Description References
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HEXAFLUOROACETYLACETONE

Description References
Product Name
HEXAFLUOROACETYLACETONE
CAS No.
1522-22-1
Chemical Name
HEXAFLUOROACETYLACETONE
Synonyms
HFACAC;HFAC;1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONE;1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE;uoroacetyL;HEXAFLUOROACETYLACETONE;Hexafluoroacetylacetone99%;Hexafluoroacetylacetone>
CBNumber
CB8188414
Molecular Formula
C5H2F6O2
Formula Weight
208.06
MOL File
1522-22-1.mol
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HEXAFLUOROACETYLACETONE Property

Boiling point:
70-71 °C (lit.)
Density 
1.47 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.332(lit.)
Flash point:
32 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Liquid
pka
4.30±0.10(Predicted)
color 
Clear colorless to slightly yellow
Specific Gravity
1.470
Water Solubility 
Not miscible in water.
Sensitive 
Hygroscopic
BRN 
1790138
InChIKey
QAMFBRUWYYMMGJ-UHFFFAOYSA-N
CAS DataBase Reference
1522-22-1(CAS DataBase Reference)
EPA Substance Registry System
2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- (1522-22-1)
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Safety

Hazard Codes 
C,F,Xi
Risk Statements 
10-20/21/22-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2920 8/PG 2
WGK Germany 
3
3
Hazard Note 
Flammable/Corrosive
TSCA 
T
HazardClass 
8
PackingGroup 
II
HS Code 
29147000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
238309
Product name
Hexafluoroacetylacetone
Purity
98%
Packaging
5g
Price
$48.7
Updated
2024/03/01
Sigma-Aldrich
Product number
238309
Product name
Hexafluoroacetylacetone
Purity
98%
Packaging
25g
Price
$143
Updated
2024/03/01
TCI Chemical
Product number
H0476
Product name
Hexafluoroacetylacetone
Purity
>95.0%(GC)
Packaging
5g
Price
$44
Updated
2024/03/01
TCI Chemical
Product number
H0476
Product name
Hexafluoroacetylacetone
Purity
>95.0%(GC)
Packaging
25g
Price
$129
Updated
2024/03/01
Alfa Aesar
Product number
L01693
Product name
1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+%
Packaging
5g
Price
$57
Updated
2024/03/01
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HEXAFLUOROACETYLACETONE Chemical Properties,Usage,Production

Description

HEXAFLUOROACETYLACETONE acts as a chelating ligand. For example, it can forms metal-chelate complexes with Ca(II), Zn (II), Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III), making it be useful in extracting related metal ions. It can also be used as liquid crystal intermediate.

References

Chattoraj, S. C., A. G. C. Jr, and R. E. Sievers. "Cadmium and zinc chelates of hexafluoroacetylacetone the gas phase reaction of a novel volatile cadmium complex with hydrogen sulphide." Journal of Inorganic & Nuclear Chemistry 28.9(1966):1937-1943.
Tomazic, Branko B., and J. W. O'Laughlin. "Synergic extraction of iron with hexafluoroacetylacetone and tributyl phosphate." Analytical Chemistry 45.8(2002):1519-1526.
http://www.sigmaaldrich.com/catalog/product/aldrich/238309?lang=en&region=US
https://www.alfa.com/zh-cn/catalog/L01693/

Chemical Properties

clear colorless to slightly yellow liquid

Uses

1,1,1,5,5,5-Hexafluoro-2,4-pentanedione acts as a chelating ligand. It is used as liquid crystal intermediate.

General Description

Hexafluoroacetylacetone forms metal-chelate complexes with Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III). Hexafluoroacetylacetone on hydration yields 1,1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraol.

Purification Methods

It forms a dihydrate which has no UV spectrum compared with max (CHCl3) 273nm ( 7,800) for the anhydrous ketone. The dihydrate decomposes at ~90o. The hydrate (10g) plus anhydous CaSO4 (Drierite, 30g) are heated and distilled, the distillate is treated with more CaSO4 and redistilled. When the distillate is treated with aqueous NaOH and heated, the dihydrate crystallises on cooling. The Cu complex has m 135o (after sublimation). [Gilman et al. J Am Chem Soc 78 2790 1956, Belford et al. J Inorg Nucl Chem 2 11 1956, Beilstein 1 IV 3681.]

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HEXAFLUOROACETYLACETONE Suppliers

West fluorine technology co., ltd
Tel
0531-85906692; 15588812394
Fax
86-0531-85906692
Email
325912682@qq.com
Country
China
ProdList
369
Advantage
58
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
SHANG FLUORO
Tel
021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
375
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Chemvon Biotechnology Co., Ltd
Tel
021-50790412
Fax
+86-21-50790419
Email
info@chemvon.com
Country
China
ProdList
371
Advantage
57
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
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View Lastest Price from HEXAFLUOROACETYLACETONE manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
HEXAFLUOROACETYLACETONE 1522-22-1
Price
US $999.00-800.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
Hexafluoroacetylacetone 1522-22-1
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-19
PNP Biotech Co. Ltd
Product
Hexafluoroacetylacetone 1522-22-1
Price
US $0.00/kg
Min. Order
25kg
Purity
GC>99%
Supply Ability
Inquiry
Release date
2022-09-16

1522-22-1, HEXAFLUOROACETYLACETONERelated Search:


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  • Hexafluoroacetylacetone&gt
  • uoroacetyL
  • 1522-22-1
  • C5H2F6O2
  • CF3COCH2COCF3
  • Organic Building Blocks
  • Ketones
  • Building Blocks
  • C3 to C6
  • Carbonyl Compounds
  • organofluorine compounds
  • Halogen compounds