulphonic acid
- Synonyms
- 8-Amino-5,7-disulfo-1-naphthol;8,1,5,7-Aminonaphtholdisulfonic acid;1-Amino-8-naphthol-2,4-disulfonic acid;8-Amino-1-hydroxy-5,7-disulfonaphthalene;4-amino-5-hydroxynaphthalene-1,3-disulfonicaci;1-AMino-8-naphthol-2,4-disulfonic acid(SS Acid);4-Amino-5-hydroxy-1,3-naphthalenedisulfonic acid;4-Amino-5-Hydorxy-1,3-Naphthalenedisulfonic Acid;4-amino-5-hydroxynaphthalene-1,3-disulfonic acid;1-Amino-8-hydroxynaphthalene-2,4-disulfonic acid
- CBNumber
- CB7925021
- Molecular Formula
- C10H9NO7S2
- Formula Weight
- 319.31
- MOL File
- 82-47-3.mol
4-amino-5-hydroxynaphthalene-1,3-disulphonic acid Property
- EPA Substance Registry System
- 1,3-Naphthalenedisulfonic acid, 4-amino-5-hydroxy- (82-47-3)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container to..…
4-amino-5-hydroxynaphthalene-1,3-disulphonic acid Chemical Properties,Usage,Production
Chemical Properties
1-Amino-8-hydroxynaphthalene-2,4-disulfonic acid [82-47-3]. (4-amino-5-hydroxynaphthalene-1,3-disulfonic acid), Chicago acid, 2 S acid, C10H9NO7S2, Mr 319.3, and its acid sodium salt are readily soluble in water; the latter can be salted out with sodium chloride. In alkaline solution, coupling with diazo compounds takes place ortho to the hydroxyl group. Alkaline hydrolysis at 170℃ gives 1,8-dihydroxynaphthalene-2,4-disulfonic acid. Heating with dilute sulfuric acid results in desulfonation to give 1-amino-8-hydroxynaphthalene-2-sulfonic acid.
Uses
Chicago acid is used as a coupling component for C.I. Direct Blue 1, C.I. Direct Blue 22, and C.I. Direct Blue 76 (the dicopper complex of demethylated).
Production Methods
A solution of the disodium salt of naphthosultam-2,4-disulfonic acid is concentrated and mixed with potassium hydroxide liquor at 130℃. The temperature is raised to 155℃ over 20 h to complete the reaction. After being cooled and diluted with water, the melt is run into excess hydrochloric acid and the monopotassium salt is collected by filtration at 30℃ and slurry washed with recycling of the wash liquors. A yield of 87 % is obtained.
4-amino-5-hydroxynaphthalene-1,3-disulphonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
4-amino-5-hydroxynaphthalene-1,3-disulphonic acid Suppliers
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- Product
- 4-amino-5-hydroxynaphthalene-1,3-disulphonic acid 82-47-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%+
- Supply Ability
- 100 tons
- Release date
- 2019-12-31