Bis(acetonitrile)dichloropalladium(II)

Reaction

Product Name: Bis(acetonitrile)dichloropalladium(II)
CAS No.: 14592-56-4
Chemical Name: Bis(acetonitrile)dichloropalladium(II)
Synonyms: BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE;(MeCN)2PdCl2;bis(acetonitrile)dichloropalladium;Palladium, bis(acetonitrile)dichloro-;TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;DICHLOROBIS(ACETONITRILE)PALLADIUM(II);BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;e)dichL;Bis(acetonitriL;Bis(Acetonitrile)Pd(II)
CBNumber: CB8245652
Molecular Formula: C4H6Cl2N2Pd
Formula Weight: 259.43
MOL File: 14592-56-4.mol

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Bis(acetonitrile)dichloropalladium(II) Property

Melting point:: 300 °C
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in acetonitrile, acetone, chloroform
form: Fine Crystalline Powder
color: Orange to rust-brown
Water Solubility: insoluble
CAS DataBase Reference: 14592-56-4(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xn
Risk Statements: 23/24/25-36/37/38-20/21/22
Safety Statements: 16-27-36/37-45-36-26
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
TSCA: No
HazardClass: 6.1
PackingGroup: III
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Precautionary statements: P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 225657
Product name: Bis(acetonitrile)dichloropalladium(II)
Purity: 99%
Packaging: 500mg
Price: $77
Updated: 2024/03/01

Sigma-Aldrich

Product number: 225657
Product name: Bis(acetonitrile)dichloropalladium(II)
Purity: 99%
Packaging: 5g
Price: $502
Updated: 2024/03/01

TCI Chemical

Product number: B1676
Product name: Bis(acetonitrile)palladium(II) Dichloride
Purity: >98.0%(T)
Packaging: 1g
Price: $279
Updated: 2024/03/01

TCI Chemical

Product number: B1676
Product name: Bis(acetonitrile)palladium(II) Dichloride
Purity: >98.0%(T)
Packaging: 5g
Price: $1046
Updated: 2024/03/01

Alfa Aesar

Product number: 010002
Product name: Bis(acetonitrile)dichloropalladium(II), Pd 40.5%
Packaging: 1g
Price: $123
Updated: 2023/06/20

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Bis(acetonitrile)dichloropalladium(II) Chemical Properties,Usage,Production

Reaction

Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
Catalyst for the aza-Michael reaction of carbamates with enones.
Catalyst for the rearrangement of allylic imidates to allylic amides.
Catalyst for the Nazarov cyclization of α-alkoxy dienones.
Catalyst for the diamination of conjugated dienes.
Three component Michael addition, cyclization, cross-coupling reaction.
C-H activation of indoles.
Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.

Chemical Properties

Light yellow to Brown powder to crystaline.

Physical properties

Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride.

Uses

suzuki reaction

Uses

It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.

Uses

Catalyst used in an ether-directed aza-Claisen rearrangement.

Application

Synthesis of Oxindoles

To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II) (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.

Preparation

Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.

General Description

This product has been enhanced for catalytic efficiency.

Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Palladium chloride Dichloromethane

Preparation Products

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Bis(acetonitrile)dichloropalladium(II) Suppliers

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View Lastest Price from Bis(acetonitrile)dichloropalladium(II) manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-03

Hebei Mojin Biotechnology Co., Ltd

Product: Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-15

henan kanbei chemical co.,ltd

Product: Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

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TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHL

Bis(acetonitrile)palladiuM(II) chloridel

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Bis(Acetonitrile)Dichloropalladium (II) extrapure, 99%, ~41% Pd

DICHLOROBIS (ACETONITRILE) PALLADIUM (II) For Synthesis

Di-(acetonitrile) palladium chloride

chloranuidylpalladiobis(ylium)]chloranuide

Acetonitrile-dichloropalladium

14592-56-4

C4H6Cl2N2Pd

C4Cl4N2Pd

C4H6N2PdCl2

Catalysis and Inorganic Chemistry

Homogeneous Pd Catalysts

Transition Metal Compounds