m-Iodobenzylchloride
- Product Name
- m-Iodobenzylchloride
- CAS No.
- 60076-09-7
- Chemical Name
- m-Iodobenzylchloride
- Synonyms
- 3-iodobenzylchloride;m-Iodobenzylchloride;1-(ChloroMethyl)-3-iodobenzene;Benzene, 1-(chloromethyl)-3-iodo-
- CBNumber
- CB81454929
- Molecular Formula
- C7H6ClI
- Formula Weight
- 252.48
- MOL File
- 60076-09-7.mol
m-Iodobenzylchloride Property
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C587950
- Product name
- 1-(Chloromethyl)-3-iodobenzene
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 8955AB
- Product name
- 1-(Chloromethyl)-3-iodobenzene
- Packaging
- 250mg
- Price
- $136
- Updated
- 2021/12/16
- Product number
- HCH0362310
- Product name
- 1-(CHLOROMETHYL)-3-IODOBENZENE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.8
- Updated
- 2021/12/16
- Product number
- 8955AB
- Product name
- 1-(Chloromethyl)-3-iodobenzene
- Packaging
- 25g
- Price
- $586
- Updated
- 2021/12/16
- Product number
- A124109
- Product name
- 1-(Chloromethyl)-3-iodobenzene
- Purity
- 95%
- Packaging
- 100mg
- Price
- $38
- Updated
- 2021/12/16
m-Iodobenzylchloride Chemical Properties,Usage,Production
Synthesis
57455-06-8
60076-09-7
General procedure for the synthesis of 1-(chloromethyl)-3-iodobenzene from 3-iodobenzyl alcohol: 3-iodobenzyl alcohol (600 mg, 2.56 mmol) was dissolved in dichloromethane (DCM, 3 mL), and thionyl chloride (3 mL, 41.3 mmol) was added, and the reaction was stirred for 18 hours at room temperature. Subsequently, thionyl chloride (1 mL, 13.7 mmol) was added and the reaction mixture was heated to reflux for 12 hours. Upon completion of the reaction, the cooled solution was alkalized with 50% sodium hydroxide solution, diluted with water and extracted with dichloromethane. The organic phases were combined, dried with anhydrous magnesium sulfate, filtered and concentrated to give a clarified slurry. After standing, the slurry crystallized to give 3-iodobenzyl chloride as a white solid (650 mg, quantitative yield).
References
[1] Patent: WO2011/86085, 2011, A1. Location in patent: Page/Page column 39-40
[2] Recueil des Travaux Chimiques des Pays-Bas, 1923, vol. 42, p. 522
[3] Patent: EP1386913, 2004, A1. Location in patent: Page 94
[4] Patent: WO2017/72021, 2017, A1. Location in patent: Page/Page column 76
m-Iodobenzylchloride Preparation Products And Raw materials
Raw materials
Preparation Products
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