(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

ChemicalBook > CAS DataBase List > (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Product Name: (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS No.: 38465-86-0
Chemical Name: (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms: methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
CBNumber: CB8242424
Molecular Formula: C34H38F6IrP3
Formula Weight: 845.79
MOL File: 38465-86-0.mol

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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property

Melting point:: 224 °C (dec.) (lit.)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Crystalline Powder
color: Red
Water Solubility: Soluble in acetone. Insoluble in water.
Sensitive: Air & Moisture Sensitive

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 337455
Product name: (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity: 97%
Packaging: 50mg
Price: $30.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 337455
Product name: (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity: 97%
Packaging: 500mg
Price: $176
Updated: 2024/03/01

Alfa Aesar

Product number: 018809
Product name: 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging: 0.5g
Price: $150
Updated: 2023/06/20

Alfa Aesar

Product number: 018809
Product name: 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging: 2g
Price: $457
Updated: 2023/06/20

TRC

Product number: C984583
Product name: 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging: 25mg
Price: $45
Updated: 2021/12/16

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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Chemical Properties

red crystalline powder

Uses

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh₂Me)₂]PF₆, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH₂(solv)₂(PPh₂Me)₂]PF₆ which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers

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38465-86-0, (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATERelated Search:

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1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate

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1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, [Ir(COD)(PPh2Me)2]PF6

38465-86-0

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