AURANTIOL
- Product Name
- AURANTIOL
- CAS No.
- 89-43-0
- Chemical Name
- AURANTIOL
- Synonyms
- AURALVA;201-908-1;AURANTIOL;AURANTION;AURANTIUM;Hydroxycitronellal;Hydroxycitronellal methyl anthranilate;METHYL ANTHRANILATE HYDROXY CITRONELLAL;HYDROXYCITRONELLYLIDENE METHYLANTHRANILATE;HYDROXYCITRONELLAL-METHYLANTHRANILATE SCHIFF'S BASE
- CBNumber
- CB8125415
- Molecular Formula
- C18H27NO3
- Formula Weight
- 305.41
- MOL File
- 89-43-0.mol
AURANTIOL Property
- Boiling point:
- 445.7±45.0 °C(Predicted)
- Density
- 1.01±0.1 g/cm3(Predicted)
- Flash point:
- 97℃
- solubility
- Almost insoluble in water, soluble in alcohol and oils, poorly soluble in Propylene glycol.
- form
- Intensely yellow, viscous to very viscous liquid
- pka
- 15.31±0.29(Predicted)
- Odor
- at 50.00 % in dipropylene glycol. floral lily orange blossom sweet
- Odor Type
- floral
- LogP
- 5.417 (est)
- EPA Substance Registry System
- Benzoic acid, 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]-, methyl ester (89-43-0)
Safety
- Toxicity
- The acute oral LD50 value in rats was reported as > 5 g/kg (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 2 g/kg (Moreno, 1973).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H317May cause an allergic skin reaction
H319Causes serious eye irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P272Contaminated work clothing should not be allowed out of the workplace.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P363Wash contaminated clothing before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- S363529
- Product name
- METHYL N-(3,7-DIMETHYL-7-HYDROXYOCTYLIDENE)-ANTHRANILATE
- Purity
- Aldrich
- Packaging
- 250mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- 3702BA
- Product name
- Aurantiol
- Packaging
- 250g
- Price
- $248
- Updated
- 2021/12/16
- Product number
- 33821
- Product name
- MethylN-(3,7-Dimethyl-7-Hydroxyoctylidene)-anthranilate,KOSHER
- Purity
- KOSHER
- Packaging
- 2.5KG
- Price
- $572.32
- Updated
- 2021/12/16
- Product number
- 33821
- Product name
- MethylN-(3,7-Dimethyl-7-Hydroxyoctylidene)-anthranilate,KOSHER
- Purity
- KOSHER
- Packaging
- 10KG
- Price
- $1542.24
- Updated
- 2021/12/16
- Product number
- 33821
- Product name
- MethylN-(3,7-Dimethyl-7-Hydroxyoctylidene)-anthranilate,KOSHER
- Purity
- KOSHER
- Packaging
- 25KG
- Price
- $3469.76
- Updated
- 2021/12/16
AURANTIOL Chemical Properties,Usage,Production
Chemical Properties
Viscous, colorless, or faintly yellow liquid; sweet lily-type odor.Soluble in alcohol (50%), fixed oils; slightly soluble in water, glycerol, and mineral oil. Combustible.
Occurrence
Has apparently not been reported to occur in nature.
Uses
hydroxycitronellal is used to mask odor.
Uses
Perfumery (fixative, muguet odor), flavoring, soap and cosmetic fragrances.
Application
This Schiff-s base Aurantiol is the most widely used of all Schiff's bases known in perfumery. Its low cost and considerable strength, its tenacity and versatility are virtues that make the product applicable in fragrances of all price levels and for numerous purposes. Obviously and almost inevitably used in Orange blossom, Neroli and related heavy florals, it finds use in smaller amounts in countless other fragrant types: Citrus blends, Ambres, and Orientals. Chyprcs, etc. It forms the steady undertone in many such sweet florals, in Honeysuckle, Frangipanni, Magnolia, exotic florals, etc. In the Citrus Cologne types, it has the ability to appear even in the initial notes, besides being a fixative. Used for nearly 50 years, it has been brought "back to life" several times, e. g., when the fruity-musky perfume was fashionable (and still is, to a certain degree), that perfume had a solid undertone of this type of material, backed up by Ethylene brassylate and Undecanolide in unusually high proportions. This base has a perceptible effect in a perfume oil at concentrations beginning well below 1%, but is often used at a much higher level.
Preparation
By hydration of citronellal (Bedoukian, 1967).
Synthesis Reference(s)
The Journal of Organic Chemistry, 39, p. 108, 1974 DOI: 10.1021/jo00915a028
Trade name
Aurantiol Pure (Givaudan).
AURANTIOL Preparation Products And Raw materials
Raw materials
Preparation Products
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