YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
- Product Name
- YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
- CAS No.
- 54761-04-5
- Chemical Name
- YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
- Synonyms
- YB(OTF)3;YTTERBIUM TRIFLUOROMETHANESULFONATE;YTTERBIUM(III) TRIFLATE HYDRATE;YTTERBIUM (III) TRIFLUOROMETHANESULFONATE;YTTERBIUM TRIFLUOROMETHANESULPHONATE;Yb(TFA)3;Ytterbiumtriflate;YTTERBIUM (III) TRIFLATE;Acid Ytterbium(III) Salt;YTTERBIUM TRIFLATE HYDRATE
- CBNumber
- CB7142534
- Molecular Formula
- C3F9O9S3Yb
- Formula Weight
- 620.24
- MOL File
- 54761-04-5.mol
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Property
- Melting point:
- 8 °C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Methanol
- form
- Powder
- color
- White to Off-White
- Sensitive
- Hygroscopic
- Hydrolytic Sensitivity
- 6: forms irreversible hydrate
- Merck
- 14,10106
- Stability:
- Hygroscopic
- CAS DataBase Reference
- 54761-04-5(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 430595
- Product name
- Ytterbium(III) trifluoromethanesulfonate
- Purity
- 99.99%
- Packaging
- 1g
- Price
- $35.5
- Updated
- 2024/03/01
- Product number
- 430595
- Product name
- Ytterbium(III) trifluoromethanesulfonate
- Purity
- 99.99%
- Packaging
- 5g
- Price
- $96.6
- Updated
- 2024/03/01
- Product number
- T1610
- Product name
- Ytterbium(III) Trifluoromethanesulfonate Hydrate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $56
- Updated
- 2024/03/01
- Product number
- T1610
- Product name
- Ytterbium(III) Trifluoromethanesulfonate Hydrate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $263
- Updated
- 2024/03/01
- Product number
- Y120010
- Product name
- Ytterbium(III) trifluoromethanesulfonate
- Packaging
- 25g
- Price
- $325
- Updated
- 2021/12/16
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Chemical Properties,Usage,Production
Uses
Ytterbium(III) Trifluoromethanesulfonate functions as a catalyst in the organic synthesis of heterocycles. Also functions as a Lewis acid in variety of organic reactions.
Uses
Versatile rare earth metal catalyst in organic synthesis.
Preparation
Ytterbium(III) Trifluoromethanesulfonate is prepared by addition of an excess of ytterbium(III) oxide (commercially available, 99.9%) to an aqueous solution of Trifluoromethanesulfonic Acid (50% v/v) followed by heating at boiling for 0.5-1 h. The mixture is then purified by filtration to remove unreacted ytterbium oxide; residual water is removed under reduced pressure. The resultant hydrate is dried by heating under vacuum (1 mmHg) at 180 to 200 °C for 48 h. The reagent is then used without further purification.[1] The organoytterbium reagent is prepared at -78 °C from Yb(OTf)3 and organolithiums or organomagnesiums.[2]
reaction suitability
core: ytterbium
reagent type: catalyst
storage
Ytterbium(III) Trifluoromethanesulfonate forms hydrates in aqueous media in the presence of amines; however, it survives mild aqueous workup.
References
1. Forsberg, J. H.; Spaziano, V. T.; Balasubramanian, T. M.; Liu, G. K.; Kinsley, S. A.; Duckworth, C. A.; Poteruca, J. J.; Brown, P. S.;
Miller, J. L. JOC 1987, 52, 1017.
2. Molander, G. A.; Burkhardt, E. R.; Weinig, P. JOC 1990, 55, 4990
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE manufacturers
- Product
- YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE 54761-04-5
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2020-01-09