ChemicalBook > CAS DataBase List > Trifluoromethanesulfonyl chloride

Trifluoromethanesulfonyl chloride

Product Name
Trifluoromethanesulfonyl chloride
CAS No.
421-83-0
Chemical Name
Trifluoromethanesulfonyl chloride
Synonyms
TRIFLYL CHLORIDE;PFC-MSC;Trifluoromethane chloride;TRIFLUOROMETHANESULFONYLCLORIDE;trifluoromethylsulfonyl chloride;Trifluoromethanesufonyl chloride;RIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromathanesulfonyl chloride;TRIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromethylsulphonyl chloride
CBNumber
CB4253800
Molecular Formula
CClF3O2S
Formula Weight
168.52
MOL File
421-83-0.mol
More
Less

Trifluoromethanesulfonyl chloride Property

Melting point:
-26 °C
Boiling point:
29-32 °C (lit.)
Density 
1.583 g/mL at 25 °C (lit.)
vapor pressure 
10.36 psi ( 20 °C)
refractive index 
n20/D 1.334(lit.)
Flash point:
32°C
storage temp. 
2-8°C
solubility 
Chloroform
form 
Liquid
color 
Clear colorless to faintly colored
Specific Gravity
1.583
Water Solubility 
Hydrolyzes with water.
Sensitive 
Lachrymatory
BRN 
1812016
InChIKey
GRGCWBWNLSTIEN-UHFFFAOYSA-N
CAS DataBase Reference
421-83-0(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
F 
10-21
Hazard Note 
Corrosive/Lachrymatory
HazardClass 
8
PackingGroup 
II
HS Code 
29049090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
164798
Product name
Trifluoromethanesulfonyl chloride
Purity
≥99%
Packaging
5g
Price
$79.3
Updated
2024/03/01
Sigma-Aldrich
Product number
164798
Product name
Trifluoromethanesulfonyl chloride
Purity
≥99%
Packaging
25g
Price
$263
Updated
2024/03/01
TCI Chemical
Product number
T1027
Product name
Trifluoromethanesulfonyl Chloride
Purity
>98.0%(GC)
Packaging
5g
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
T1027
Product name
Trifluoromethanesulfonyl Chloride
Purity
>98.0%(GC)
Packaging
25g
Price
$204
Updated
2024/03/01
Alfa Aesar
Product number
B21774
Product name
Trifluoromethanesulfonyl chloride
Purity
98%
Packaging
5g
Price
$72.9
Updated
2024/03/01
More
Less

Trifluoromethanesulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to faintly colored liquid

Uses

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

Application

Trifluoromethanesulfonyl chloride can be used as:
A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
A sulfonating agent for alcohols.
A chlorinating agent for carbanions.

Synthesis

Add 150g (1mol) of trifluoromethanesulfonic acid to the reactor equipped with thermometer, distillation device and mechanical stirrer, slowly add 435mL (6mol) of thionyl chloride under ice bath, and then add the catalyst N,N-dimethyl Formamide 7.36 (0.1 mol), slowly raise the temperature to room temperature, stir for half an hour, continue to heat up to 40°C, continue to stir, react for 12 hours, and then drop to room temperature after the reaction is complete.Subsequently, vacuum distillation was carried out at 110° C. and -0.1 to -0.08 MPa, and at the same time, the temperature was slowly raised to 50° C. to obtain 147 g of trifluoromethanesulfonyl chloride, with a yield of 87.5%.

Trifluoromethanesulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

N-Phenyl-bis(trifluoromethanesulfonimide)
More
Less

Trifluoromethanesulfonyl chloride Suppliers

Belgium 2 China 218 France 2 Germany 8 India 6 Japan 7 Russia 1 Switzerland 2 Ukraine 1 United Kingdom 10 United States 28 Global 285
Ji'nan Langhua Chemical Co. Ltd.
Tel
0531-85906691 18660816586
Fax
+86-0531-85906692
Email
325912680@qq.com
Country
China
ProdList
100
Advantage
50
SHANG FLUORO
Tel
021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
372
Advantage
60
Ningbo Jiaheshan New Material Co., LTD
Tel
13758655631
Email
2573039014@qq.com
Country
China
ProdList
15
Advantage
58
Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
More
Less

View Lastest Price from Trifluoromethanesulfonyl chloride manufacturers

airuikechemical co., ltd.
Product
trifluoromethanesulfonyl chloride 421-83-0
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-09
Shandong Deshang Chemical Co., Ltd.
Product
Trifluoromethanesulfonyl chloride 421-83-0
Price
US $10.00-7.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-14
Hebei Weibang Biotechnology Co., Ltd
Product
TRIFLUOROMETHANESULFONYL CHLORIDE 421-83-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-06

421-83-0, Trifluoromethanesulfonyl chloride Related Search:

TRIFLUOROMETHYL SULFINYL CHLORIDE (S)-(-)-Trityl glycidyl ether Cyhalothrin COPPER(II) TRIFLUOROMETHANESULFONATE Silver(I) trifluoromethanethiolate Silicon monoxide Bismuth(III) trifluoromethanesulfonate Lithium trifluoromethanesulfonate Zinc trifluoromethanesulfonate Lanthanum trifluoromethanesulfonate Aluminum trifluoromethanesulfonate YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Sodium trifluoromethanesulfonate Trifluoromethanesulfonic anhydride SILVER TRIFLUOROMETHANESULFONATE Potassium trifluoromethanesulfonate Trifluoromethanesulfonic acid Sodium trifluoromethanesulfinate

  • TRIFLUOROMETHANESULFONYL CHLORIDE
  • TRIFLUOROMETHANESULPHONYL CHLORIDE
  • TRIFLYL CHLORIDE
  • Methanesulfonyl chloride, trifluoro-
  • PFC-MSC
  • Trifluoromathanesulfonyl chloride
  • Trifluoromethanesulphonylchloride,99%
  • trifluoromethylsulfonyl chloride
  • Trifluoromethanesulphonyl chloride 99%
  • TRIFLUOROMETHANESULFONYLCLORIDE
  • TRIFLUOROMETHANESULFONYL CHLORIDE, 99+%
  • Trifluoromethanesulfonylchloride,98%
  • Trifluoromethylsulphonyl chloride
  • Trifluoromethanesulfonic acid chloride
  • Trifluoromethanesufonyl chloride
  • Trifluoromethylsulphonyl chloride 99%
  • TriMethylsilyltrilfluoroMethanesulfonate
  • TrifluoroMethanesulfonyl chloride, 99% 25GR
  • TRIFLUOROMETHANESULFONYL CHLORIDE FOR SY
  • Three fluorineMethane sulfonyl chloride
  • Trifluoromethanesulfonyl chloride, 99.5%
  • trifluoromethanesulfonyl chloride CClF3O2S
  • Trifluoromethane chloride
  • Trifluoromethanesulfonyl chloride, 98%, for synthesis
  • RIFLUOROMETHANESULFONYL CHLORIDE
  • Trifluoromethanesulfonyl Chloride, ≥ 98.0%
  • 421-83-0
  • 421-86-0
  • CClF3O2S
  • CF3SO2Cl
  • C3F4l2
  • CF3ClO2S
  • CClF3SO2
  • Protection and Derivatization
  • Protecting and Derivatizing Reagents
  • Others
  • Synthetic Reagents
  • Piperazine derivates
  • organofluorine compounds
  • Others
  • Protecting and Derivatizing Reagents
  • Protection and Derivatization