Tris(dibenzylideneacetone)dipalladium

Product Name: Tris(dibenzylideneacetone)dipalladium
CAS No.: 52409-22-0
Chemical Name: Tris(dibenzylideneacetone)dipalladium
Synonyms: PD(DBA)2;Pd(dba)3;PALLADIUM(0) BIS(DIBENZYLIDENEACETONE);Bis(dibenzylideneacetone)dipalladium;tris(dibenzylideneacetone)dipalladium(o)(pd2(dba)3);Tris(dibenzylideneacetone;Tris(dibenzylideneacetone)dipalladium;BIS(DIBENZYLIDENEACETONE) PALLADIUM(0);Tris(dibenzilideneacetone)dipalladium(0);Tris(dibenzylidineacetone)-dipalladium(o)
CBNumber: CB8132457
Molecular Formula: C51H42O3Pd2
Formula Weight: 915.71738
MOL File: 52409-22-0.mol

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Tris(dibenzylideneacetone)dipalladium Property

Melting point:: 152-155 °C(lit.)
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
InChI: InChI=1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;
InChIKey: UKSZBOKPHAQOMP-SVLSSHOZSA-N
SMILES: [Pd].C(=C/C1=CC=CC=C1)\C(/C=C/C1=CC=CC=C1)=O.C(=C/C1=CC=CC=C1)\C(/C=C/C1=CC=CC=C1)=O
CAS DataBase Reference: 52409-22-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38
Safety Statements: 22-24/25
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Arctom

Product number: AS463461
Product name: Pd2(DBA)3
Purity: 98%
Packaging: 250mg
Price: $36
Updated: 2021/12/16

Arctom

Product number: AS463461
Product name: Pd2(DBA)3
Purity: 98%
Packaging: 1g
Price: $78
Updated: 2021/12/16

Crysdot

Product number: CD52001724
Product name: Pd2(DBA)3
Purity: 98%
Packaging: 5g
Price: $83
Updated: 2021/12/16

Crysdot

Product number: CD52001724
Product name: Pd2(DBA)3
Purity: 98%
Packaging: 10g
Price: $161
Updated: 2021/12/16

Arctom

Product number: AS463461
Product name: Pd2(DBA)3
Purity: 98%
Packaging: 5g
Price: $237
Updated: 2021/12/16

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Tris(dibenzylideneacetone)dipalladium Chemical Properties,Usage,Production

Uses

Tris(dibenzylideneacetone)dipalladium is used as a source of soluble Pd(0), in particular as a catalyst for various coupling reactions. Examples of reactions using this reagent are the Negishi coupling, Suzuki coupling, Carroll rearrangement, and Trost asymmetric allylic alkylation, as well as Buchwald–Hartwig amination

Synthesis

A process for the preparation of tris(dibenzylideneacetone)dipalladium (chloroform) comprising the steps of:
(a) reacting a Pd(II) complex with an alkali metal halide in at least one alcohol solvent; and
(b) reacting the product of step (a) with a mixture comprising dibenzylideneacetone, chloroform and an inorganic base to form Pd2(dba)3.CHCl3.

Tris(dibenzylideneacetone)dipalladium Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(dibenzylideneacetone)dipalladium Suppliers

China 137 Europe 2 Germany 3 India 3 Japan 2 Switzerland 1 United Kingdom 5 United States 15 Global 168

Wuhan Jiade Ruifeng New Materials Co., Ltd

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View Lastest Price from Tris(dibenzylideneacetone)dipalladium manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Tris(dibenzylideneacetone)dipalladium 60748-74-2
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-11

Shaanxi Dideu Medichem Co. Ltd

Product: Tris(dibenzylideneacetone)dipalladium 52409-22-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2020-04-17

Career Henan Chemical Co

Product: BIS(DIBENZYLIDENEACETONE)PALLADIUM 52409-22-0
Price: US $8.00/KG
Min. Order: 1KG
Purity: ＞98% HPLC
Supply Ability: 20 tons
Release date: 2020-02-17

52409-22-0, Tris(dibenzylideneacetone)dipalladiumRelated Search:

Benzalacetone Bis(triphenylphosphinepalladium) acetate BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Bis(tricyclohexylphosphine)palladium(II) Dichloride Tris(dibenzylideneacetone)dipalladium-chloroform adduct Tris(dibenzylideneacetone)dipalladium dichlorobis(di-tert-butylphenylphosphine)palladium(II) A Ten.JPC palladium carbon fine chemical catalyzer Tris(dibenzylideneacetone)dipalladium Bis(dibenzylideneacetone)palladium trans,trans-Dibenzylideneacetone Palladium Benzylacetone Dibenzylideneacetone

PALLADIUM(0) BIS(DIBENZYLIDENEACETONE)

PALLADIUM (0) BIS(DIBENZYLIDENEACETONE) SALT

PD(DBA)2

BIS(DIBENZYLIDENEACETONE) PALLADIUM(0)

tris(dibenzylideneacetone)dipalladium(o)(pd2(dba)3)

Tris(dibenzylideneacetone)dipalladium(0) [20% Pd]

Bis(dibenzylideneacetone)dipalladium

Pd(dba)3

Tris(dibenzilideneacetone)dipalladium(0)

Tris(dibenzylideneacetone)dipalladium

Tris(dibenzylideneacetone

Tris(dibenzylidineacetone)-dipalladium(o)

Tris(dibenzylideneacetone)diplalladium(I)

52409-22-0

C21H42O3Pd2

Pd2C17H14O3

Catalysis and Inorganic Chemistry

Homogeneous Pd Catalysts

Homogeneous Catalysts

Catalysts for Organic Synthesis

Classes of Metal Compounds

Transition Metal Compounds

Metal Complexes

Pd (Palladium) Compounds

Catalysts-Ligands