ChemicalBook > CAS DataBase List > Aluminum trifluoromethanesulfonate

Aluminum trifluoromethanesulfonate

Product Name
Aluminum trifluoromethanesulfonate
CAS No.
74974-61-1
Chemical Name
Aluminum trifluoromethanesulfonate
Synonyms
ALUMINUM TRIFLATE;ALUMINIUM TRIFLATE;Aluminium(III) triflate;uminum trifL;ALUMINUM TRIFLUOROMETHANESULFONATE;ALUMINIUM TRIFLUOROMETHANESULFONATE;Aluminum Trifluoromethanesulfonatec;ALUMINIUM TRIFLUOROMETHANESULPHONATE;Aluminumtrifluoromethanesulfonate,98%;Aluminiumtrifluoromethanesulphonate99%
CBNumber
CB7387584
Molecular Formula
CH4AlF3O3S
Formula Weight
180.08
MOL File
74974-61-1.mol
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Aluminum trifluoromethanesulfonate Property

Melting point:
300 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in ether, acetone, acetonitrile, and diglyme; poorly soluble in nitromethane; sparingly soluble in SO2 and SO2 ClF.
form 
Powder
color 
White
Water Solubility 
Insoluble in water.
Sensitive 
Hygroscopic
Hydrolytic Sensitivity
6: forms irreversible hydrate
Stability:
hygroscopic
CAS DataBase Reference
74974-61-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-36/37/38
Safety Statements 
26-36/37/39-45-36
RIDADR 
UN 3261 8/PG 3
WGK Germany 
3
Hazard Note 
Corrosive
TSCA 
No
HazardClass 
8
PackingGroup 
III
HS Code 
29049020
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
515884
Product name
Aluminum trifluoromethanesulfonate
Purity
99.9% trace metals basis
Packaging
10g
Price
$120
Updated
2024/03/01
Sigma-Aldrich
Product number
515884
Product name
Aluminum trifluoromethanesulfonate
Purity
99.9% trace metals basis
Packaging
50g
Price
$380
Updated
2024/03/01
Alfa Aesar
Product number
B20785
Product name
Aluminum trifluoromethanesulfonate, 99%
Packaging
5g
Price
$61.3
Updated
2024/03/01
Alfa Aesar
Product number
038568
Product name
Aluminum trifluoromethanesulfonate
Packaging
10g
Price
$97.4
Updated
2024/03/01
Strem Chemicals
Product number
13-1500
Product name
Aluminum trifluoromethanesulfonate, 99% (Aluminum triflate)
Packaging
10g
Price
$114
Updated
2024/03/01
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Aluminum trifluoromethanesulfonate Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Lewis acid used as a catalyst for Friedel–Crafts, ketalization, nucleophilic substitution, hydroalkoxylation, methoxycarbonyla- tion, rearrangement, and epoxide ring-opening reactions.

Uses

Aluminum trifluoromethanesulfonate is used in pharmaceutical intermediates.

Preparation

Can be prepared from aluminum trichloride and tribromide by heating with triflic acid in anhydrous conditions. Preparations from triethylaluminum, aluminum carbide, and aluminum isopropoxide have also been described.

Reactions

Friedel-Crafts Reactions.
Aluminum trifluoromethanesulfonate has been used for the Friedel-Crafts alkylation reaction of toluene with isopropyl and tert-butyl chlorides (eq 1), and for theacylationofbenzeneandtoluenewithacetylandbenzoylchlo- rides in low to moderate yields. Intramolecular Friedel-Crafts acylation of an aromatic compound with Meldrum’s acid has also been reported using catalytic amounts of Al(OTf) 3 . Acylation of 2-methoxynaphthalene with acetic anhydride has been reported using Al(OTf) 3 and lithium perchlorate as an additive to afford the corresponding 6-acetylated adduct in 83% yield. Effective acylation of arenes with carboxylic acids has also been disclosed using polystyrene-supported Al(OTf)3.

Aluminum trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Aluminum trifluoromethanesulfonate manufacturers

Career Henan Chemical Co
Product
ALUMINUM TRIFLUOROMETHANESULFONATE 74974-61-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-07-04

74974-61-1, Aluminum trifluoromethanesulfonateRelated Search:

Trifluoromethanesulfonic acid Tri(o-tolyl)phosphine CATECHOLBORANE Cesium RHENIUM Titanous chloride Bismuth(III) trifluoromethanesulfonate Lithium trifluoromethanesulfonate Zinc trifluoromethanesulfonate Lanthanum trifluoromethanesulfonate YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Sodium trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Trifluoromethanesulfonyl chloride SILVER TRIFLUOROMETHANESULFONATE Potassium trifluoromethanesulfonate PALLADIUM(II) TRIFLUOROACETATE 2-Bromoethyl trifluoromethanesulphonate

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