2-Bromo-1-bromomethyl-5-chlorobenzene

Product Name: 2-Bromo-1-bromomethyl-5-chlorobenzene
CAS No.: 66192-24-3
Chemical Name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Synonyms: 2-Bromo-1-bromomethyl-5-chlorobenzene;Benzene, 1-bromo-2-(bromomethyl)-4-chloro-
CBNumber: CB82502904
Molecular Formula: C7H5Br2Cl
Formula Weight: 284.38
MOL File: 66192-24-3.mol

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2-Bromo-1-bromomethyl-5-chlorobenzene Property

Melting point:: 63-64°C
Boiling point:: 281.5±25.0 °C(Predicted)
Density: 1.933
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Solid
color: White
InChI: InChI=1S/C7H5Br2Cl/c8-4-5-3-6(10)1-2-7(5)9/h1-3H,4H2
InChIKey: UTKGZXVMMFBCJC-UHFFFAOYSA-N
SMILES: C1(Br)=CC=C(Cl)C=C1CBr

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC

Product number: B680600
Product name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Packaging: 1g
Price: $80
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19053
Product name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Packaging: 50g
Price: $95
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19053
Product name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Packaging: 100g
Price: $152
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19053
Product name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Packaging: 25g
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19053
Product name: 2-Bromo-1-bromomethyl-5-chlorobenzene
Packaging: 250g
Price: $305
Updated: 2021/12/16

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2-Bromo-1-bromomethyl-5-chlorobenzene Chemical Properties,Usage,Production

Chemical Properties

Colourless Oil

Synthesis

14495-51-3

66192-24-3

The general procedure for the synthesis of 2-bromo-5-chlorobenzyl bromide from 2-bromo-5-chlorotoluene was as follows: 20.5 g (100 mmol) of 2-bromo-5-chlorotoluene was dissolved in 200 mL of carbon tetrachloride, followed by the addition of 0.2 g (1 mmol) of AIBN (azobisisobutyronitrile) and 19.6 g (110 mmol) of N-bromosuccinimide (NBS). The resulting mixture was refluxed for 2 h and then cooled to room temperature. The reaction mixture was sequentially washed twice with 50 mL of water, then with 50 mL of brine solution and finally dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure to give an oil containing a small amount of unreacted material. The oily substance was dissolved in 20 mL of hexane and recrystallized at room temperature to give 22.7 g (80% yield) of 2-bromo-1-bromomethyl-5-chlorobenzene. The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.50 (d, 1H, J = 8.7 Hz), 7.45 (d, 1H, J = 2.4 Hz), 7.15 (dd, 1H, J = 8.7 Hz, 2.4 Hz), 4.53 (s, 2H).

References

[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 31, p. 6404 - 6409
[2] Patent: WO2005/123054, 2005, A1. Location in patent: Page/Page column 25
[3] Patent: WO2006/46030, 2006, A2. Location in patent: Page/Page column 28
[4] Organic Letters, 2015, vol. 17, # 19, p. 4654 - 4657
[5] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 19, p. 2903 - 2909

2-Bromo-1-bromomethyl-5-chlorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-1-bromomethyl-5-chlorobenzene Suppliers

Canada 1 China 115 Germany 1 India 4 United Kingdom 1 United States 9 Global 131

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View Lastest Price from 2-Bromo-1-bromomethyl-5-chlorobenzene manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 1-Bromo-2-(bromomethyl)-4-chlorobenzene 66192-24-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-11-11

Henan Aochuang Chemical Co.,Ltd.

Product: 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-17

Henan Fengda Chemical Co., Ltd

Product: 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3
Price: US $80.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-27

66192-24-3, 2-Bromo-1-bromomethyl-5-chlorobenzeneRelated Search:

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2-Bromo-1-bromomethyl-5-chlorobenzene

Benzene, 1-bromo-2-(bromomethyl)-4-chloro-

66192-24-3

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