ChemicalBook > CAS DataBase List > Chinomethionate

Chinomethionate

Product Name
Chinomethionate
CAS No.
2439-01-2
Chemical Name
Chinomethionate
Synonyms
MQD;erade;joust;QUINO;ss2074;B-36205;Morstan;Forstan;SS 2074;bay36205
CBNumber
CB8223940
Molecular Formula
C10H6N2OS2
Formula Weight
234.3
MOL File
2439-01-2.mol
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Chinomethionate Property

Melting point:
172°
Boiling point:
476.6±55.0 °C(Predicted)
Density 
1.4147 (rough estimate)
vapor pressure 
2.6 x 10-5 Pa (20 °C)
refractive index 
1.6800 (estimate)
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), Methanol (Slightly, Heated)
form 
Solid
Water Solubility 
1 mg l-1 (20 °C)
pka
-5.28±0.20(Predicted)
color 
Yellow crystals
Merck 
13,7048
LogP
3.78 at 20℃
NIST Chemistry Reference
Quinomethionate(2439-01-2)
EPA Substance Registry System
Chinomethionate (2439-01-2)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
20/21/22-36-43-48/22-50/53-62
Safety Statements 
24-37-60-61
RIDADR 
UN3077 9/PG 3
RTECS 
FG1400000
HS Code 
29349990
Hazardous Substances Data
2439-01-2(Hazardous Substances Data)
Toxicity
LD50 in male, female rats (mg/kg): 1800, 1100 orally (Gaines)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H332Harmful if inhaled

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P314Get medical advice/attention if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
C292000
Product name
Chinomethionate
Packaging
250mg
Price
$50
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0006024
Product name
CHINOMETHIONAT
Purity
95.00%
Packaging
5G
Price
$909.56
Updated
2021/12/16
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Chinomethionate Chemical Properties,Usage,Production

Description

Chinomethionate is a quinoxaline fungicide and acaricide introduced in 1968 to control powdery mildew and spider mites on fruits, ornamentals, cucurbits, cotton, coffee, tea, tobacco, walnuts, vegetables and glasshouse crops. It is nonsystemic, with contact activity only.

Chemical Properties

Chinomethionate is a tan to yellow crystals. Soluble in benzene, toluene, and dioxane; insoluble in water. It has been shown to have low toxicity to mammals, birds and bees, but is highly toxic to fish and some aquatic invertebrates.

Uses

Chinomethionat exhibits both acaricidal and fungicidal activities. It is a selective, non-systemic contact fungicide with both protective and eradicant control of powdery mildews on fruits, cucurbits, vegetables, ornamentals, tobacco and glasshouse crops.

Definition

ChEBI: A dithioloquinoxaline that results from the formal condensation of 6-methylquinoxaline-2,3-dithiol with phosgene. It has been used as a fungicide and acaricide for the control of mites and powdery mildew on citrus, vegetables, and walnuts, but is not appro ed for use in the EU.

General Description

Yellow crystals. Non-corrosive. Used as a selective fungicide.

Air & Water Reactions

Hydrolyzed in alkaline solution.

Reactivity Profile

A member of the quinoxaline, dithiolane family.

Hazard

Toxic by ingestion and inhalation.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by intraperitoneal, ingestion, and skin contact routes. A pesticide. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Environmental Fate

Chemical/Physical. Reacts with ammonia forming 6-methyl-2,3-quinoxalinedithiol.

Metabolic pathway

Limited information is available to describe the degradation and metabolic fate of chinomethionat. Hydrolytic cleavage of the dithiocarbonate ring is the primary degradation reaction in water, plants and animals.

Degradation

Chinomethionat was degraded at pH 4,7 and 9 at 22 °C with DT50 values of 10 days, 3.3 days and 3.6 hours, respectively. It is degraded under alkaline conditions to yield 6-methyl-2,3-quinoxalinedithiol (2) (PM) as shown in Scheme 1. Clark and Loeffler (1980) reported the extensive photodegradation of chinomethionat in benzene in a nitrogen atmosphere under UV light to yield dimeric condensation products and benzene insertion products.

Mode of action

Chinomethionate reacts with sulfur-containing amino acids in proteins, thereby disrupting the function of many enzymes and other proteins. Because there is no single target site, target site resistance is unlikely.

Chinomethionate Preparation Products And Raw materials

Raw materials

Preparation Products

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Chinomethionate Suppliers

BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9901
Advantage
58
Nanjing Sunlida Biological Technology Co., Ltd.
Tel
025-57798810
Fax
025-57019371
Email
sales@sunlidabio.com
Country
China
ProdList
3750
Advantage
55
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ:800101999
Email
cdhxsj@163.com
Country
China
ProdList
13358
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58
Shanghai Xilong Biochemical Technology Co., Ltd.
Tel
021-52907766-8042
Fax
021-52906523
Country
China
ProdList
9947
Advantage
58
Raw material medicin reagent co.,Ltd
Tel
025-57798860
Email
sales@njromanme.com
Country
China
ProdList
4534
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131981
Advantage
58
Guangdong wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2886750 13927877953
Fax
0751-2886750
Email
3005811397@qq.com
Country
China
ProdList
13374
Advantage
58
Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799 20)
Fax
0539-6362799(To 20)
Country
China
ProdList
10007
Advantage
58
Beijing altar ink quality inspection technology co., LTD
Tel
010-52889049
Email
2250970673@qq.com
Country
CHINA
ProdList
1133
Advantage
58
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View Lastest Price from Chinomethionate manufacturers

Hebei Duling International Trade Co. LTD
Product
Chinomethionate 2439-01-2
Price
US $25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-04-12
Shaanxi Dideu Medichem Co. Ltd
Product
Chinomethionate 2439-01-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
500 tons
Release date
2020-04-27
Career Henan Chemical Co
Product
Chinomethionate 2439-01-2
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2019-12-31

2439-01-2, ChinomethionateRelated Search:


  • 1,3-Dithiolo[4,5-b]quinoxalin-2-one, 6-methyl-
  • 3-quinoxalinedithiol,6-methyl-cycliccarbonate
  • 3-quinoxalinedithiol,6-methyl-cyclicdithiocarbonate(ester)
  • 5-b)quinoxalin-2-one,6-methyl-3-dithiolo(4
  • 5-b)quinoxalin-2-one,6-methyl-dithiolo(
  • 6-methyl-1,3-dithiolo(4,5-b)quinoxalin-2-one
  • 6-Methyl-1,3-Dithiolo[4,5-b]quinoxalin-2-one
  • 6-methyl-2,3-quinoxalinedithiocarbonate
  • 6-Methyl-2,3-quinoxalinedithiol cyclic carbonate
  • 6-Methyl-2,3-quinoxalinedithiol cyclic dithiocarbonate
  • 6-methyl-2,3-quinoxalinedithiolcycliccarbonate
  • 6-methyl-2,3-quinoxalinedithiolcyclicdithiocarbonate
  • 6-methyl-2-oxo-1,3-dithiolo(4,5-b)quinoxaline
  • 6-methyl-chinoxalin-2,3-dithiol-cyclo-carbonat
  • 6-methyldithiolo(4,5-b)quinoxalin-2-one
  • 6-methyl-quinoxaline-2,3-dithiolcyclocarbonate
  • quinomethionate chinomethionat (ISO) 6-methyl-1,3-dithiolo(4,5-b)quinoxalin-2-one
  • 6-Methyl-1,3-dithiolo[4,5-b]quiuoxalin-2-one
  • B-36205
  • Morstan
  • 6-METHYLQUINOXALIN-2,3-DITHIOCARBONATE
  • 6-METHYLQUINOXALIN-2,3-DITHIOCARBONATE, 6-methyl-1,3-dithiolo(4,5-b)quinoxalin-2-one, chinomethionat (ISO), quinomethionate
  • Chinomethionate Standard
  • BAY 36205
  • bay36205
  • Bayer 4964
  • bayer4964
  • Carbonic acid, dithio-, cyclic S,S-(6-methyl-2,3-quinoxalinediyl) ester
  • carbonicacid,dithio-,cyclics,s-(6-methyl-2,3-quinoxalinediyl)ester
  • carbonicacid,dithio-,cyclics,s-esterwith6-methyl-2,3-quinoxalinedithiol
  • cetactaelate
  • cyclics,s-(6-methyl-2,3-quinoxalinediyl)dithiocarbonate
  • daisonetxl21
  • dithioquinox
  • ENT 25606
  • ent25,606
  • erade
  • erazidon
  • Forstan
  • joust
  • 7-methyl-[1,3]dithiolo[4,5-b]quinoxalin-2-one
  • Chinomethionate,Oxythioquinox
  • 6-Methyl-2H-[1,3]dithiolo[4,5-b]quinoxalin-2-one
  • Chinomethionate Solution,100ppm
  • morestan2
  • Morestane
  • MQD
  • Oxythioquinox
  • quinomethionat
  • Quinoxalines
  • S,S-(6-Methylquinoxaline-2,3-diyl)dithiocarbonate
  • SS 2074
  • ss2074
  • QUINOMETHIONATE
  • QUINO
  • OXYTHIOQUINOX(R)
  • MORESTAN
  • MORESTAN R(R)