ChemicalBook > CAS DataBase List > 3-Furancarboxylicacid,5-methyl-,methylester(9CI)

3-Furancarboxylicacid,5-methyl-,methylester(9CI)

Product Name
3-Furancarboxylicacid,5-methyl-,methylester(9CI)
CAS No.
35351-35-0
Chemical Name
3-Furancarboxylicacid,5-methyl-,methylester(9CI)
Synonyms
methylfuran-​Methyl 5-methyl-3-furoate;methyl 5-methylfuran-3-carboxyla;Methyl 5-methylfuran-3-carboxylate;5-Methyl-3-furancarboxylic acid methyl ester;3-Furancarboxylic acid, 5-methyl-, methyl ester;3-Furancarboxylicacid,5-methyl-,methylester(9CI)
CBNumber
CB81285912
Molecular Formula
C7H8O3
Formula Weight
140.14
MOL File
35351-35-0.mol
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3-Furancarboxylicacid,5-methyl-,methylester(9CI) Property

Boiling point:
80-83 °C(Press: 29 Torr)
Density 
1.108±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M355865
Product name
methyl5-methylfuran-3-carboxylate
Packaging
10mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
118937
Product name
Methyl 5-methylfuran-3-carboxylate
Purity
95+%
Packaging
250mg
Price
$324
Updated
2021/12/16
AK Scientific
Product number
4402AB
Product name
Methyl5-methylfuran-3-carboxylate
Packaging
250mg
Price
$371
Updated
2021/12/16
Matrix Scientific
Product number
118937
Product name
Methyl 5-methylfuran-3-carboxylate
Purity
95+%
Packaging
1g
Price
$810
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0078573
Product name
3-FURANCARBOXYLIC ACID, 5-METHYL-, METHYL ESTER
Purity
95.00%
Packaging
1G
Price
$1152.11
Updated
2021/12/16
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3-Furancarboxylicacid,5-methyl-,methylester(9CI) Chemical Properties,Usage,Production

Synthesis

123-38-6

292638-85-8

35351-35-0

Palladium(II) acetate [Pd(OAc)2] (0.2 mmol), H4PMo11V1O40 (15 μmol), cerium chloride heptahydrate (CeCl3-7H2O) (0.2 mmol), methanol (30 mmol), and acetic acid (4.5 mL) were added sequentially to the reactor. The reaction mixture was heated to 70 °C. A mixture of methyl acrylate (1 mmol), propionaldehyde (6 mmol) and acetic acid (0.5 mL) was added dropwise to the reaction system using a syringe pump at a rate of 5 μL/min under an oxygen atmosphere of 1 atm (0.1 MPa) for 8 hours. Upon completion of the reaction, the reaction mixture was analyzed by gas chromatography and the yield of methyl 5-methyl-3-furancarboxylate was measured to be 90%.

References

[1] Journal of Organic Chemistry, 2007, vol. 72, # 23, p. 8820 - 8823
[2] Patent: US2007/197806, 2007, A1. Location in patent: Page/Page column 7

3-Furancarboxylicacid,5-methyl-,methylester(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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