4-Fluorobenzylboronic acid pinacol ester

Application

Product Name: 4-Fluorobenzylboronic acid pinacol ester
CAS No.: 243145-83-7
Chemical Name: 4-Fluorobenzylboronic acid pinacol ester
Synonyms: 2-(4-Fluorobenzyl);4-Fluorobenzylboronic acid pinacol este;4-fluorobenzylboronic acid pinacol ester;4-Fluorobenzylboronic acid, pinacol ester 95+%;2-(4-Fluorobenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxabo;4-Fluorobenzylboronic acid pinacol ester ISO 9001：2015 REACH;2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-dioxaborolane, 2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-;1,3,2-dioxaborolane, 2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl- - [D22589]
CBNumber: CB81267617
Molecular Formula: C13H18BFO2
Formula Weight: 236.09
MOL File: 243145-83-7.mol

More

Less

4-Fluorobenzylboronic acid pinacol ester Property

Boiling point:: 275 °C
Density: 1.04
Flash point:: 120 °C
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: liquid
color: Colourless

More

Less

Safety

HS Code: 2931900090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TRC

Product number: F596758
Product name: 4-Fluorobenzylboronicacidpinacolester
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Synthonix

Product number: D22589
Product name: 1,3,2-dioxaborolane,2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-
Purity: 97.0%
Packaging: 250mg
Price: $80
Updated: 2021/12/16

Apolloscientific

Product number: PC412402
Product name: 4-Fluorobenzylboronicacid,pinacolester
Purity: 95+%
Packaging: 250mg
Price: $83
Updated: 2021/12/16

AK Scientific

Product number: 1788AB
Product name: 2-(4-Fluorobenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Packaging: 250mg
Price: $131
Updated: 2021/12/16

Apolloscientific

Product number: PC412402
Product name: 4-Fluorobenzylboronicacid,pinacolester
Purity: 95+%
Packaging: 1g
Price: $206
Updated: 2021/12/16

More

Less

4-Fluorobenzylboronic acid pinacol ester Chemical Properties,Usage,Production

Application

In scientific research, boron esters are primarily used as synthetic intermediates in transition metal-catalyzed cross-coupling reactions to construct structurally complex target compounds. In industrial production, boron esters have found wide applications in pharmaceuticals, pesticides, and materials.

Synthesis

352-11-4

73183-34-3

243145-83-7

Example 6: Under argon protection, magnesium shavings (16.8 mg, 0.7 mmol) were added to tetrahydrofuran (1 ml), followed by bis(pinacolato)borate (127.0 mg, 0.5 mmol) and p-fluorobenzyl chloride (162 μl, 1.35 mmol). Fe(acac)3 catalyst (3.5 mg, 0.010 mmol, 2 mol%) was added at 0 °C and the reaction was carried out for 3 hours. Upon completion of the reaction, the reaction was quenched with water and the reaction product was extracted with ethyl acetate. The yield of 4-fluorobenzylboronic acid pinacol ester was calculated to be 93% by gas chromatographic analysis.

References

[1] Patent: CN107903281, 2018, A. Location in patent: Paragraph 0028
[2] Green Chemistry, 2012, vol. 14, # 3, p. 661 - 667
[3] Journal of the American Chemical Society, 2014, vol. 136, # 27, p. 9521 - 9523

4-Fluorobenzylboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

4-Fluorobenzylboronic acid pinacol ester Suppliers

China 73 India 2 United Kingdom 1 United States 7 Global 83

PharmaBlock Sciences (Nanjing),Inc.

Tel: 025-86918202 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 5000
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai ZaiQi Bio-Tech Co., Ltd.

Tel: 021-54824098, 021-37212705 021-37212706, 13391256916
Fax: 021-54824069
Email: sales@chemzq.com
Country: China
ProdList: 570
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

shanghai aokchem co., ltd

Tel: 021-68712331 39130253
Fax: 18621350903
Email: aokchem@gmail.com
Country: China
ProdList: 332
Advantage: 58

Shanghai Hong-chuang Pharma Tech Co., Ltd.

Tel: 18151128828
Fax: -
Email: hc-sales@foxmail.com
Country: China
ProdList: 2647
Advantage: 55

Cochemical Ltd.

Tel: 029-86115547 17791676824
Fax: 02151602123
Email: sales@cochemical.com
Country: China
ProdList: 3014
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 42446
Advantage: 60

Shanghai ShiXian Chemical Technology Co., Ltd.

Tel: 18681884732
Fax: 021-51632502
Email: 2245256225@qq.com
Country: China
ProdList: 1729
Advantage: 50

Hangzhou Milestone Pharmtech Co., Ltd.

Tel: 0571-82896630 18969958410
Email: sales_hz@milestonepharmtech.com
Country: China
ProdList: 4894
Advantage: 55

More

Less

View Lastest Price from 4-Fluorobenzylboronic acid pinacol ester manufacturers

Career Henan Chemical Co

Product: 4-Fluorobenzylboronic acid pinacol ester 243145-83-7
Price: US $0.10/g
Min. Order: 1g
Purity: 98%min
Supply Ability: 10g,100g,1kg
Release date: 2020-01-10

243145-83-7, 4-Fluorobenzylboronic acid pinacol esterRelated Search:

Benzylboronic acid Ammonium fluoborate Sodium tetrafluoroborate Benzyl chloride Fluoroboric acid Methyl acrylate Potassium tetrafluoroborate Tris(trimethylsilyl)phosphate 4-Fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 2-(2,5-Dibromo-3-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 3-FLUORO-4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE 1-Ethyl-1H-pyrazole-4-boronic acid, pinacol ester 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-3-CYCLOHEXENE-1-CARBOXYLIC ACID METHYL ESTER 1-(4-FLUOROPHENYL)VINYLBORONIC ACID, PINACOL ESTER 2-fluorobenzylboronic acid pinacol ester Benzylboronic acid pinacol ester Boronic acid, [(4-fluorophenyl)methyl]- (9CI) 4-Fluorobenzylboronic acid pinacol ester

4-fluorobenzylboronic acid pinacol ester

4-Fluorobenzylboronic acid, pinacol ester 95+%

1,3,2-dioxaborolane, 2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-

2-(4-Fluorobenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-Fluorobenzylboronic acid pinacol este

2-(4-Fluorobenzyl)

2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-Fluorobenzylboronic acid pinacol ester ISO 9001：2015 REACH

2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxabo

1,3,2-dioxaborolane, 2-[(4-fluorophenyl)methyl]-4,4,5,5-tetramethyl- - [D22589]

243145-83-7