Reaction
ChemicalBook > CAS DataBase List > (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

Reaction
Product Name
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
CAS No.
130004-33-0
Chemical Name
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
Synonyms
(S)-RuCl[(p-cymene(BINAP)Cl;S-(-)-BINAP-CHLORO(P-CYM;[RuCl(p-cymene)((S)-binap)]Cl;[RuCl(p-cymene)((S)-binap)]Cl >S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE;[bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl;(S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore;Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](...;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl;(R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
CBNumber
CB8228824
Molecular Formula
C54H44Cl2P2Ru
Formula Weight
926.86
MOL File
130004-33-0.mol
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(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Property

Melting point:
>100°C
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly)
form 
Powder
color 
orange
Sensitive 
Air Sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692972
Product name
(S)-RuCl[(p-cymene(BINAP)]Cl
Packaging
500mg
Price
$53.2
Updated
2024/03/01
Sigma-Aldrich
Product number
692972
Product name
(S)-RuCl[(p-cymene(BINAP)]Cl
Packaging
100mg
Price
$36.1
Updated
2023/06/20
TCI Chemical
Product number
R0147
Product name
[RuCl(p-cymene)((S)-binap)]Cl
Purity
>90.0%(HPLC)
Packaging
200mg
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
R0147
Product name
[RuCl(p-cymene)((S)-binap)]Cl
Purity
>90.0%(HPLC)
Packaging
1g
Price
$168
Updated
2024/03/01
Strem Chemicals
Product number
44-0086
Product name
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
Packaging
250mg
Price
$53
Updated
2024/03/01
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(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Chemical Properties,Usage,Production

Reaction

This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Brown crystalline powder

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Suppliers

Belgium 3 China 130 Germany 2 India 7 Japan 2 Switzerland 3 The Netherlands 1 United Kingdom 2 United States 9 Global 159
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TAKASAGO INTERNATIONAL CORPORATION
Tel
--
Fax
--
Email
finechemicals@takasago.com
Country
Japan
ProdList
203
Advantage
75
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View Lastest Price from (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE 130004-33-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-21
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride/ (S)-RuCl[(p-cymene(BINAP)]Cl 130004-33-0
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-28
Career Henan Chemical Co
Product
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE 130004-33-0
Price
US $1.00/g
Min. Order
100g
Purity
98%min
Supply Ability
G/KG/T
Release date
2019-12-20

130004-33-0, (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDERelated Search:

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Cumene (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Ruthenium DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride DIPHENYL(O-TOLYL)PHOSPHINE Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride 1,1'-BINAPHTHYL

  • [(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • (S)-(-)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
  • [bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl
  • (S)-RuCl[(p-cymene(BINAP)Cl
  • (R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
  • [(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • S-(-)-BINAP-CHLORO(P-CYM
  • [(1S)-(1,1'-Binaphthalene)-2,2'-diylbis-(diphenylphosphine)]-chloro-[(1,2,3,4,5,6)-1-methyl-4-(1-methylethyl)-benzene]-ruthenium chloride
  • (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLO
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst.
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride,9
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst., 97+%
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
  • (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-
  • (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-,chloride (1:1) )
  • (S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore
  • [RuCl(p-cymene)((S)-binap)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-
  • [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
  • -binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride, 97+%, ca 5% MeOH of cryst.
  • CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
  • CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
  • (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • [RuCl(p-cymene)((S)-binap)]Cl &gt
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride/ (S)-RuCl[(p-cymene(BINAP)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](...
  • (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • (S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride
  • Ruthenium(1+), [1,1′-(1S)-[1,1′-binaphthalene]-2,2′-diylbis[1,1-diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-, chloride (1:1) (ACI)
  • 130004-33-0
  • C54H46ClP2RuCl
  • C54H46Cl2P2Ru
  • Ru