6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE

Product Name: 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE
CAS No.: 4044-99-9
Chemical Name: 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE
Synonyms: 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE;IMidazo[1,2-a]pyridine, 6-broMo-2-Methyl-
CBNumber: CB81253515
Molecular Formula: C8H7BrN2
Formula Weight: 211.06
MOL File: 4044-99-9.mol

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6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE Property

Melting point:: 101.0-101.5 °C
Density: 1.60±0.1 g/cm3(Predicted)
storage temp.: Store at room temperature
pka: 5.47±0.10(Predicted)
Appearance: Off-white to yellow Solid

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B614390
Product name: 6-Bromo-2-methylimidazo[1,2-a]pyridine
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB134866
Product name: 6-Bromo-2-methylimidazo[1,2-a]pyridine
Packaging: 50mg
Price: $40
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB134866
Product name: 6-Bromo-2-methylimidazo[1,2-a]pyridine
Packaging: 100mg
Price: $70
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB134866
Product name: 6-Bromo-2-methylimidazo[1,2-a]pyridine
Packaging: 250mg
Price: $140
Updated: 2021/12/16

Apolloscientific

Product number: OR110182
Product name: 6-Bromo-2-methylimidazo[1,2-a]pyridine
Packaging: 1g
Price: $203
Updated: 2021/12/16

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6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE Chemical Properties,Usage,Production

Synthesis

1072-97-5

78-95-5

4044-99-9

General procedure for the synthesis of 6-bromo-2-methylimidazo[1,2-a]pyridine from 2-amino-5-bromopyridine and chloroacetone: 2-amino-5-bromopyridine (6.2 g) was dissolved in ethanol (60 mL), followed by chloroacetone (5.7 mL). The reaction mixture was heated to 90 °C and refluxed for 16 hours under stirring conditions. Upon completion of the reaction, the mixture was cooled and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (Biotage, 100 g) using a gradient elution of dichloromethane with methanol (2-15%) to yield 6-bromo-2-methylimidazo[1,2-a]pyridine (6.1 g, 80.6% yield) as a yellow solid.1H NMR (500 MHz, CD3OD) δ 9.03 (s, 1H),. 8.02 (m, 1H), 7.93 (s, 1H), 7.79 (d, J=9.4Hz, 1H), 2.56 (d, J=1.0Hz, 3H).

References

[1] Patent: WO2015/86498, 2015, A1. Location in patent: Page/Page column 94
[2] Patent: WO2015/86506, 2015, A1. Location in patent: Page/Page column 99
[3] Patent: WO2015/86512, 2015, A1. Location in patent: Page/Page column 97
[4] Patent: US2010/204214, 2010, A1. Location in patent: Page/Page column 112
[5] Patent: WO2014/9295, 2014, A1. Location in patent: Page/Page column 115

6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE Suppliers

China 75 Switzerland 1 United Kingdom 4 United States 7 Global 87

Shanghai Topbiochem Technology Co., Ltd

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Jiaxing Rich Biological Technology Co., Ltd.

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Shanghai Carlow Chemicals Co., Ltd.

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View Lastest Price from 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE 4044-99-9
Price: US $3.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200000KG
Release date: 2024-07-29

Career Henan Chemical Co

Product: 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE 4044-99-9
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 200KG
Release date: 2018-12-23

4044-99-9, 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINERelated Search:

6-BROMO-2-METHYL-3,4-DIHYDROQUINAZOLIN-4-ONE 6-BROMO-2-METHYLOXAZOLO[4,5-B]PYRIDINE 6-Bromo-2-methylimidazo[1,2-a]pyrazine 6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLIC ACID 6-BROMO-2-METHYL-IMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLIC ACID ETHYL ESTER 6-bromoH-imidazo[1,2-a]pyridine-2-carboxylic acid 6-Bromo-2-phenyl-imidazo[1,2-a]pyridine-3-carboxaldehyde 6-BROMO-2-(3-METHOXY-PHENYL)-IMIDAZO[1,2-A]-PYRIDINE-3-CARBALDEHYDE 6-Bromo-2-(4-iodo-phenyl)-imidazo[1,2-a]pyridine 6-BROMO-2-PHENYL-IMIDAZO[1,2-A]PYRIDINE-3-CARBALDEHYDE 6-Bromo-2-(4-nitro-phenyl)-imidazo[1,2-a]pyridine 6-BROMO-2-PHENYL-IMIDAZO[1,2-A]PYRIDINE 6-BROMO-2-(4-FLUORO-PHENYL)-IMIDAZO[1,2-A]-PYRIDINE-3-CARBALDEHYDE 6-BROMO-2-(4-BROMOPHENYL)-IMIDAZO[1,2-A]PYRIDINE 3,6,8-tribromo-2-methylimidazo[1,2-a]pyridine IMIDAZO[1,2-A]PYRIDIN-3-AMINE, 6-BROMO-N-(1,1-DIMETHYLETHYL)-2-(4-PYRIDINYL)- 6-BROMO-2-(4-NITRO-PHENYL)-IMIDAZO[1,2-A]PYRIDINE-3-CARBALDEHYDE 6-BROMO-2-(4-BROMO-PHENYL)-IMIDAZO[1,2-A]PYRIDINE-3-CARBALDEHYDE

6-BROMO-2-METHYLIMIDAZO[1,2-A]PYRIDINE

IMidazo[1,2-a]pyridine, 6-broMo-2-Methyl-

4044-99-9

Fused Ring Systems

Halides