ChemicalBook > CAS DataBase List > 2-CHLORO-1,3,2-BENZODIOXABOROLE

2-CHLORO-1,3,2-BENZODIOXABOROLE

Product Name
2-CHLORO-1,3,2-BENZODIOXABOROLE
CAS No.
55718-76-8
Chemical Name
2-CHLORO-1,3,2-BENZODIOXABOROLE
Synonyms
2-Chlorobenzo[d][1;?Chlorocatecholborane;B-CHLOROCATECHOLBORANE;SS-CHLOROCATECHOLBORANE;iBi-Chlorocatecholborane;BETA-CHLOROCATECHOLBORANE;B-Chlorocatecholborane 97%;2-Chlor-1,3,2-benzodioxaborol;2-CHLORO-1,3,2-BENZODIOXABOROLE;1,3,2-Benzodioxaborole, 2-chloro-
CBNumber
CB9333893
Molecular Formula
C6H4BClO2
Formula Weight
154.36
MOL File
55718-76-8.mol
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2-CHLORO-1,3,2-BENZODIOXABOROLE Property

Melting point:
56-58 °C (lit.)
Boiling point:
64 °C(Press: 10 Torr)
Density 
1.31±0.1 g/cm3(Predicted)
Flash point:
140 °F
storage temp. 
2-8°C
form 
powder to crystal
color 
White to Light yellow to Light red
BRN 
2093985
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14-34-37
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2925 4.1/PG 2
WGK Germany 
3
10-23
HS Code 
2915.40.5050
HazardClass 
8
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
362700
Product name
B-Chlorocatecholborane
Purity
97%
Packaging
5g
Price
$243
Updated
2024/03/01
TCI Chemical
Product number
C1669
Product name
B-Chlorocatecholborane
Packaging
5G
Price
$152
Updated
2024/03/01
TCI Chemical
Product number
C1669
Product name
B-Chlorocatecholborane
Packaging
25G
Price
$611
Updated
2024/03/01
TRC
Product number
C364528
Product name
2-​Chloro-​1,​3,​2-​benzodioxaborole
Packaging
100mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB160594
Product name
B-Chlorocatecholborane
Packaging
500mg
Price
$60
Updated
2021/12/16
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2-CHLORO-1,3,2-BENZODIOXABOROLE Chemical Properties,Usage,Production

Uses

B-Chlorocatecholborane can be used:

  • To prepare 2-arachidonoylglycerol by acetal cleavage of cis-arachidonoylbenzylidene glycerol.
  • To prepare metal boryl complexes (Rh and Ir complexes) through oxidative addition.
  • To remove the trityl group in one of the key steps for the synthesis of (?)-dictyostatin.

General Description

B-Chlorocatecholborane is a boron reagent and a Lewis acid, known to facilitate the borylative cyclization of alkynes to yield the borylated heterocycles. It is also used in the preparation of lactones, and thiophenes.

2-CHLORO-1,3,2-BENZODIOXABOROLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-1,3,2-BENZODIOXABOROLE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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TOKYO CHEMICAL INDUSTRY CO., LTD.
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Americas
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9ding chemical ( Shanghai) Limited
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86-021-52271987
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China
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View Lastest Price from 2-CHLORO-1,3,2-BENZODIOXABOROLE manufacturers

Career Henan Chemical Co
Product
2-CHLORO-1,3,2-BENZODIOXABOROLE 55718-76-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-08-20

55718-76-8, 2-CHLORO-1,3,2-BENZODIOXABOROLERelated Search:


  • SS-CHLOROCATECHOLBORANE
  • BETA-CHLOROCATECHOLBORANE
  • B-CHLOROCATECHOLBORANE
  • ?Chlorocatecholborane
  • 2-Chlor-1,3,2-benzodioxaborol
  • 2-CHLORO-1,3,2-BENZODIOXABOROLE
  • B-Chlorocatecholborane 97%
  • 2-Chlorobenzo[d][1,3,2]dioxaborole
  • 2-Chlorobenzo[d][1
  • 1,3,2-Benzodioxaborole, 2-chloro-
  • iBi-Chlorocatecholborane
  • 2- chloro -1,3,2- benzodioxa boron heterocyclic pentene
  • 55718-76-8
  • C6H4BClO2
  • B-Bromocatecholborane, etc.
  • B (Classes of Boron Compounds)
  • Synthetic Reagents
  • C-X Bond Formation (Halogen)
  • Haloboration
  • B (Classes of Boron Compounds)
  • B-Bromocatecholborane, etc.