Sodium trifluoromethanesulfonate
- Product Name
- Sodium trifluoromethanesulfonate
- CAS No.
- 2926-30-9
- Chemical Name
- Sodium trifluoromethanesulfonate
- Synonyms
- SODIUM TRIFLATE;Sodium trifluoride;Sodium trifluorometha;Sodium trifluomethanesulfonate;SODIUM TRIFLUOROMETHANESULFONATE;SODIUM TRIFLUOROMETHANESULPHONATE;Sodiumtrifluoromethanesulphonate98%;Sodium trifluoromethanesulfonate,98%;SodiuM trifluoroMethanesulfonate 98%;Sodium trifluoromethanesulphonate 98%
- CBNumber
- CB5330814
- Molecular Formula
- CF3NaO3S
- Formula Weight
- 172.06
- MOL File
- 2926-30-9.mol
Sodium trifluoromethanesulfonate Property
- Melting point:
- 253-255 °C (lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- White to off-white
- Water Solubility
- soluble
- Sensitive
- Hygroscopic
- Hydrolytic Sensitivity
- 0: forms stable aqueous solutions
- BRN
- 3728797
- InChIKey
- KKVTYAVXTDIPAP-UHFFFAOYSA-M
- CAS DataBase Reference
- 2926-30-9(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,C,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- F
- 3-10
- Hazard Note
- Corrosive
- TSCA
- No
- HS Code
- 29049090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 367907
- Product name
- Sodium trifluoromethanesulfonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $72
- Updated
- 2024/03/01
- Product number
- 367907
- Product name
- Sodium trifluoromethanesulfonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $219
- Updated
- 2024/03/01
- Product number
- T1550
- Product name
- Sodium Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $31
- Updated
- 2024/03/01
- Product number
- T1550
- Product name
- Sodium Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $89
- Updated
- 2024/03/01
- Product number
- 020837
- Product name
- Sodium trifluoromethanesulfonate
- Packaging
- 2g
- Price
- $20.65
- Updated
- 2024/03/01
Sodium trifluoromethanesulfonate Chemical Properties,Usage,Production
Description
Sodium trifluoromethanesulfonate is commonly known as trifluoromethanesulfonic acid or TFMS. Possessing unique properties, TFMS is water-soluble, anionic, and boasts a range of valuable attributes. As a colorless, odorless, and non-toxic substance, TFMS finds widespread use as a reagent in organic synthesis, a catalyst in industrial applications, and a buffer in various biochemical experiments. In scientific research, TFMS stands out due to its robust acidity, enabling it to act as a potent catalyst in organic synthesis. Additionally, it effectively serves as a reliable buffer at pH levels, ensuring precise pH maintenance in biochemical experiments. As an anionic compound, TFMS functions as a strong acid in solution, facilitating the donation of protons to other molecules, thus reducing the pH.
Chemical Properties
White to off-white powder
Uses
Sodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).
Uses
Sodium trifluoromethanesulfonate can be employed as a reagent for the preparation of:
- Aryl fluorides via silver-catalyzed fluorination of arylstannanes.
- Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate.
It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides.
Preparation
Sodium trifluoromethanesulfonate is prepared by adding a slight excess of sodium sulfate to an aqueous solution of barium trifluoromethanesulfonate. The reaction mixture is stirred for several minutes and allowed to stand for one day, and the white precipitate of barium sulfate is removed by filtration. The clear filtrate is evaporated to dryness, and the solid product is recrystallized from dry acetone. The salt is dried under vacuum at 110?°C.1 Barium trifluoromethanesulfonate can be easily prepared from aqueous trifluoromethanesulfonic acid and barium carbonate. Other methods include the preparation of sodium trifluoromethane sulfonate from sodium dithionite and bromotrifluoromethane and its oxidation to sodium trifluoromethane sulfonate using hydrogen peroxide.
General Description
Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.
Solubility in organics
soluble in water, alcohol, acetonitrile, N,N-dimethylformamide, and most highly polar organic solvents.
Sodium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Sodium trifluoromethanesulfonate manufacturers
- Product
- Sodium trifluoromethanesulfonate 2926-30-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- Sodium trifluoromethanesulfonate 2926-30-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%+
- Supply Ability
- 100 tons
- Release date
- 2020-01-13
- Product
- Sodium trifluoromethanesulfonate 2926-30-9
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2020-01-07