3-Furancarboxylicacid,5-methyl-,methylester(9CI)
- Product Name
- 3-Furancarboxylicacid,5-methyl-,methylester(9CI)
- CAS No.
- 35351-35-0
- Chemical Name
- 3-Furancarboxylicacid,5-methyl-,methylester(9CI)
- Synonyms
- methylfuran-Methyl 5-methyl-3-furoate;methyl 5-methylfuran-3-carboxyla;Methyl 5-methylfuran-3-carboxylate;5-Methyl-3-furancarboxylic acid methyl ester;3-Furancarboxylic acid, 5-methyl-, methyl ester;3-Furancarboxylicacid,5-methyl-,methylester(9CI)
- CBNumber
- CB81285912
- Molecular Formula
- C7H8O3
- Formula Weight
- 140.14
- MOL File
- 35351-35-0.mol
3-Furancarboxylicacid,5-methyl-,methylester(9CI) Property
- Boiling point:
- 80-83 °C(Press: 29 Torr)
- Density
- 1.108±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
N-Bromosuccinimide Price
- Product number
- M355865
- Product name
- methyl5-methylfuran-3-carboxylate
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 118937
- Product name
- Methyl 5-methylfuran-3-carboxylate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $324
- Updated
- 2021/12/16
- Product number
- 4402AB
- Product name
- Methyl5-methylfuran-3-carboxylate
- Packaging
- 250mg
- Price
- $371
- Updated
- 2021/12/16
- Product number
- 118937
- Product name
- Methyl 5-methylfuran-3-carboxylate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $810
- Updated
- 2021/12/16
- Product number
- CHM0078573
- Product name
- 3-FURANCARBOXYLIC ACID, 5-METHYL-, METHYL ESTER
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $1152.11
- Updated
- 2021/12/16
3-Furancarboxylicacid,5-methyl-,methylester(9CI) Chemical Properties,Usage,Production
Synthesis
123-38-6
292638-85-8
35351-35-0
Palladium(II) acetate [Pd(OAc)2] (0.2 mmol), H4PMo11V1O40 (15 μmol), cerium chloride heptahydrate (CeCl3-7H2O) (0.2 mmol), methanol (30 mmol), and acetic acid (4.5 mL) were added sequentially to the reactor. The reaction mixture was heated to 70 °C. A mixture of methyl acrylate (1 mmol), propionaldehyde (6 mmol) and acetic acid (0.5 mL) was added dropwise to the reaction system using a syringe pump at a rate of 5 μL/min under an oxygen atmosphere of 1 atm (0.1 MPa) for 8 hours. Upon completion of the reaction, the reaction mixture was analyzed by gas chromatography and the yield of methyl 5-methyl-3-furancarboxylate was measured to be 90%.
References
[1] Journal of Organic Chemistry, 2007, vol. 72, # 23, p. 8820 - 8823
[2] Patent: US2007/197806, 2007, A1. Location in patent: Page/Page column 7