ChemicalBook > CAS DataBase List > (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Product Name
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS No.
38465-86-0
Chemical Name
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms
methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
CBNumber
CB8242424
Molecular Formula
C34H38F6IrP3
Formula Weight
845.79
MOL File
38465-86-0.mol
More
Less

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property

Melting point:
224 °C (dec.) (lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Crystalline Powder
color 
Red
Water Solubility 
Soluble in acetone. Insoluble in water.
Sensitive 
Air & Moisture Sensitive
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
337455
Product name
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity
97%
Packaging
50mg
Price
$30.3
Updated
2024/03/01
Sigma-Aldrich
Product number
337455
Product name
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity
97%
Packaging
500mg
Price
$176
Updated
2024/03/01
Alfa Aesar
Product number
018809
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
0.5g
Price
$150
Updated
2023/06/20
Alfa Aesar
Product number
018809
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
2g
Price
$457
Updated
2023/06/20
TRC
Product number
C984583
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
25mg
Price
$45
Updated
2021/12/16
More
Less

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Chemical Properties

red crystalline powder

Uses

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers

Belgium 1 China 48 Germany 1 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 6 Global 62
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
Advantage
62
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
18017383231 18017383231
Fax
qq：2817624287
Email
lyh_antaeus@163.com
Country
China
ProdList
9347
Advantage
55
Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65

38465-86-0, (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATERelated Search:

METHYLDIPHENYLPHOSPHINE 1,3-CYCLOOCTADIENE (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE 1,5-Cyclooctadiene

  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
  • 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate
  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%
  • Iridium(1+), (1,2,5,6-.eta.)-1,5-cyclooctadienebis(methyldiphenylphosphine)-, hexafluorophosphate(1-)
  • methyl(diphenyl)phosphane
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i)
  • (bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate
  • 1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM
  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH
  • 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, [Ir(COD)(PPh2Me)2]PF6
  • 38465-86-0
  • C34H38F6lrP3
  • C34H38F6IrP3
  • C34H38IrP2F6P
  • C42H50F6IrP3
  • C36H46F6IrP3
  • Iridium
  • Catalysis and Inorganic Chemistry
  • Ir
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Iridium