Reaction
ChemicalBook > CAS DataBase List > ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

Reaction
Product Name
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
CAS No.
192139-92-7
Chemical Name
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
Synonyms
RuCL;TsDPEN;RuCl[(R,R)-Tsdpen](p-cymene);RuCl(p-cymene)[(R,R)-Ts-DPEN];Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);(R,R)-N-;R)-2-AMINO-1;[(R,R)-Tsdpen](p-cymene);RuCl (cymene)[(R,R)-TsDPEN];CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
CBNumber
CB81564668
Molecular Formula
C21H21ClN2O2RuS.C10H14
Formula Weight
636.219
MOL File
192139-92-7.mol
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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Property

Melting point:
215 °C
storage temp. 
2-8°C
solubility 
Deuterated Chloroform, DMF
form 
solid
color 
yellow to dark brown
optical activity
[α]20/D 116°, c = 0.1 in chloroform
Sensitive 
air sensitive
InChIKey
AZFNGPAYDKGCRB-MNPNNRAMNA-M
SMILES
C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r|
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Safety

WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
930008
Product name
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging
250MG
Price
$67.6
Updated
2024/03/01
Sigma-Aldrich
Product number
930008
Product name
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging
1G
Price
$172
Updated
2024/03/01
Sigma-Aldrich
Product number
703907
Product name
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging
100mg
Price
$28.2
Updated
2024/03/01
Sigma-Aldrich
Product number
703907
Product name
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging
500mg
Price
$102
Updated
2024/03/01
TCI Chemical
Product number
R0125
Product name
RuCl[(R,R)-Tsdpen](p-cymene)
Purity
>90%(HPLC)
Packaging
200mg
Price
$49
Updated
2024/03/01
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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Usage,Production

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Orange to brown powder

Uses

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

  • Quinolines
  • N-Alkyl ketimines
  • Antitumor and antiproliferative derivatives of natural products isolated from bacteria
  • Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

General Description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Suppliers

Belgium 1 China 153 Germany 1 India 5 Japan 2 Switzerland 1 United Kingdom 1 United States 9 Global 173
Eurolabs Limited
Tel
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Fax
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Country
United Kingdom
ProdList
6309
Advantage
46
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View Lastest Price from ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE manufacturers

Hangzhou ICH Biofarm Co., Ltd
Product
RuCl[(R,R)-Tsdpen](p-cymene) 192139-92-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.0%min
Supply Ability
800kg
Release date
2023-06-09
Hangzhou ICH Biofarm Co., Ltd
Product
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE 192139-92-7
Price
US $0.00/kg
Min. Order
1kg
Purity
98.00%
Supply Ability
200kg
Release date
2023-06-28
Career Henan Chemical Co
Product
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE 192139-92-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5kg
Release date
2019-07-03

192139-92-7, ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDERelated Search:

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl[(S,S)-FsDPEN](p-cymene) Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene) tBuXPhos Pd G1 (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

  • ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
  • RuCl(p-cymene)[(R,R)-Ts-DPEN]
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
  • (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-<br />cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
  • Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene)
  • ((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride
  • Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS
  • Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene)
  • RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-
  • [((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM
  • TsDPEN
  • (R,R)-N-
  • RuCl[(R,R)-Tsdpen](p-cymene)
  • ((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride
  • [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-
  • [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)]
  • RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98%
  • [(R,R)-Tsdpen](p-cymene)
  • RuCL
  • Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
  • [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)
  • Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH
  • RuCl (cymene)[(R,R)-TsDPEN]
  • 2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
  • R)-2-AMINO-1
  • ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p...
  • [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide
  • (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro
  • [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)
  • <font color="#ff0000">192139-92-7</font>
  • [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide
  • RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
  • 192139-92-7
  • C31H35ClN2O2RuS
  • Ru
  • organometallic complex