methyl 3-(4-bromophenyl)propanoate

Product Name: methyl 3-(4-bromophenyl)propanoate
CAS No.: 75567-84-9
Chemical Name: methyl 3-(4-bromophenyl)propanoate
Synonyms: ThebroMoMethyl propionate;3-(4-broMophenyl)propionate;Methyl 3-(4-BroMophenyl)propionate;methyl 3-(4-bromophenyl)propanoate;Methyl 3-(4-Bromophenyl)propionate >4-bromobenzenepropanoic acid methyl ester;3-(4-Bromophenyl)propionic acid methyl ester;3-(4-bromophenyl)propanoic acid methyl ester;Benzenepropanoic acid, 4-broMo-, Methyl ester
CBNumber: CB81563919
Molecular Formula: C10H11BrO2
Formula Weight: 243.1
MOL File: 75567-84-9.mol

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methyl 3-(4-bromophenyl)propanoate Property

Boiling point:: 92℃/0.4Torr
Density: 1.389±0.06 g/cm3(Predicted)
refractive index: 1.5360 to 1.5400
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: Colorless to pale yellow

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Safety

HS Code: 2916.39.7900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2588
Product name: Methyl 3-(4-Bromophenyl)propionate
Purity: >98.0%(GC)
Packaging: 1g
Price: $32
Updated: 2025/07/31

TCI Chemical

Product number: M2588
Product name: Methyl 3-(4-Bromophenyl)propionate
Purity: >98.0%(GC)
Packaging: 5g
Price: $98
Updated: 2025/07/31

TRC

Product number: M295970
Product name: Methyl3-(4-bromophenyl)propanoate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 074741
Product name: Methyl 3-(4-bromophenyl)propanoate
Purity: 95+%
Packaging: 1g
Price: $116
Updated: 2021/12/16

Matrix Scientific

Product number: 074741
Product name: Methyl 3-(4-bromophenyl)propanoate
Purity: 95+%
Packaging: 10g
Price: $429
Updated: 2021/12/16

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methyl 3-(4-bromophenyl)propanoate Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 4709, 1989 DOI: 10.1016/S0040-4039(01)80781-4

Synthesis

1643-30-7

75567-84-9

To a 250 mL round bottom flask was added 3-(4-bromophenyl)propionic acid (5 g, 21.83 mmol, 1.00 equiv) and methanol (50 mL). Thionyl chloride (7.76 g, 65.23 mmol, 5.30 eq.) was added slowly and dropwise with stirring. The reaction mixture was stirred at 70 °C for 2 hours. Upon completion of the reaction, the reaction was quenched by the addition of a water/ice mixture. The aqueous phase was extracted with ethyl acetate (200 mL × 3), the organic phases were combined, washed sequentially with brine (100 mL × 2), dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography with petroleum ether:ethyl acetate (5:2, v/v) as eluent to afford methyl 4-bromo-3-phenylpropionate (4.84 g, 91% yield) as a colorless oil.

References

[1] Patent: WO2018/39386, 2018, A1. Location in patent: Page/Page column 291; 292

methyl 3-(4-bromophenyl)propanoate Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl 3-(4-bromophenyl)propanoate Suppliers

Americas 1 Canada 1 China 97 Europe 1 Germany 2 India 4 Japan 1 United Kingdom 1 United States 19 Global 127

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View Lastest Price from methyl 3-(4-bromophenyl)propanoate manufacturers

Career Henan Chemical Co

Product: methyl 3-(4-bromophenyl)propanoate 75567-84-9
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-24

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75567-84-9