COPPER(II) TRIFLUOROMETHANESULFONATE
Reaction- Product Name
- COPPER(II) TRIFLUOROMETHANESULFONATE
- CAS No.
- 34946-82-2
- Chemical Name
- COPPER(II) TRIFLUOROMETHANESULFONATE
- Synonyms
- Cu(OTf)2;COPPER(II) TRIFLATE;copper(II) bis(trifluoromethanesulfonate);COPPER TRIFLATE;CUPRIC TRIFLUOROMETHANESULFONATE;COPPER(II) TRIFLUOROMETHANESULPHONATE;Bis(((trifluoromethyl)sulfonyl)oxy)copper;Copper(II) trifL;CUPRIC-2-TRIFLATE;Copper (Ii) Trifluorome
- CBNumber
- CB8184128
- Molecular Formula
- C2CuF6O6S2
- Formula Weight
- 361.68
- MOL File
- 34946-82-2.mol
COPPER(II) TRIFLUOROMETHANESULFONATE Property
- Melting point:
- ≥300 °C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Water (Slightly)
- form
- Powder
- color
- White to slightly blue or light gray
- Water Solubility
- Soluble in water.
- Sensitive
- Hygroscopic
- Hydrolytic Sensitivity
- 6: forms irreversible hydrate
- BRN
- 4028198
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 - Stability:
- hygroscopic
- InChIKey
- SBTSVTLGWRLWOD-UHFFFAOYSA-L
- CAS DataBase Reference
- 34946-82-2(CAS DataBase Reference)
Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45-27
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 3-10
- Hazard Note
- Irritant/Hygroscopic
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29049085
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 283673
- Product name
- Copper(II) trifluoromethanesulfonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $152
- Updated
- 2024/03/01
- Product number
- 283673
- Product name
- Copper(II) trifluoromethanesulfonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $427
- Updated
- 2024/03/01
- Product number
- T1292
- Product name
- Copper(II) Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $24
- Updated
- 2024/03/01
- Product number
- T1292
- Product name
- Copper(II) Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $72
- Updated
- 2024/03/01
- Product number
- 040133
- Product name
- Copper(II) trifluoromethanesulfonate, 99% min
- Packaging
- 10g
- Price
- $116
- Updated
- 2024/03/01
COPPER(II) TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production
Reaction
- Ring-Opening of epoxides and aziridines.
- Asymmetric conjugate addition of organozinc reagents to α,β-unsaturated ketones.
- Electrophilic addition of olefins.
- Asymmetric aziridination of olefins.
- Asymmetric cycloadditions and aldol condensations.
- Asymmetric Kharasch oxidation.
- Asymmetric Michael addition of enamides.
- Asymmetric O-H or O-R insertion reactions.
- Enantioselective intramolecular aminooxygenation of alkenes.
- Enantioselective addition of dialkylzinc reagents to N-acylpyridinium salts.
- Pd-catalyzed C-H functionalizations of oximes with arylboronic acids.
- Used as a Lewis acid in the Nazarov cyclization.
- Catalyst in the diacetoxylation olefins.
- Catalyst in the meta-selective direct arylation of α-aryl carbonyl compounds.
- Catalyst in the three-component coupling of amines, aldehydes, and alkynes.
Chemical Properties
white to slightly blue or light grey cryst. powder
Uses
Copper(II) trifluoromethanesulfonate is a mild lewis acid. It is used as catalyst which promotes dehydration of alcohols and diols to alkenes at ambient temperatures. It is widely used to generate carbenoid species from ?-diazo esters and ketones, via in situ reduction to the Cu(I) species. It is also promotes the reaction between diazo esters and imines to give aziridines. It catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes, Friedel-Crafts alkylation, acylation reactions of aromatics and addition of trimethylsilyl cyanide to carbonyl compounds.
Purification Methods
Dissolve it in MeCN, add dry Et2O until cloudy and cool at -20o in a freezer. The light blue precipitate is collected and dried in a vacuum oven at 130o/20mm for 8hours. It has 737nm ( 22.4 max M1cm -1) in AcOH. [Salomon & Kochi J Am Chem Soc 95 330 1973]. It has also been dried in a vessel at 0.1Torr by heating with a Fischer burner [Andrist et al. J Org Chem 43 3422 1978]. It has been dried at 110-120o/5mm for 1hour before use and forms a *benzene complex which should be handled in a dry box because it is air sensitive [Kobayashi et al. Chem Pharm Bull Jpn 28 262 1980, Salomon & Kochi J Am Chem Soc 95 330 1973]. [Beilstein 3 IV 34.]
COPPER(II) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
COPPER(II) TRIFLUOROMETHANESULFONATE Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
View Lastest Price from COPPER(II) TRIFLUOROMETHANESULFONATE manufacturers
- Product
- COPPER(II) TRIFLUOROMETHANESULFONATE 34946-82-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-03-10
- Product
- COPPER(II) TRIFLUOROMETHANESULFONATE 34946-82-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-18
- Product
- COPPER(II) TRIFLUOROMETHANESULFONATE 34946-82-2
- Price
- US $10.00/KG
- Min. Order
- 100KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-12-03