BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER

Product Name: BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER
CAS No.: 103440-54-6
Chemical Name: BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER
Synonyms: Methyl 5-iodo-2-Methylbenzoate;5-IODO-2-METHYL-, METHYL ESTER;Methyl 2-methyl-5-iodobenzoate;5-iodo-2-Methylbenzoic acid Methyl ester;BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER
CBNumber: CB82460095
Molecular Formula: C9H9IO2
Formula Weight: 276.07
MOL File: 103440-54-6.mol

More

Less

BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER Property

Melting point:: 60℃
Boiling point:: 290.4±28.0 °C(Predicted)
Density: 1.666±0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
form: crystalline needles
color: Off-white

More

Less

Safety

HS Code: 2916399090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More

Less

N-Bromosuccinimide Price

TRC

Product number: M262743
Product name: Methyl5-Iodo-2-methylbenzoate
Packaging: 500mg
Price: $130
Updated: 2021/12/16

Apolloscientific

Product number: OR42276
Product name: Methyl 5-iodo-2-methylbenzoate
Packaging: 1g
Price: $26
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-H-02
Product name: Methyl 5-iodo-2-methylbenzoate
Packaging: 2g
Price: $55
Updated: 2021/12/16

Apolloscientific

Product number: OR42276
Product name: Methyl 5-iodo-2-methylbenzoate
Packaging: 5g
Price: $100
Updated: 2021/12/16

AK Scientific

Product number: Z1827
Product name: Methyl5-iodo-2-methylbenzoate
Packaging: 5g
Price: $183
Updated: 2021/12/16

More

Less

BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER Chemical Properties,Usage,Production

Synthesis

67-56-1

54811-38-0

103440-54-6

General procedure for the synthesis of methyl 5-iodo-2-methylbenzoate from methanol and 5-iodo-2-methylbenzoic acid: Thionyl chloride (74 g, 0.62 mol) was added slowly and dropwise to a solution of 5-iodo-2-methylbenzoic acid (86 g, 0.57 mol) in methanol (0.5 L) at 0 °C. After the dropwise addition, the reaction mixture was heated to reflux and maintained for 2 hours. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently concentrated under reduced pressure to remove the solvent. The concentrated residue was diluted with water and extracted with ethyl acetate (2 x 300 mL). The organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate, and finally concentrated under reduced pressure to afford the target product methyl 5-iodo-2-methylbenzoate (69 g, 73% yield), which could be used in subsequent reactions without further purification.

References

[1] Patent: WO2015/189744, 2015, A1. Location in patent: Page/Page column 73-74
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 23, p. 6273 - 6278
[3] Patent: WO2006/117669, 2006, A1. Location in patent: Page/Page column 41; 115

BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER Suppliers

China 71 India 2 United Kingdom 1 United States 3 Global 77

Shanghai Harvest Chemical Industrial Co., Ltd.

Tel: 021-31038972,31038973 17321035817
Fax: +86-21-51385350
Email: sales@harvest-chem.com
Country: China
ProdList: 2816
Advantage: 64

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Hangzhou Sage Chemical Co., Ltd.

Tel: +86057186818502 13588463833
Fax: Pls mail us for more information!
Email: info@sagechem.com
Country: China
ProdList: 10266
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

Quzhou AMK BioTech Co., Ltd

Tel: 0570-3081766 18357083060
Fax: 0570-3072337
Email: sales@qzamkbio.com
Country: China
ProdList: 1046
Advantage: 55

Nanjing River Chemical Co., Ltd.

Tel: 13951936332 18305166317
Fax: -
Email: info@serpharm.com
Country: China
ProdList: 493
Advantage: 55

Kaifute（Tianjin）Chemical Co., Ltd.

Tel: 022-58659859 13820733852
Fax: 022-5865 9859
Email: sales@kftchem.com
Country: China
ProdList: 299
Advantage: 55

BioPharmaMatrix,Inc.

Tel: 0510-86010668
Fax: 0510-86010668
Email: sales@biopharmamatrix.com
Country: China
ProdList: 4739
Advantage: 55

More

Less

View Lastest Price from BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER 103440-54-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-07

Career Henan Chemical Co

Product: BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER 103440-54-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 97%-99.9%
Supply Ability: 100kg
Release date: 2020-03-05

103440-54-6, BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTERRelated Search:

METHYL 5-IODO-2-METHOXYBENZOATE Ethyl 5-iodo-2-methylbenzoate 1,2-BENZENEDICARBOXYLIC ACID,4-IODO-,1,2-DIETHYL ESTER BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER dimethyl 4-iodophthalate

BENZOIC ACID, 5-IODO-2-METHYL-, METHYL ESTER

Methyl 5-iodo-2-Methylbenzoate

5-iodo-2-Methylbenzoic acid Methyl ester

Methyl 2-methyl-5-iodobenzoate

5-IODO-2-METHYL-, METHYL ESTER

103440-54-6