ChemicalBook > CAS DataBase List > 4-bromo-3-bromomethyl-benzoic acid methyl ester

4-bromo-3-bromomethyl-benzoic acid methyl ester

Product Name
4-bromo-3-bromomethyl-benzoic acid methyl ester
CAS No.
142031-67-2
Chemical Name
4-bromo-3-bromomethyl-benzoic acid methyl ester
Synonyms
Methyl 4-broMo-3-(broMoMethyl)benzoate;Methyl 3-(bromomethyl)-3-bromophenylacetate;3-Bromomethyl-4-bromobenzoic acid methyl ester;4-BROMO-3-BROMOMETHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 4-bromo-3-(bromomethyl)-, methyl ester
CBNumber
CB82465883
Molecular Formula
C9H8Br2O2
Formula Weight
307.97
MOL File
142031-67-2.mol
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4-bromo-3-bromomethyl-benzoic acid methyl ester Property

Boiling point:
356.9±32.0 °C(Predicted)
Density 
1.780±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
White flakes
InChI
InChI=1S/C9H8Br2O2/c1-13-9(12)6-2-3-8(11)7(4-6)5-10/h2-4H,5H2,1H3
InChIKey
GRJDNFSKEWOMIM-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(Br)C(CBr)=C1
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
M296223
Product name
Methyl4-bromo-3-(bromomethyl)benzoate
Packaging
250mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
4272AJ
Product name
Methyl4-bromo-3-(bromomethyl)benzoate
Packaging
100mg
Price
$138
Updated
2021/12/16
SynQuest Laboratories
Product number
2723-9-29
Product name
Methyl 4-bromo-3-(bromomethyl)benzoate
Packaging
250mg
Price
$240
Updated
2021/12/16
SynQuest Laboratories
Product number
2723-9-29
Product name
Methyl 4-bromo-3-(bromomethyl)benzoate
Packaging
1g
Price
$520
Updated
2021/12/16
AK Scientific
Product number
4272AJ
Product name
Methyl4-bromo-3-(bromomethyl)benzoate
Packaging
250mg
Price
$154
Updated
2021/12/16
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4-bromo-3-bromomethyl-benzoic acid methyl ester Chemical Properties,Usage,Production

Synthesis

In a 6-liter reactor equipped with a condenser, a central mechanical stirrer, and a thermometer, introduce 575 g (2.5 mol) of methyl 4-bromo-3-methylbenzoate, 3 liters of methylene chloride, 494 g (2.75 mol) of N-bromosuccinimide and 17 g of benzoyl peroxide (0.05 mol; 70percent in water). Heat the mixture at reflux under irradiation with a 1000-watt lamp for 10 h. Wash the mixture twice with 1 liter of water, then with 1 liter of saturated sodium chloride solution. Evaporate the methylene chloride. Recrystallize the crude product obtained from heptane. This gives 596 g of 4-bromo-3-bromomethyl-benzoic acid methyl ester as off-white crystals.

4-bromo-3-bromomethyl-benzoic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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142031-67-2, 4-bromo-3-bromomethyl-benzoic acid methyl esterRelated Search:

3-(BROMOMETHYL)BENZOIC ACID

  • Methyl 4-broMo-3-(broMoMethyl)benzoate
  • 4-BROMO-3-BROMOMETHYL-BENZOIC ACID METHYL ESTER
  • Benzoic acid, 4-bromo-3-(bromomethyl)-, methyl ester
  • Methyl 3-(bromomethyl)-3-bromophenylacetate
  • 3-Bromomethyl-4-bromobenzoic acid methyl ester
  • 142031-67-2