CATECHOLBORANE
- Product Name
- CATECHOLBORANE
- CAS No.
- 274-07-7
- Chemical Name
- CATECHOLBORANE
- Synonyms
- 1,3,2-BENZODIOXABOROLE;Benzo[1,3,2]dioxaborole;Catchelborane;1,3,2;C6H5BO2;O-dioxolane;Ctecholborane;CATECHOLBORANE;Catecholatoborane;Benzcatechinborane
- CBNumber
- CB2490830
- Molecular Formula
- C6H5BO2
- Formula Weight
- 119.91
- MOL File
- 274-07-7.mol
CATECHOLBORANE Property
- Melting point:
- 12 °C(lit.)
- Boiling point:
- 50 °C50 mm Hg(lit.)
- Density
- 1.125 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.507(lit.)
- Flash point:
- 36 °F
- storage temp.
- 2-8°C
- solubility
- Miscible with diethyl ether, tetrahydrofuran, dichloromethane, chloroform, carbon tetrachloride, toluene, and benzene.
- form
- liquid
- color
- Hazy Colourless
- Water Solubility
- Reacts with water.
- Sensitive
- Moisture Sensitive
- BRN
- 972072
- Stability:
- Hygroscopic
- InChIKey
- CENMEJUYOOMFFZ-UHFFFAOYSA-N
- CAS DataBase Reference
- 274-07-7(CAS DataBase Reference)
- EPA Substance Registry System
- 1,3,2-Benzodioxaborole (274-07-7)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-19-34-67-65-63-48/20-14-40-37
- Safety Statements
- 26-36/37/39-45-62-16-43
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 3
- F
- 1-10
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29209090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 188913
- Product name
- Catecholborane
- Purity
- 98%
- Packaging
- 25g
- Price
- $296
- Updated
- 2024/03/01
- Product number
- 188913
- Product name
- Catecholborane
- Purity
- 98%
- Packaging
- 100g
- Price
- $604
- Updated
- 2024/03/01
- Product number
- H30234
- Product name
- Catecholborane, 50% w/w in toluene (98% dry wt.)
- Packaging
- 100g
- Price
- $1008
- Updated
- 2021/12/16
- Product number
- H30234
- Product name
- Catecholborane, 50% w/w in toluene (98% dry wt.)
- Packaging
- 25g
- Price
- $306
- Updated
- 2021/12/16
- Product number
- 225762
- Product name
- Catecholborane solution
- Purity
- 1.0 M in THF
- Packaging
- 100ml
- Price
- $106
- Updated
- 2024/03/01
CATECHOLBORANE Chemical Properties,Usage,Production
Chemical Properties
CATECHOLBORANE is clear colorless solution
Uses
Catecholborane is used to prepare B-alkylcatecholboranes. It finds application for the preparation of amides and macrocyclic lactams from carboxylic acids. It is used as a stereoselective reducing agent to convert beta-hydroxy ketones to syn 1,3-diols. Further, it reacts with alkyne through hydroboration to form trans vinyl borane, which is a precursor to Suzuki reaction.
Uses
CATECHOLBORANE is used in the transition metal catalyzed hydroboration of alkenes.1,2,3
Purification Methods
It is a moisture-sensitive flammable liquid which is purified by distillation in a vacuum under a N2 atmosphere and stored under N2 at 0-4o. It liberates H2 when added to H2O or MeOH. A solution in THF, after 25hours at 25o, has residual hydride of 95% (under N2) and 80% (under air) [Brown & Gupta J Am Chem Soc 97 5249 1975].
CATECHOLBORANE Preparation Products And Raw materials
Raw materials
Preparation Products
CATECHOLBORANE Suppliers
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View Lastest Price from CATECHOLBORANE manufacturers
- Product
- CATECHOLBORANE 274-07-7
- Price
- US $1.90/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 ton
- Release date
- 2024-08-20
- Product
- CATECHOLBORANE 274-07-7
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- CATECHOLBORANE 274-07-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-26