(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- Product Name
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- CAS No.
- 38465-86-0
- Chemical Name
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- Synonyms
- methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
- CBNumber
- CB8242424
- Molecular Formula
- C34H38F6IrP3
- Formula Weight
- 845.79
- MOL File
- 38465-86-0.mol
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property
- Melting point:
- 224 °C (dec.) (lit.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Crystalline Powder
- color
- Red
- Water Solubility
- Soluble in acetone. Insoluble in water.
- Sensitive
- Air & Moisture Sensitive
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 337455
- Product name
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Purity
- 97%
- Packaging
- 50mg
- Price
- $30.3
- Updated
- 2024/03/01
- Product number
- 337455
- Product name
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Purity
- 97%
- Packaging
- 500mg
- Price
- $176
- Updated
- 2024/03/01
- Product number
- 018809
- Product name
- 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Packaging
- 0.5g
- Price
- $150
- Updated
- 2023/06/20
- Product number
- 018809
- Product name
- 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Packaging
- 2g
- Price
- $457
- Updated
- 2023/06/20
- Product number
- C984583
- Product name
- 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Packaging
- 25mg
- Price
- $45
- Updated
- 2021/12/16
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production
Chemical Properties
red crystalline powder
Uses
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
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