Aluminum trifluoromethanesulfonate

Product Name: Aluminum trifluoromethanesulfonate
CAS No.: 74974-61-1
Chemical Name: Aluminum trifluoromethanesulfonate
Synonyms: ALUMINUM TRIFLATE;ALUMINIUM TRIFLATE;Aluminium(III) triflate;uminum trifL;ALUMINUM TRIFLUOROMETHANESULFONATE;ALUMINIUM TRIFLUOROMETHANESULFONATE;Aluminum Trifluoromethanesulfonatec;ALUMINIUM TRIFLUOROMETHANESULPHONATE;Aluminumtrifluoromethanesulfonate,98%;Aluminiumtrifluoromethanesulphonate99%
CBNumber: CB7387584
Molecular Formula: CH4AlF3O3S
Formula Weight: 180.08
MOL File: 74974-61-1.mol

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Aluminum trifluoromethanesulfonate Property

Melting point:: 300 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in ether, acetone, acetonitrile, and diglyme; poorly soluble in nitromethane; sparingly soluble in SO2 and SO2 ClF.
form: Powder
color: White
Water Solubility: Insoluble in water.
Sensitive: Hygroscopic
Hydrolytic Sensitivity: 6: forms irreversible hydrate
Stability:: hygroscopic
InChI: InChI=1S/CHF3O3S.Al.3H/c2-1(3,4)8(5,6)7;;;;/h(H,5,6,7);;;;
InChIKey: GCRKPTQIRSZTMM-UHFFFAOYSA-N
SMILES: C(F)(F)(F)S(O)(=O)=O.[AlH3]
CAS DataBase Reference: 74974-61-1(CAS DataBase Reference)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/37/38
Safety Statements: 26-36/37/39-45-36
RIDADR: UN 3261 8/PG 3
WGK Germany: 3
Hazard Note: Corrosive
TSCA: No
HazardClass: 8
PackingGroup: III
HS Code: 29049020

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 515884
Product name: Aluminum trifluoromethanesulfonate
Purity: 99.9% trace metals basis
Packaging: 10g
Price: $124
Updated: 2025/07/31

Sigma-Aldrich

Product number: 515884
Product name: Aluminum trifluoromethanesulfonate
Purity: 99.9% trace metals basis
Packaging: 50g
Price: $392
Updated: 2025/07/31

Strem Chemicals

Product number: 13-1500
Product name: Aluminum trifluoromethanesulfonate, 99% (Aluminum triflate)
Packaging: 10g
Price: $114
Updated: 2024/03/01

Strem Chemicals

Product number: 13-1500
Product name: Aluminum trifluoromethanesulfonate, 99% (Aluminum triflate)
Packaging: 50g
Price: $448
Updated: 2024/03/01

GFS CHEMICALS

Product number: 11732
Product name: ALUMINUMTRIFLATE
Packaging: 25g
Price: $171.93
Updated: 2021/12/16

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Aluminum trifluoromethanesulfonate Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Lewis acid used as a catalyst for Friedel–Crafts, ketalization, nucleophilic substitution, hydroalkoxylation, methoxycarbonyla- tion, rearrangement, and epoxide ring-opening reactions.

Uses

Aluminum trifluoromethanesulfonate is used in pharmaceutical intermediates.

Preparation

Can be prepared from aluminum trichloride and tribromide by heating with triflic acid in anhydrous conditions. Preparations from triethylaluminum, aluminum carbide, and aluminum isopropoxide have also been described.

Reactions

Friedel-Crafts Reactions.
Aluminum trifluoromethanesulfonate has been used for the Friedel-Crafts alkylation reaction of toluene with isopropyl and tert-butyl chlorides (eq 1), and for theacylationofbenzeneandtoluenewithacetylandbenzoylchlo- rides in low to moderate yields. Intramolecular Friedel-Crafts acylation of an aromatic compound with Meldrum’s acid has also been reported using catalytic amounts of Al(OTf) 3 . Acylation of 2-methoxynaphthalene with acetic anhydride has been reported using Al(OTf) 3 and lithium perchlorate as an additive to afford the corresponding 6-acetylated adduct in 83% yield. Effective acylation of arenes with carboxylic acids has also been disclosed using polystyrene-supported Al(OTf)3.

reaction suitability

core: aluminum
reagent type: catalyst

Aluminum trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Aluminum trifluoromethanesulfonate Suppliers

Belgium 2 China 189 Europe 1 France 1 Germany 4 India 9 Japan 1 Singapore 1 Switzerland 1 United Kingdom 14 United States 34 Global 257

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View Lastest Price from Aluminum trifluoromethanesulfonate manufacturers

Hubei Lidu New Material Technology Co., Ltd

Product: ALUMINUM TRIFLUOROMETHANESULFONATE 74974-61-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 20TONS
Release date: 2025-11-04

RongNa Biotechnology Co.,Ltd

Product: Aluminum trifluoromethanesulfonate 74974-61-1
Price: US $10.00/ASSAYS
Min. Order: 1ASSAYS
Purity: 99%
Supply Ability: 1 ton
Release date: 2025-08-19

Shaanxi Didu New Materials Co. Ltd

Product: Aluminum trifluoromethanesulfonate 74974-61-1
Price: US $1.50/g
Min. Order: 1g
Purity: 99.0% Min
Supply Ability: 100 Tons
Release date: 2025-03-28

74974-61-1, Aluminum trifluoromethanesulfonateRelated Search:

Trifluoromethanesulfonic acid Tri(o-tolyl)phosphine CATECHOLBORANE Cesium RHENIUM Titanous chloride Bismuth(III) trifluoromethanesulfonate Lithium trifluoromethanesulfonate Zinc trifluoromethanesulfonate Lanthanum trifluoromethanesulfonate YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Sodium trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Trifluoromethanesulfonyl chloride SILVER TRIFLUOROMETHANESULFONATE Potassium trifluoromethanesulfonate PALLADIUM(II) TRIFLUOROACETATE 2-Bromoethyl trifluoromethanesulphonate

ALUMINIUM TRIFLATE

ALUMINIUM TRIFLUOROMETHANESULFONATE

ALUMINIUM TRIFLUOROMETHANESULPHONATE

ALUMINUM TRIFLATE

ALUMINUM TRIFLUOROMETHANESULFONATE

Aluminumtrifluoromethanesulfonate,99%(Aluminumtriflate)

Aluminium triflate~Trifluoromethanesulphonic acid aluminium salt

ALUMINUM TRIFLUOROMETHANESULFONATEALUMINUM TRIFLUOROMETHANESULFONATEALUMINUM TRIFLUOROMETHANESULFONATEALUMINUM TRIFLUOROMETHANESULFONATE

Aluminium trifluoromethanesulfonate,98%

Aluminumtrifluoromethanesulfonate,98%

trifluoromethanesulfonic acid aluminum salt

Aluminium trifluoromethanesulphonate 99%

Aluminiumtrifluoromethanesulphonate99%

ALUMINUM TRIFLUOROMETHANESULFONATE (ALUMINUM TRIFLATE)

ALUMINUM TRIFLUOROMETHANESULFONATE, 99.9 %

Aluminium(III)trifluoromethanesulphonate99%

Aluminium trifluoromethanesulfonate,99%

AluMinuM trifluoroMethanesulfonate,99% Al(CF3SO3)3

Aluminium(III) triflate

Aluminium(III) trifluoromethanesulphonate 99%

AluMinuM trifluoroMethanesulfonate 99.9% trace Metals basis

Aluminum tris(trifluoromethanesulfonate)

Tris(trifluoromethanesulfonato)aluminum

Aluminum trifluoromethanesulfonate, 98%, for synthesis

uminum trifL

Aluminum Trifluoromethanesulfonatec

ALUMINUM TRIFLUOROMETHANESULFONATE ISO 9001：2015 REACH

Aluminium(III) trifluoromethanesulphonate

74974-61-1

CF3SO33Al

3CF3O3SAl

C3AlF9O9S3

AlCF3SO33

AlSO3CF33

C3HAlF9O9S

C3F9O9S3Al

Aluminum

Catalysis and Inorganic Chemistry

metal triflate compounds

triflate