5-bromo-1-nitro-naphthalene
- Product Name
- 5-bromo-1-nitro-naphthalene
- CAS No.
- 5328-76-7
- Chemical Name
- 5-bromo-1-nitro-naphthalene
- Synonyms
- 5-bromo-1-nitro-naphthalene;Naphthalene, 1-bromo-5-nitro-;1-Bromo-5-nitronaphthalene96%
- CBNumber
- CB81465626
- Molecular Formula
- C10H6BrNO2
- Formula Weight
- 252.06
- MOL File
- 5328-76-7.mol
5-bromo-1-nitro-naphthalene Property
- Melting point:
- 121 °C
- Boiling point:
- 363.8±17.0 °C(Predicted)
- Density
- 1.662±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder
- color
- Light brown to brown
Safety
- HS Code
- 2904990090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B697998
- Product name
- 1-Bromo-5-nitronaphthalene
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- J53153
- Product name
- 1-Bromo-5-nitronaphthalene
- Packaging
- 5g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 143405
- Product name
- 1-Bromo-5-nitronaphthalene
- Purity
- 97%
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- V6445
- Product name
- 1-Bromo-5-nitronaphthalene
- Packaging
- 5g
- Price
- $81
- Updated
- 2021/12/16
- Product number
- V6445
- Product name
- 1-Bromo-5-nitronaphthalene
- Packaging
- 25g
- Price
- $214
- Updated
- 2021/12/16
5-bromo-1-nitro-naphthalene Chemical Properties,Usage,Production
Synthesis
86-57-7
5328-76-7
The general procedure for the synthesis of 1-bromo-5-nitronaphthalene from 1-nitronaphthalene is as follows: 77.5 g (0.485 mol) of bromine was added slowly and dropwise to a stirred mixture of 86 g (0.5 mol) of 1-nitronaphthalene and 0.8-1.0 g of reduced iron powder over a period of 30 min, while the reaction temperature was maintained at 80-85°C. The reaction was carried out in the following manner. After about one hour, the reaction mixture crystallized directly when gas escape ceased. Subsequently, one crystallization was carried out with ethanol and two more with Sorit A from acetone. An average of 52.0 g of a fine yellow needle-like product was obtained with a melting point of 121-122°C (41% yield); the literature reports a melting point of 122.5°C.
References
[1] New Journal of Chemistry, 2005, vol. 29, # 4, p. 579 - 586
[2] Chemistry Letters, 2015, vol. 44, # 6, p. 743 - 745
[3] Angewandte Chemie - International Edition, 2008, vol. 47, # 32, p. 6062 - 6064
[4] Journal of Organic Chemistry, 2017, vol. 82, # 7, p. 3873 - 3879
[5] Journal of Organic Chemistry, 1949, vol. 14, p. 111,114
5-bromo-1-nitro-naphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
5-bromo-1-nitro-naphthalene Suppliers
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
View Lastest Price from 5-bromo-1-nitro-naphthalene manufacturers
- Product
- 5-bromo-1-nitro-naphthalene 5328-76-7
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%MIN
- Supply Ability
- ASK
- Release date
- 2020-01-07