ChemicalBook > CAS DataBase List > Bisphenol TMC

Bisphenol TMC

Product Name
Bisphenol TMC
CAS No.
129188-99-4
Chemical Name
Bisphenol TMC
Synonyms
BPTMC;BISP-TMC;Bisphenol TMC;Bisphenol TMC,BPTMC;Bisphenol TMC Solution;Bisphenol TMC in acetonitrile;Bisphenol TMC@10 mg/mL in Methanol;Bisphenol TMC 100 μg/mL in Methanol;1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCY;4,4'-(3,3,5-Trimethylcyclohexylidene)diphenol
CBNumber
CB81428034
Molecular Formula
C21H26O2
Formula Weight
310.43
MOL File
129188-99-4.mol
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Bisphenol TMC Property

Melting point:
204-207°C
Boiling point:
450.8±38.0 °C(Predicted)
Density 
1.075±0.06 g/cm3(Predicted)
storage temp. 
Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
pka
9.91±0.30(Predicted)
form 
Solid
color 
White to Off-White
BRN 
9785841
InChI
InChI=1S/C21H26O2/c1-15-12-20(2,3)14-21(13-15,16-4-8-18(22)9-5-16)17-6-10-19(23)11-7-17/h4-11,15,22-23H,12-14H2,1-3H3
InChIKey
UMPGNGRIGSEMTC-UHFFFAOYSA-N
SMILES
C1(C2=CC=C(O)C=C2)(C2=CC=C(O)C=C2)CC(C)CC(C)(C)C1
EPA Substance Registry System
Phenol, 4,4'-(3,3,5-trimethylcyclohexylidene)bis- (129188-99-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
61923
Product name
Bisphenol TMC
Purity
analytical standard
Packaging
25mg
Price
$120
Updated
2022/05/15
TCI Chemical
Product number
T4130
Product name
Bisphenol TMC
Packaging
25G
Price
$126
Updated
2025/07/31
TRC
Product number
B519570
Product name
Bisphenol TMC
Packaging
1g
Price
$95
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM1049236
Product name
BISPHENOL TMC
Purity
95.00%
Packaging
5MG
Price
$501.08
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
54716
Product name
Bisphenol TMC
Packaging
1kg
Price
$1075
Updated
2021/12/16
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Bisphenol TMC Chemical Properties,Usage,Production

Description

Bisphenol TMC, also known as 2,2-bis-(4-hydroxy phenyl) butane, is a very important organic chemistry raw material, they are as macromolecular material intermediate, are applied in the fields such as synthetic epoxy resin, cyanate, polycarbonate, polyarylester and resol widely.

Uses

Bisphenol TMC(1,1-Bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane) is a bisphenol derivative used in the preparation of polycarbonate, polyester and epoxy resins.

Synthesis

The synthesis of 1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE is as follows:112.8 g (1.2 mol) of phenol, 16.9 g of water, 0.5 g of 75% aqueous solution of phosphoric acid and 7.2 g of BPTMCP crystals were placed in a one liter capacity four-necked flask provided with a thermometer, a dropping funnel, a reflux condenser and a stirrer to prepare a slurry. The slurry was adjusted at a temperature of 20° C. After the inside the flask was replaced by nitrogen gas, hydrogen chloride gas was introduced into the flask under stirring. The gas composition in the reaction vessel was analyzed and the volume concentration of hydrogen chloride gas was adjusted at 80%. 4.2 g of 15% aqueous solution of sodium methyl mercaptide was added dropwise to the slurry while the slurry was maintained at a temperature of 20° C., and then a mixture of 112.8 g (1.2 mol) of phenol and 42.0 g (0.3 mol) of TMC was added dropwise to the slurry over a period of six hours. The reaction mixture was found to increase in temperature during the addition, and when the addition was completed, the temperature was found to be 40° C. Then, the reaction was further continued at a temperature of 40° C. for anther three hours under stirring until completion. The reaction mixture was found to be slurry throughout the reaction from the start of the reaction when the mixture of phenol and TMC was added dropwise to the slurry to the completion of the reaction. The resulting reaction mixture was analyzed by liquid chromatography. The production yield (mol of BPTMC produced/mol of starting TMC used) was found 92.9%.

Bisphenol TMC Preparation Products And Raw materials

Raw materials

Preparation Products

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Bisphenol TMC Suppliers

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View Lastest Price from Bisphenol TMC manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Bisphenol TMC 129188-99-4
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-17
Henan Aochuang Chemical Co.,Ltd.
Product
1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE 129188-99-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-20
airuikechemical co., ltd.
Product
Bisphenol TMC 129188-99-4
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08

129188-99-4, Bisphenol TMCRelated Search:


  • 1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
  • 1,1-BIS(4-HYDROXYPHENYL)PROPANEBIS(2-HYDROXYPROPYL)ETHER
  • 4,4'-(3,3,5-Trimethyl-1,1-cyclohexanediyl)bisphenol
  • 4,4'-(3,3,5-Trimethylcyclohexane-1,1-diyl)bisphenol
  • 4,4'-(3,3,5-Trimethylcyclohexylidene)bisphenol
  • 4,4'-(3,3,5-Trimethylcyclohexylidene)diphenol
  • 3,3,5-TriMethyl-1,1-bis(4-hydroxyphenyl)cyclohexane
  • Bis(4-hydroxyphenyl)-3,3,5-triMethylcyclohexane
  • Bisphenol TMC
  • BISP-TMC
  • BPTMC
  • 4,4'-(3,3,5-Trimethylcyclohexane-1,1-diyl)diphenol
  • Phenol,4,4'-(3,3,5-trimethylcyclohexylidene)bis-
  • Bisphenol TMC,BPTMC
  • Bisphenol TMC Solution
  • Bisphenol TMC@10 mg/mL in Methanol
  • 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol
  • 1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCY
  • Bisphenol TMC in acetonitrile
  • Bisphenol TMC 100 μg/mL in Methanol
  • 129188-99-4
  • Aromatics
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Aromatics, Pharmaceuticals, Intermediates & Fine Chemicals