ChemicalBook > CAS DataBase List > 2-PIPERIDIN-1-YL-BENZALDEHYDE

2-PIPERIDIN-1-YL-BENZALDEHYDE

Product Name
2-PIPERIDIN-1-YL-BENZALDEHYDE
CAS No.
34595-26-1
Chemical Name
2-PIPERIDIN-1-YL-BENZALDEHYDE
Synonyms
TIMTEC-BB SBB010807;ASINEX-REAG BAS 10156457;2-Piperidinobenzaldehyde;1-(2-Formylphenyl)piperidine;2-(1-Piperidinyl)benzaldehyde;2-PIPERIDIN-1-YL-BENZALDEHYDE;2-PIPERIDINOBENZENECARBALDEHYDE;Benzaldehyde, 2-(1-piperidinyl)-;2-Piperidin-1-ylbenzaldehyde 95%;2-PIPERIDIN-1-YL-BENZALDEHYDE, 95+%
CBNumber
CB8126760
Molecular Formula
C12H15NO
Formula Weight
189.25
MOL File
34595-26-1.mol
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2-PIPERIDIN-1-YL-BENZALDEHYDE Property

Melting point:
95 °C(Solv: ethanol (64-17-5))
Boiling point:
143 °C(Press: 1.0 Torr)
Density 
1.091±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
liquid
pka
4.36±0.40(Predicted)
color 
Clear, yellow / oil
CAS DataBase Reference
34595-26-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36-52
Safety Statements 
26
HazardClass 
IRRITANT
HS Code 
2913000090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
019261
Product name
2-Piperidinobenzenecarbaldehyde
Packaging
500mg
Price
$11
Updated
2021/12/16
Matrix Scientific
Product number
019261
Product name
2-Piperidinobenzenecarbaldehyde
Packaging
1g
Price
$18
Updated
2021/12/16
Matrix Scientific
Product number
019261
Product name
2-Piperidinobenzenecarbaldehyde
Packaging
5g
Price
$56
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
COR0001837
Product name
2-PIPERIDIN-1-YL-BENZALDEHYDE
Purity
95.00%
Packaging
1G
Price
$127.05
Updated
2021/12/16
SynQuest Laboratories
Product number
4H15-1-J9
Product name
2-(Piperidin-1-yl)benzaldehyde
Purity
95.0%
Packaging
5G
Price
$136
Updated
2021/12/16
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2-PIPERIDIN-1-YL-BENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

110-89-4

446-52-6

34595-26-1

General procedure for the synthesis of 2-piperidinyl-1-benzaldehyde from hexahydropyridine and 2-fluorobenzaldehyde: To a solution of 2-fluorobenzaldehyde (20 g, 161.1 mmol) in anhydrous DMF (160 ml) was added piperidine (19.1 ml, 193.4 mmol, 1.2 eq.) and potassium carbonate (26.73 g, 193.4 mmol, 1.2 eq.), in that order. . The suspension was heated with stirring at 130 °C for 3 hours. After completion of the reaction, the reaction mixture was poured into cold water. The pH was adjusted with citric acid to 5. The aqueous layer was extracted three times with ethyl acetate (EtOAc), the organic phases were combined and washed sequentially with water, saturated sodium bicarbonate (NaHCO3) solution and brine. The organic phase was dried with anhydrous magnesium sulfate (MgSO4), filtered and concentrated to give the target product 2-piperidinyl-1-benzaldehyde as a red oil (28.23 g, 92% yield).

References

[1] Angewandte Chemie - International Edition, 2012, vol. 51, # 8, p. 1950 - 1953
[2] Heterocycles, 2008, vol. 75, # 4, p. 799 - 838
[3] Patent: WO2004/108673, 2004, A2. Location in patent: Page 38-39
[4] Patent: US2004/192921, 2004, A1. Location in patent: Page 4
[5] Russian Chemical Bulletin, 2004, vol. 53, # 6, p. 1240 - 1247

2-PIPERIDIN-1-YL-BENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-PIPERIDIN-1-YL-BENZALDEHYDE Suppliers

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View Lastest Price from 2-PIPERIDIN-1-YL-BENZALDEHYDE manufacturers

Career Henan Chemical Co
Product
2-PIPERIDIN-1-YL-BENZALDEHYDE 34595-26-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-11