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TETRABROMO-THIENO[3,2-B]THIOPHENE

Product Name
TETRABROMO-THIENO[3,2-B]THIOPHENE
CAS No.
124638-53-5
Chemical Name
TETRABROMO-THIENO[3,2-B]THIOPHENE
Synonyms
perbromothieno[3,2-b]thiophen;Perbromothieno[3,2-b]thiophene;TETRABROMO-THIENO[3,2-B]THIOPHENE;Tetrabromothiopheno [3,2-B] thiophene;2,3,5,6-TetrabroMothieno[3,2-b]thiophene;Thieno[3,2-b]thiophene,2,3,5,6-tetrabromo-.;TIANFU CHEM-- TETRABROMO-THIENO[3,2-B]THIOPHENE;2,3,5,6-Tetrabromothieno[3,2-b]thiophene
CBNumber
CB8166722
Molecular Formula
C6Br4S2
Formula Weight
455.81
MOL File
124638-53-5.mol
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TETRABROMO-THIENO[3,2-B]THIOPHENE Property

Melting point:
232.0 to 236.0 °C
Boiling point:
443.2±40.0 °C(Predicted)
Density 
2.725±0.06 g/cm3(Predicted)
storage temp. 
Storage temp. 2-8°C
form 
powder to crystal
color 
White to Light yellow
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Safety

HS Code 
2934.99.4400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2772
Product name
2,3,5,6-Tetrabromothieno[3,2-b]thiophene
Purity
>98.0%(GC)
Packaging
1g
Price
$254
Updated
2025/07/31
TRC
Product number
P288403
Product name
Perbromothieno[3,2-b]thiophene
Packaging
50mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
099390
Product name
Perbromothieno[3,2-b]thiophene
Purity
95+%
Packaging
250mg
Price
$265
Updated
2021/12/16
AK Scientific
Product number
4683AA
Product name
Perbromothieno[3,2-b]thiophene
Packaging
1g
Price
$550
Updated
2021/12/16
Matrix Scientific
Product number
099390
Product name
Perbromothieno[3,2-b]thiophene
Purity
95+%
Packaging
1g
Price
$588
Updated
2021/12/16
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TETRABROMO-THIENO[3,2-B]THIOPHENE Chemical Properties,Usage,Production

Synthesis

251-41-2

124638-53-5

S1. Thieno[3,2-b]thiophene (5 g, 35.7 mmol) was dissolved in a solvent mixture of glacial acetic acid (36 ml) and chloroform (10 ml). Bromine (28.5 g, 180.56 mmol) was added slowly dropwise at room temperature and stirring was continued for 30 min after completion of the dropwise addition. The reaction mixture was then heated to 78°C refluxing overnight. After completion of the reaction, it was cooled to room temperature and the reaction mixture was washed with water to precipitate a white solid product. The product was washed sequentially three times each with water and methanol and finally dried under vacuum at room temperature to afford tetrabromothieno[3,2-b]thiophene (Compound 1) as a white solid with mass spectrometry detection [M+] = 455.0 in 95% yield.

References

[1] Patent: CN106188090, 2016, A. Location in patent: Paragraph 0086
[2] Patent: CN107056798, 2017, A. Location in patent: Paragraph 0055; 0056; 0057
[3] Patent: WO2016/92065, 2016, A1. Location in patent: Page/Page column 21
[4] Journal of Materials Chemistry C, 2018, vol. 6, # 16, p. 4471 - 4478
[5] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 5, p. 1547 - 1555

TETRABROMO-THIENO[3,2-B]THIOPHENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from TETRABROMO-THIENO[3,2-B]THIOPHENE manufacturers

Career Henan Chemical Co
Product
TETRABROMO-THIENO[3,2-B]THIOPHENE 124638-53-5
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
500g; 1kg; 25kg
Release date
2020-01-10

124638-53-5, TETRABROMO-THIENO[3,2-B]THIOPHENERelated Search:


  • TETRABROMO-THIENO[3,2-B]THIOPHENE
  • Perbromothieno[3,2-b]thiophene
  • Thieno[3,2-b]thiophene,2,3,5,6-tetrabromo-.
  • 2,3,5,6-Tetrabromothieno[3,2-<i>b</i>]thiophene
  • 2,3,5,6-TetrabroMothieno[3,2-b]thiophene
  • perbromothieno[3,2-b]thiophen
  • TIANFU CHEM-- TETRABROMO-THIENO[3,2-B]THIOPHENE
  • Tetrabromothiopheno [3,2-B] thiophene
  • 124638-53-5
  • C6Br4S2