1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE
- Product Name
- 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE
- CAS No.
- 106854-77-7
- Chemical Name
- 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE
- Synonyms
- UKRORGSYN-BB BBV-081072;4-(Trifluoroethoxy)bromobenzene;4-(2,2,2-Trifluoroethoxy)bromobenzene;1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE;4-bromo-1-(2,2,2-trifluoroethoxy)benzene;Benzene, 1-bromo-4-(2,2,2-trifluoroethoxy)-
- CBNumber
- CB8242828
- Molecular Formula
- C8H6BrF3O
- Formula Weight
- 255.03
- MOL File
- 106854-77-7.mol
1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Property
- Boiling point:
- 212.8±40.0 °C(Predicted)
- Density
- 1.569±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C8H6BrF3O/c9-6-1-3-7(4-2-6)13-5-8(10,11)12/h1-4H,5H2
- InChIKey
- SMDIDUHBHCDCRQ-UHFFFAOYSA-N
- SMILES
- C1(Br)=CC=C(OCC(F)(F)F)C=C1
Safety
- HS Code
- 2909309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B695128
- Product name
- 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- Z3856
- Product name
- 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
- Packaging
- 1g
- Price
- $85
- Updated
- 2021/12/16
- Product number
- 2607-B-84
- Product name
- 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
- Packaging
- 5G
- Price
- $85
- Updated
- 2021/12/16
- Product number
- PC500829
- Product name
- 4-(2,2,2-Trifluoroethoxy)bromobenzene
- Packaging
- 5g
- Price
- $152
- Updated
- 2021/12/16
- Product number
- PC500829
- Product name
- 4-(2,2,2-Trifluoroethoxy)bromobenzene
- Packaging
- 25g
- Price
- $446
- Updated
- 2021/12/16
1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Chemical Properties,Usage,Production
Synthesis
106-41-2
6226-25-1
106854-77-7
General procedure for the synthesis of 1-bromo-4-(2,2,2-trifluoroethoxy)benzene from 4-bromophenol and 2,2,2-trifluoroethyl trifluoromethanesulfonate: first, 4-bromophenol (9.57 g, 55 mmol) was dissolved in acetone (200 mL), followed by the addition of potassium carbonate (22.89 g, 166 mmol) and 2,2,2-trifluoroethyl trifluoromethanesulfonate ester (16.0 g, 69 mmol). The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was filtered to remove the insoluble salt and then concentrated under reduced pressure at 300 mbar at 30 °C to remove the acetone. The final product was 1-bromo-4-(2,2,2-trifluoroethoxy)benzene as a waxy solid (more than 100% yield, as a small amount of acetone remained in the product).
References
[1] Patent: WO2005/822, 2005, A1. Location in patent: Page/Page column 44
[2] Patent: US2016/332999, 2016, A1. Location in patent: Paragraph 0576; 0577
1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Suppliers
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