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Amentoflavone 4',4''',7''-trimethyl ether

Product Name
Amentoflavone 4',4''',7''-trimethyl ether
CAS No.
481-45-8
Chemical Name
Amentoflavone 4',4''',7''-trimethyl ether
Synonyms
Kayaflavone;Amentoflavone 4',4''',7''-trimethyl ether;Amentoflavone 4',4''',7''-trimethyl ether USP/EP/BP;8-[5-(5,7-Dihydroxy-4-oxo-4H-1-benzopyran-2-yl)-2-methoxyphenyl]-5-hydroxy-7-methoxy-2-(4-methoxyphenyl)-4H-1-benzopyran-4-one;2-(4-Methoxyphenyl)-5-hydroxy-7-methoxy-8-[2-methoxy-5-(5,7-dihydroxy-4-oxo-4H-1-benzopyran-2-yl)phenyl]-4H-1-benzopyran-4-one;4H-1-Benzopyran-4-one, 8-[5-(5,7-dihydroxy-4-oxo-4H-1-benzopyran-2-yl)-2-methoxyphenyl]-5-hydroxy-7-methoxy-2-(4-methoxyphenyl)-
CBNumber
CB82256692
Molecular Formula
C33H24O10
Formula Weight
580.54
MOL File
481-45-8.mol
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Amentoflavone 4',4''',7''-trimethyl ether Property

Melting point:
314-315 °C (decomp)(Solv: methanol (67-56-1))
Boiling point:
815.4±65.0 °C(Predicted)
Density 
1.445±0.06 g/cm3(Predicted)
pka
6.00±0.40(Predicted)
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Hazard and Precautionary Statements (GHS)

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Amentoflavone 4',4''',7''-trimethyl ether Chemical Properties,Usage,Production

Uses

Kayaflavone is an amentoflavone type biflavonoid. Kayaflavone has an inhibitory activity against amyloid-β42 cytotoxicity in PC-12 cells with an EC50 value of 5.29 μΜ. Kayaflavone is promising for research of Alzheimer’s disease[1].

Synthesis

Willow leaf loosestrife leaves crushed, weighing 20kg, with 8 times 90% methanol solution ultrasonic extraction for 30 minutes, extracted three times, the extract was concentrated under reduced pressure and added to the HZ816 macroporous resin column adsorption, with 5 times the volume of the column 50% methanol solution elution, and then 8 times the volume of the column 85% methanol solution elution, the eluent was concentrated and adjusted to ph4, add ethyl acetate stirred thoroughly, collect the ethyl acetate layer, the solid was obtained. Crude extract. Take chloroform, methanol, water, according to 3:2:1 mixing, fully layered, take the upper phase filled with high-speed counter-current chromatography tube as stationary phase, turn on the host, speed 800rpm, while pumping the lower phase to do the fluid phase, the establishment of dynamic equilibrium, the flow rate is adjusted to 2ml/min, with the mobile phase to dissolve the extracts, by the injection valve into the sample, the evaporation of light scattering detector on-line monitoring, the collection of target components, continuous preparation, flow points The reagent was recovered to obtain 1.2 g of Cephalosporin, which was detected as 99.5% by HPLC.

References

[1] Sasaki H, et al. Inhibitory activities of biflavonoids against amyloid-β peptide 42 cytotoxicity in PC-12 cells. Bioorg Med Chem Lett. 2015 Jul 15;25(14):2831-3. DOI:10.1016/j.bmcl.2015.04.106
[2] Sun CM, et al. Selective cytotoxicity of ginkgetin from Selaginella moellendorffii. J Nat Prod. 1997 Apr;60(4):382-4. DOI:10.1021/np960608e

Amentoflavone 4',4''',7''-trimethyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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Amentoflavone 4',4''',7''-trimethyl ether Suppliers

Sichuan Wei Keqi Biological Technology Co., Ltd.
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481-45-8, Amentoflavone 4',4''',7''-trimethyl etherRelated Search:


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  • 8-[5-(5,7-Dihydroxy-4-oxo-4H-1-benzopyran-2-yl)-2-methoxyphenyl]-5-hydroxy-7-methoxy-2-(4-methoxyphenyl)-4H-1-benzopyran-4-one
  • Amentoflavone 4',4''',7''-trimethyl ether
  • Kayaflavone
  • 4H-1-Benzopyran-4-one, 8-[5-(5,7-dihydroxy-4-oxo-4H-1-benzopyran-2-yl)-2-methoxyphenyl]-5-hydroxy-7-methoxy-2-(4-methoxyphenyl)-
  • Amentoflavone 4',4''',7''-trimethyl ether USP/EP/BP
  • 481-45-8