4-bromo-3-bromomethyl-benzoic acid methyl ester
- Product Name
- 4-bromo-3-bromomethyl-benzoic acid methyl ester
- CAS No.
- 142031-67-2
- Chemical Name
- 4-bromo-3-bromomethyl-benzoic acid methyl ester
- Synonyms
- Methyl 4-broMo-3-(broMoMethyl)benzoate;Methyl 3-(bromomethyl)-3-bromophenylacetate;3-Bromomethyl-4-bromobenzoic acid methyl ester;4-BROMO-3-BROMOMETHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 4-bromo-3-(bromomethyl)-, methyl ester
- CBNumber
- CB82465883
- Molecular Formula
- C9H8Br2O2
- Formula Weight
- 307.97
- MOL File
- 142031-67-2.mol
4-bromo-3-bromomethyl-benzoic acid methyl ester Property
- Boiling point:
- 356.9±32.0 °C(Predicted)
- Density
- 1.780±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- White flakes
- InChI
- InChI=1S/C9H8Br2O2/c1-13-9(12)6-2-3-8(11)7(4-6)5-10/h2-4H,5H2,1H3
- InChIKey
- GRJDNFSKEWOMIM-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(Br)C(CBr)=C1
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- M296223
- Product name
- Methyl4-bromo-3-(bromomethyl)benzoate
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4272AJ
- Product name
- Methyl4-bromo-3-(bromomethyl)benzoate
- Packaging
- 100mg
- Price
- $138
- Updated
- 2021/12/16
- Product number
- 2723-9-29
- Product name
- Methyl 4-bromo-3-(bromomethyl)benzoate
- Packaging
- 250mg
- Price
- $240
- Updated
- 2021/12/16
- Product number
- 2723-9-29
- Product name
- Methyl 4-bromo-3-(bromomethyl)benzoate
- Packaging
- 1g
- Price
- $520
- Updated
- 2021/12/16
- Product number
- 4272AJ
- Product name
- Methyl4-bromo-3-(bromomethyl)benzoate
- Packaging
- 250mg
- Price
- $154
- Updated
- 2021/12/16
4-bromo-3-bromomethyl-benzoic acid methyl ester Chemical Properties,Usage,Production
Synthesis
In a 6-liter reactor equipped with a condenser, a central mechanical stirrer, and a thermometer, introduce 575 g (2.5 mol) of methyl 4-bromo-3-methylbenzoate, 3 liters of methylene chloride, 494 g (2.75 mol) of N-bromosuccinimide and 17 g of benzoyl peroxide (0.05 mol; 70percent in water). Heat the mixture at reflux under irradiation with a 1000-watt lamp for 10 h. Wash the mixture twice with 1 liter of water, then with 1 liter of saturated sodium chloride solution. Evaporate the methylene chloride. Recrystallize the crude product obtained from heptane. This gives 596 g of 4-bromo-3-bromomethyl-benzoic acid methyl ester as off-white crystals.
4-bromo-3-bromomethyl-benzoic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
4-bromo-3-bromomethyl-benzoic acid methyl ester Suppliers
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