(S)-(-)-2-ACETOXYPROPIONYL CHLORIDE
- Product Name
- (S)-(-)-2-ACETOXYPROPIONYL CHLORIDE
- CAS No.
- 36394-75-9
- Chemical Name
- (S)-(-)-2-ACETOXYPROPIONYL CHLORIDE
- Synonyms
- (S)-1-chloro-1-oxopropan-2-yl acetate;L-(-)-2-ACETOXYPROPIONYL CHLORIDE;AP-CL;Mosandl reagent;O-ACETYL-L-LACTYL CHLORIDE;S-ACETOXYPROPIONYL CHLORIDE;2-Acetoxy propionyl chloride;L-α-Acetoxypropionyl Chloride;)-2-Acetoxypropionyl chloride;L-α-Acetoxypropionyl Chloride
- CBNumber
- CB8123118
- Molecular Formula
- C5H7ClO3
- Formula Weight
- 150.56
- MOL File
- 36394-75-9.mol
(S)-(-)-2-ACETOXYPROPIONYL CHLORIDE Property
- Boiling point:
- 50 °C5 mm Hg(lit.)
- alpha
- -31o (C=4 IN CHLOROFORM)
- Density
- 1.189 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.423(lit.)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Chloroform (Sparingly)
- form
- clear liquid
- color
- Colorless to Light yellow
- Specific Gravity
- 1.19
- optical activity
- [α]20/D 31°, c = 4 in chloroform
- BRN
- 1722943
- Stability:
- Hygroscopic, Moisture sensitive
- CAS DataBase Reference
- 36394-75-9(CAS DataBase Reference)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-43-22
- Safety Statements
- 26-36/37/39-45-23
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 2918199890
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 447056
- Product name
- (S)-(?)-2-Acetoxypropionyl chloride
- Purity
- 97%
- Packaging
- 5g
- Price
- $194
- Updated
- 2024/03/01
- Product number
- A1297
- Product name
- (S)-(-)-2-Acetoxypropionyl Chloride
- Purity
- >97.0%(GC)(T)
- Packaging
- 1g
- Price
- $43
- Updated
- 2024/03/01
- Product number
- A1297
- Product name
- (S)-(-)-2-Acetoxypropionyl Chloride
- Purity
- >97.0%(GC)(T)
- Packaging
- 5g
- Price
- $128
- Updated
- 2024/03/01
- Product number
- A167743
- Product name
- L-α-AcetoxypropionylChloride
- Packaging
- 1g
- Price
- $50
- Updated
- 2021/12/16
- Product number
- OR42238
- Product name
- (2S)-(-)-2-Acetoxypropanoylchloride
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
(S)-(-)-2-ACETOXYPROPIONYL CHLORIDE Chemical Properties,Usage,Production
Uses
Frequently used chiral building block. Also used to resolve a bicyclic α-hydroxylactone and to prepare chiral phosphonates used in an enantiomeric excess assay of unprotected amino acids. Useful chiral derivatizing agent.
Purification Methods
It is moisture sensitive and is hydrolysed to the corresponding acid. Check the IR spectrum. If the OH band above 3000cm -1 is too large and broad then the mixture should be refluxed with pure acetyl chloride for 1hour, evaporated and distilled under reduced pressure. [Julia & Sans J Chromatographic Sci 17 651 1979, Dolittle & Heath J Org Chem 49 5041 1984, Beilstein 3 II 189.]
(S)-(-)-2-ACETOXYPROPIONYL CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (S)-(-)-2-ACETOXYPROPIONYL CHLORIDE manufacturers
- Product
- (S)-()-2-Acetoxypropionyl chloride 36394-75-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- (S)-1-chloro-1-oxopropan-2-yl acetate 36394-75-9
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1KG
- Purity
- 99.0%+
- Supply Ability
- 600 tons
- Release date
- 2020-01-02
- Product
- (S)-(-)-2-ACETOXYPROPIONYL CHLORIDE 36394-75-9
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2020-01-31